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Tellurite And Fluorotellurite Glasses For Active And Passive

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2. Literature review; MDO 56<br />

2.5.2.1. TeO2-ZnF2 glasses reported in the literature<br />

Table (2.5) summarises the ZnF2 containing fluorotellurite compositions found in the<br />

literature, and the melting procedures used:<br />

Table (2.5): <strong>Fluorotellurite</strong> glasses reported in the literature and melting procedures used<br />

(T = melting temperature and t = melting time)<br />

Composition<br />

Mol. %<br />

ZnF2<br />

Crucible<br />

Material<br />

T / °C<br />

t /<br />

min.<br />

Ref.<br />

9TeO2-2PbO-1ZnF2<br />

8.20<br />

4TeO2-1PbO-1ZnF2<br />

7TeO2-2PbO-3ZnF2<br />

3TeO2-1PbO-2ZnF2<br />

16.40<br />

24.80<br />

33.20<br />

Fused silica and<br />

zirconia<br />

950 to<br />

1000<br />

N/A [13]<br />

75.9TeO2-9.13PbO-15.17ZnF2 15.17<br />

63.29TeO2-7.99PbO-28.72ZnF2<br />

52.14TeO2-6.93PbO-40.91ZnF2<br />

42.79TeO2-5.4PbO-51.81ZnF2<br />

28.72<br />

40.91<br />

51.81<br />

N/A 3 750 15 [56]<br />

64TeO2-24ZnO-12ZnF2<br />

12.00<br />

65TeO2-13ZnO-22ZnF2<br />

22.00 Alumina 650 N/A [29]<br />

65TeO2-2ZnO-33ZnF2<br />

33.00<br />

45.4TeO2-9PbO-45ZnF2-0.6PrF3 45.00 Platinum 600 30 [58]<br />

63.3TeO2-8PbO-28.7ZnF2<br />

28.70<br />

52.1TeO2-7PbO-40.9ZnF2<br />

42.1TeO2-6PbO-51.9ZnF2<br />

37.7TeO2-5.3PbO-57ZnF2<br />

40.90<br />

51.90<br />

57.00<br />

N/A N/A N/A [59]<br />

61.7TeO2-14.9ZnO-23.4ZnF2<br />

44.9TeO2-17.3ZnO-37.8ZnF2<br />

23.40<br />

37.80<br />

Silica 650 60 [60]<br />

68TeO2-12PbO-20ZnF2<br />

20.00<br />

59TeO2-11PbO-30ZnF2<br />

50TeO2-10PbO-40ZnF2<br />

30.00<br />

40.00<br />

Platinum 600 30 [61]<br />

46TeO2-9PbO-45ZnF2<br />

45.00<br />

50TeO2-9.6As2O3-40ZnF2-0.4Cr2O3 40.00<br />

50TeO2-9.6Bi2O3-40ZnF2-0.4Cr2O3 40.00 N/A N/A N/A [62]<br />

50TeO2-9.6P2O5-40ZnF2-0.4Cr2O3 40.00<br />

74.7TeO2-18.3ZnO-7.1ZnF2<br />

7.10<br />

74.6TeO2-8.8ZnO-16.6ZnF2<br />

16.60<br />

69TeO2-9.3ZnO-21.7ZnF2<br />

21.70 Platinum 650-800 20 [30, 31]<br />

60.5TeO2-12ZnO-27.5ZnF2<br />

27.50<br />

46.6TeO2-18.2ZnO-35.2ZnF2<br />

35.20<br />

3 No data given in reference.

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