Control of Volatile Organic Compounds Emissions from Manufacturing

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Within Line Table F-8. STYRENE'-IN-AIR UNCONTROLLED EMISSION RATES EQUIVALENT TO $1,00O/Mg, $2,00O/Mg, , and $3,00O/Mg Uncontrolled Emi ssion Rates, kg/Mg _I Across Line 0.1983 0.165)4 0.1561 I I I , I I 1
TECHNJCAL REPORT DATA {Please read lnstruct~ons on the reverse before completing) .REPORT NO. 2. 3. RECIPIENT'S ACCESSION NO. EPA-450/3-83-008 .TITLE AND SUBTlTLE 5. REPORT DATE Control of Volatile Organic Compound Emissions from November, 1983 .. Manufacture of High-Densi ty Polyethylene, Polypropylene 6, ORGANIZATloN CODE and Polystyrene Resins .AUTHOR(S) 8. PERFORMING ORGANIZATION REPORT NO. 1 .PERFORMING ORGANIZATION NAME AND ADDRESS (10. PROGRAM ELEMENT NO. Pacific Environmental Services, Inc. 1905 Chapel Hi1 1 Road Durham,, NC 27707 I 2. SPONSORING AGENCY NAME AND ADDRESS 113.TYPE OF REPORT AND PERIOD COVERED U. S. Environmental Protection Agency Fin-1 14. SP'O~'$U~~INGAGENCY CODE Office of Air Qua1 ity Pl anning and Standards Research Triangle Park, North Carolina 27711 5. SUPPLEMENTARY NOTES 6. ABSTRACT Control techniques guide1 ines (CTG) are issued for the control of volatile organic compounds (VOC) from certain pol'ymer manufacturing plants to inform Regional , State, and local air pollution control agencies of reasonably available control technology (RACT) for development of regulations necessary to attain the national ambient air quality standards for ozone. This document contains information on VOC emissions and the costs and environmental impacts of RACT in polypropylene liquid-phase process plants, high-density polyethylene slurry process plants and polystyrene continuous process plants. 7. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS DEN DEN TI FIERS/OPEN ENDED TERMS Ic. COSATI FieId/Group Air Pollution Volatile Organic Compounds Polymers Resins Polyethylene Pol ypropyl ene Polystyrene 1 18. DISTRIBUTION STATEMENT 19. SECURITY CLASS (ThisReporf) 121. NO. OF PAGES . Unclassified 302 20. SECURITY CLASS (This page) 22. PRICE Unl imi ted Unclassified EPA Form (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE I
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dine Series Emission Standards and
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TABLE OF CONTENTS ................
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D.2 THERMAL INCINERATOR VOC EMISSIO
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LIST OF TABLES End Uses of Polyprop
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Typical Inci nerator Parameters for
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LIST OF FIGURES Simplified Process
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2.1 INTRODUCTION 2.0 PROCESS AND PO
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Polypropylene resins are supplied i
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Table 2-2. POLYPROPYLENE (PP) PLANT
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Fxlrus loll l'el lciiz ltlq Methano
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Tab1e 2-3. CHARACTER1 STICS OF VENT
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in addition to C3 and process dilue
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used in maki fig shopping bags. For
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I 2 CTC E%% PCS A wrcc 2 C W P U iZ
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Table '2-6. CHARACTERISTICS OF VENT
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A1 though polymers with molecular w
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A - . STYREL +VACUUH SYSTEM (8) (9)
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Tab1e 2-8. CHARACTERISTICS OF VENT
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3.0 EMISSION CONTROL TECHNIQUES Vol
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that they require for complete comb
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PILOT AND CENTER mAlri JET ELNATION
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Ground flares are usually enclosed
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flare was operated with from 130 t
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w Table 3-1 . FLARE EMISSIONS STUDI
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has become less common during the p
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Waste Gas- Stack Section Figure 3-3
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chamber temperatures ranging from 7
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= alti-
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control can be used. Any breakdown
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and, in some cases, reused in the p
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are immiscible with the coolant. Th
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3.2 .I .1 Condenser Control Efficie
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VOC -*, VENT TO VcntS~ AmOSPnERE Fi
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ABSORBlHG UQUlD WITH VOC OUT To Dis
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REFERENCES FOR CHAPTER 3 Lee, K.C.,
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Reference 24, p. 34. Key, J . A. Or
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4.1 INTRODUCTION 4.0 ENVIRONME NTAL
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Table 4-1. UNCONTROLLED EMISSION RA
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C Table 4-3. UNCONTROLLED EMISSION
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the results and an analysis of cost
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Tab1e 4-4. MODEL PLANT ENVIRONMENTA
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Tab1e 4-5. ADDITIONAL ENERGY REQUIR
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-- Table 4-7. ADDITIONAL ENERGY REQ
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5.0 CONTROL COST ANALYSIS OF RACT T
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m I W 1. Simple. continuous uanuall
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Tab1e 5-2, INSTALLATION COST FACTOR
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FOOTNOTES FOR Tab1 e 5-3 a Incl ude
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In order to prevent an explosion ha
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analysis of the Distil 1 ation NSPS
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Install ed piping and ducting costs
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estimated by the same procedure as
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.ble 5-4. POLYPROPYLENE MODEL PLANT
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Table 5-6. POLYSTYRENE MODEL PLANT
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emitters, while other dryers, e.g.,
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Table 5-8. COST ANALYSIS FOR POLYPR
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other dryers may have higher or low
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Table 5-11. COST ANALYSIS FOR HIGH
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Table 5-12. COST ANALYSIS FOR POLYS
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Polymer Table 5-15. COST EFFECTIVEN
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effectiveness of polystyrene contro
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EEA. Distil lation NSPS Pi peline C
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APPENDIX A LIST OF COMFIENJERS
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APPENDIX B COMMENTS OW MAY 1982 DRA
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Mr. J. R. Famet Page 2 EPA June 16,
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October 19, 1981 Attachment to June
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Be The mocial plant does nst incEud
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1000 BRAZOS, SUITE 200, AUSTIN, TEX
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our previous comments the TCC quest
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. . . . " . . 5. Emission Reduction
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REFERENCES Texas Chemical Council t
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' Y !. Jack R. Faner o The A~ency h
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NATION& AIR POLLUTION CONTROL Y COM
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" DEFINITION OF INCINERATION AS MCT
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-5- IN SUWRYj THE AGENCY, BY RELYIN
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STRUMS WITH RELATIVELY STABLE FLOW
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1 I CoHPlTIONS OF 10 TIMES NORMAL S
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I 1 I - gU - I I n G PROPO.SED INCI
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The use of data from the CTG for ai
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Mr. Jack R. Farmer, Chief July 19,
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APPENDIX C MAJOR ISSUES AND RESPONS
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generally for large volume, variabl
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control devices, such as thermal an
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modification or rep1 acement, based
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epresent excellent agreement for su
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Response: The following responses a
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processes (e.g ., polypropylene and
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I I I I The purpose of this appendi
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Data collection continued for each
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Test . Number ~104Velocity (scfm) (
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found for tests of incinerators at
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7' Tab1e 0-4. TYPICAL INCINERATOR P
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I I I I I l l I averages for the mo
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Table D-5. ARC0 POLYMERS INCINERATO
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Thempies Spaced Evenly Across the T
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probe for the temperature while a w
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The total installed capital cost of
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3. Test Results - VOC destruction e
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Figure D-4. Petro-Tex 0x0 unit inci
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air to reduce the air flow through
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HEAT EXCHANGE1 NOTE: From Exchanger
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' organic carbon. chromatography. T
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D.3 VAPOR RECOVERY SYSTEM VOC EMISS
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However, the calculations assume pe
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The 20 pprn level was judged to be
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REFERENCES FOR APPENDIX D McDaniel,
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APPENDIX E: DETAILED DESIGN AND COS
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characteristics: volumetric flow ra
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Footnotes for Table E-1 astandad co
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sources to the flare header were as
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Flare Tip Diameter (in.) Figure E-1
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Table E-3. CAPITAL AND ANNUAL OPERA
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Footnotes for Table E-3 aFluidic se
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Tab1e E-4. WtORKSHEET FOR CALCULATI
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excess air for oxygen in the waste
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Table E-6. PROCEDURE TO DESIGN THER
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I I a plant had a use for it, heat
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Footnotes for Table E-7 Wpdated usi
Page 255 and 256: Table E-8. OPERATING PARAMETERS AND
Page 257: TABLE E-9. GAS PARAMETERS USED FOR
Page 260 and 261: ~ 1 1 I I l 1 I I represent June 19
Page 262 and 263: Tabl e -11 CAPITAL AND . IERATIONG
Page 264 and 265: $0.335/scfm for units with no heat
Page 266 and 267: Table E-12. PROCEDURE TO CALCULATE
Page 268 and 269: Footnotes for Table E-12 (Concluded
Page 270 and 271: i m- Table E-13. PROCEDURE TO CALCU
Page 272 and 273: I - I - 1 A nnnrrn~~nrc rn rnl PIII
Page 274 and 275: Table E-15. CAPITAL AND ANNUAL OPER
Page 276 and 277: aUpdated using Chemical ~ I nneiri
Page 278 and 279: Condenser ~y2 ! ;tern Area (ftL) Fi
Page 280 and 281: ased on an equation in the Chemical
Page 282 and 283: m Equi p ent Type Check Valves Gate
Page 284 and 285: - 1/8 - - Table E-20. INSTALLED DUC
Page 286 and 287: Reference 12, p. 6-3 and 6-4. Refer
Page 289 and 290: APPENDIX F CALCULATION OF UNCONTROL
Page 291 and 292: Table F-1 . INITIAL EMISSION CHARAC
Page 293 and 294: Table F12. SUMMARY OF ANNUAL COSTS,
Page 295: = the difference between the operat
Page 298 and 299: I 8 - a F.Z. 1 Sty rene-i n-Steam m
Page 300 and 301: (9 CE = AC - (0.9 ~ CDnA ~ x eRC) d
Page 302 and 303: Substituting the values from Table
Page 304 and 305: Table 7. EXPONENTS USED FOR CONDENS
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Control of Volatile Organic Compounds Emissions from Manufacturing

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