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Tellurite And Fluorotellurite Glasses For Active And Passive

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6. Optical properties; MDO 171<br />

where δmax = maximum pathlength difference of the inferometer. Therefore, a resolution<br />

of 0.2 cm -1 , gives δmax = 2.5 cm.<br />

Detectors<br />

The detector in a spectrometer converts the incident radiation received from the sample<br />

into an electronic signal to be processed. Much like the source, the detector type depends<br />

on the region of the electromagnetic spectrum being investigated. However,<br />

semiconductor detectors are commonly used in the ultraviolet (UV), visible and IR. One<br />

popular type of semiconductor detector is known as a charge coupled device (CCD) [3].<br />

In higher frequency regions, such as the visible and UV, a photomultiplier is alternatively<br />

used. This photomultiplier works by releasing an electron from a photosensitive screen<br />

each time it is struck by an incident photon. This electron is accelerated by a current,<br />

striking further screens creating a cascade effect, resulting in an amplified signal.<br />

Although semiconductor devices are becoming more frequently used, thermocouple<br />

detectors are sometimes used for the IR [3].<br />

Intensities of absorption bands and the Beer-Lambert law<br />

An empirical equation, known as the Beer-Lambert law, can be used to calculate the<br />

intensity of absorption, I, with sample thickness, l. This is shown by equation (6.8) [3].<br />

log<br />

I<br />

I<br />

0<br />

= −ε[<br />

J ] l<br />

(6.8)

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