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282 E. Allison<br />

The most significant drawback of prospecting for hydrate using a BSR is<br />

that it provides no information about the hydrate volume. Determination of a<br />

complete methane hydrate petroleum system and seismic attribute and travel<br />

time analysis are the most reliable techniques for estimating methane hydrate<br />

volumes. These advanced techniques are in their infancy, but are rapidly progressing<br />

based on laboratory studies of methane hydrate properties, modelling<br />

seismic properties of methane hydrate-bearing sediment and comparison of<br />

seismic predictions with drilling.<br />

2.2 . Petroleum system approach<br />

Using a petroleum system approach to predict methane hydrate deposits provides<br />

a more precise prediction of the location and volume of methane hydrate deposits.<br />

Definition of a geological setting in which coarse-grained sediments occur in areas<br />

with methane and within the hydrate stability zone provides a more reliable indicator<br />

of concentrated methane hydrate deposits than BSRs. The petroleum system<br />

includes the source rock, migration path, reservoir rock and seal. For methane<br />

hydrate, the formation temperature and pressure, pore water salinity, and gas<br />

chemistry must also be within the hydrate stability field. The MMS and BLM<br />

assessments that will be published in 2008 use a petroleum system approach.<br />

2.3 .<br />

Types of hydrate accumulations<br />

Methane hydrates have been identified and sampled from sub-sea outcrops<br />

and below sediments in the Arctic and offshore. Arctic deposits are contained<br />

in porous and permeable strata, much as are conventional hydrocarbons. In the<br />

marine realm, methane hydrate may form mounds on the seafloor, fill steeply<br />

dipping fractures or faults, or occupy pores of sub-sea sediments.<br />

The critical fact guiding technology for future production is that hydrate concentrations<br />

are greater in coarser-grained sediment. For comparison, hydrate<br />

deposits occur in fine-grained sediments, at Blake Ridge, Atlantic offshore the<br />

south-east USA, and in coarse-grained sediments, in the Arctic deposits in<br />

Alaska and Canada.<br />

At Blake Ridge, Ocean Drilling Program leg 164 found methane hydrate disseminated<br />

in sediments and filling faults. Disseminated hydrate represented<br />

1–5% of bulk volume. Sediment analysis showed that although essentially all<br />

sediments are silt- and clay-sized, hydrate concentrations were highest, based<br />

on negative chlorine anomalies in pore waters, in the coarsest grained sediments<br />

[17] . The estimated total volume of methane hydrate at Blake Ridge is<br />

2–3%, which is too low to consider commercial exploitation.<br />

In the 2007 methane hydrate stratigraphic test well at Milne Point Field, Alaska,<br />

hydrate pore saturations were 60–75% in sediments ranging from very-finegrained<br />

sandstone to medium-grained sandstone. The Mallik 2002 well in the<br />

Mackenzie Delta, Canada, logged about 110 m of methane hydrate-bearing strata<br />

(sand, pebble conglomerate and minor siltstone), with hydrate concentrations

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