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Tellurite And Fluorotellurite Glasses For Active And Passive

Tellurite And Fluorotellurite Glasses For Active And Passive

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6. Optical properties; MDO 194<br />

Absorption coefficient / cm -1<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

Baseline: y=[(1590/x)^4]+0.45<br />

Chi^2 = 0.00008<br />

R^2 = 0.99767<br />

y0 0.00187 ±0.00048<br />

xc1 2257.82319 ±0.47642<br />

w1 235.31403 ±1.0363<br />

A1 61.8435 ±0.40145<br />

xc2 2910.02939 ±2.74629<br />

w2 505.17789 ±3.48049<br />

A2 358.85514 ±3.78988<br />

xc3 3265.15307 ±2.05741<br />

w3 312.84954 ±3.92314<br />

A3 81.39494 ±3.61733<br />

Wavelength / µm<br />

5.5 5.0 4.5 4.0 3.5 3.0<br />

FTIR data<br />

Gaussian fit<br />

Strong OH (2258 cm -1 )<br />

Weak OH (2910 cm -1 )<br />

Free OH (3265 cm -1 )<br />

2000 2500 3000 3500<br />

Wavenumber / cm -1<br />

Fig. (6.16): Gaussian deconvolution of OH bands in glass MOD007 (78TeO2-10Na2O-<br />

12ZnO mol. %).<br />

Absorption coefficient / cm -1<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

Baseline: y=[(1570/x)^4]+0.33<br />

Chi^2 = 0.00011<br />

R^2 = 0.99615<br />

y0 0 ±0<br />

xc1 2261.38432 ±1.08347<br />

w1 208.90675 ±2.17886<br />

A1 46.6942 ±0.51201<br />

xc2 2916.60287 ±4.42523<br />

w2 480.60961 ±5.92156<br />

A2 298.9132 ±5.24167<br />

xc3 3262.28566 ±3.32385<br />

w3 284.56526 ±6.47127<br />

A3 65.64121 ±4.89148<br />

Wavelength / µm<br />

5.0 4.5 4.0 3.5 3.0<br />

2000 2200 2400 2600 2800 3000 3200 3400 3600<br />

Wavenumber / cm -1<br />

FTIR data<br />

Gaussian fit<br />

Strong OH (2261 cm -1 )<br />

Weak OH (2917 cm -1 )<br />

Free OH (3262 cm -1 )<br />

Fig. (6.17): Gaussian deconvolution of OH bands in glass MOD013 (80TeO2-10Na2O-<br />

10ZnO mol. %), thickness 2.98 mm.<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

Loss / dB.m -1<br />

Loss / dB.m -1

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