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Tellurite And Fluorotellurite Glasses For Active And Passive

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6. Optical properties; MDO 169<br />

quartz / glass prism. As refractive index increases with frequency, high frequency<br />

radiation is deflected to a higher degree as it passes though the prism [3]. Problems<br />

associated with passing the beam through a material (such as absorption) can be avoided<br />

by using a diffraction grating. This device consists of a glass or ceramic plate with fine<br />

parallel grooves of the order of the wavelength of light (≈ 1 µm). The grating is covered<br />

in a reflective coating (aluminium). Reflection from the grating results in interference,<br />

which is constructive at certain angles, depending on the wavelength of the light. The<br />

intensity of the diffracted beam is enhanced by shaping the grating in a certain way,<br />

resulting in blazing [3].<br />

Fourier transform (FT)<br />

The spectrometer used in this study operated by a Fourier transform (FT) method. The<br />

Fourier transform infrared (FTIR) spectrometer used a Michelson inferometer to analyse<br />

the individual frequencies present in a composite signal. The Michelson inferometer<br />

operated by splitting the beam from the sample into two, then introduced a path<br />

difference, δ, into one of them, which was varied. The two beams were then recombined,<br />

and interfered constructively or destructively, depending on δ. The intensity of the signal<br />

from the sample, I, varied according to equation (6.4) [3].<br />

~ ~<br />

I ( δ ) = I(<br />

f )( 1+<br />

cos 2πfδ<br />

)<br />

(6.4)

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