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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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PL.ATINUM 101<br />

S. Bidwell studied the relati<strong>on</strong> between the resistance, R, <strong>and</strong> the thermal<br />

expansi<strong>on</strong> ; <strong>and</strong> A. Stein, the relati<strong>on</strong> between the resistance <strong>and</strong> the melting-point.<br />

According to E. L. Nichols, if I denotes the length of platinum at temp, up to<br />

near the m.p., then taking the values of R <strong>and</strong> I at 0°, as unity, the corresp<strong>on</strong>ding<br />

values of Z <strong>and</strong> R are :<br />

I . 1-0000 1-00125 1O0489 1-01022 1-01229 1-01371 1-01495 1-01567<br />

R . l-OOOO 1-5057 2-3035 3-3533 3-7090 3-8904 40655 4-2005<br />

W. Br<strong>on</strong>iewsky studied the subject. The relati<strong>on</strong> between the resistance <strong>and</strong> the<br />

thermal c<strong>on</strong>ductivity was studied by G. Wiedemann <strong>and</strong> R. Franz, <strong>and</strong> H. Reddemann<br />

; <strong>and</strong> W. Jager <strong>and</strong> H. Diesselhorst observed that platinum has a greater<br />

value for the ratio thermal : electrical c<strong>on</strong>ductivity, <strong>and</strong> a greater temp. coefF.<br />

than corresp<strong>on</strong>ds with Wiedemann <strong>and</strong> Franz's rule—3. 21, 5. F. Streintz, <strong>and</strong><br />

8. Bidwell studied the relati<strong>on</strong> between the specific heat <strong>and</strong> the resistance of<br />

platinum ; <strong>and</strong> N. F. Mott, the relati<strong>on</strong> between the latent heat, the m.p., <strong>and</strong> the<br />

electrical c<strong>on</strong>ductivity. R. Bornstein said that the c<strong>on</strong>ductivity of platinum is<br />

increased by exposure to light ; but C. W. v<strong>on</strong> Siemens observed no perceptible<br />

change. The subject was discussed by C. Hausemann, <strong>and</strong> F. Weber. According<br />

to W. Jager <strong>and</strong> H. v<strong>on</strong> Steinwehr, the percentage increase in the resistance, SR,<br />

of a platinum wire—0-1 mm. in diameter, <strong>and</strong> 35 cms. in length, <strong>and</strong> total resistance<br />

5 ohms—by the passage of a current of C amperes, as the temp, rises 86°, is as<br />

follows :<br />

(1 . . . 00043 0Ol 96 00355 0-0524 0-0689 O-IOOO<br />

SR . . O 0-035 OIO 0-235 0-41 0-88<br />

80. . . O 0009 0-025 0-059 0101 0-220<br />

The subject was studied by F. Weber. A. Broca <strong>and</strong> M. Turchini studied the<br />

resistance of platinum to alternating currents. A. T. Waterman, <strong>and</strong> J. W. Nichols<strong>on</strong><br />

.studied the electr<strong>on</strong> theory of c<strong>on</strong>ducti<strong>on</strong>. K. Bamberger observed no change in<br />

the resistance of platinum in a magnetic field, <strong>and</strong> the subject was studied by<br />

W. Kohlrausch, S. U. Christie, <strong>and</strong> P. Kapitza ; <strong>and</strong> L. Grmimaeh found that a<br />

transverse magnetic field produces but a very small change in the resistance.<br />

F. Weigert found that a platinum wire 0-05 mm. diameter <strong>and</strong> of resistance<br />

13-18 ohms, had a resistance of 13-311 ohms in a magnetic field of 11,500 gauss,<br />

<strong>and</strong> 13-242 ohms in a magnetic field of 16'21O ohms. N. d'Agostino observed<br />

that with a wire 0-15 mm. <strong>and</strong> 13*48 ohms resistance, the quotients x of the changein<br />

the magnetic field <strong>and</strong> the total resistance for magnetic fields of 2400, 3690,<br />

4840, <strong>and</strong> 6510 gauss are respectively — 0-0s25, 0-0561, OC)4Il, <strong>and</strong> 0-0420.<br />

J. Frenkel <strong>and</strong> N. Miroluboff, G. Borelius, H. M. Barlow, A. T. Waterman,<br />

F. Sim<strong>on</strong>, H. F. Mott, <strong>and</strong> E. H. Hall studied the theory of c<strong>on</strong>ductivity ; <strong>and</strong><br />

Z. A. Epstein, the periodic variati<strong>on</strong> of the resistance of metals with at. wts.<br />

The heating effect of the electric current in platinum was studied by<br />

E. Becquerel,2 G. D. Botto, J. G. Children, H. Davy, A. Farkas <strong>and</strong> H. H. Rowley,<br />

R. T. Glazebrook <strong>and</strong> co-workers, W. R. Grove, E. Lenz, J. Muller, W. H. Preece,<br />

P. Riess, A. de la Rive, M. Viard, <strong>and</strong> F. Zollner ; the use of platinum for<br />

resistance wires in electric furnaces, by G. Nordstrom ; the development of<br />

stati<strong>on</strong>ary waves by wires heated by alternating currents, by A. Imhof ; the effect<br />

<strong>on</strong> sounds produced by the current, by T. Argyropulos, B. M. Fergus<strong>on</strong>, <strong>and</strong><br />

W. H. Preece ; the mechanical acti<strong>on</strong> of the current by A. Berliner, E. Edlund,<br />

F. Exner, W. R. Grove, R. Nahrwold, G. -v<strong>on</strong> Quintus-Icilius, <strong>and</strong> H. Streintz ;<br />

<strong>and</strong> the resistance at the c<strong>on</strong>tact surface of electrode <strong>and</strong> electrolyte by O. Scarpa ;<br />

<strong>and</strong> R. Holm, at the c<strong>on</strong>tact of two surfaces ; E. Branly observed the unipolar<br />

c<strong>on</strong>ductivity of the Ag-Mica—Pt c<strong>on</strong>denser ; F. Skaupy <strong>and</strong> O. Kantorowicz, the<br />

resistance of the compressed powder ; H. Rohmann, the unipolar c<strong>on</strong>tact between<br />

two pieces of platinum wire which have been heated to inc<strong>and</strong>escence for a l<strong>on</strong>g<br />

time in vacuo ; R. Holm <strong>and</strong> R. Stormer, the resistance of platinum c<strong>on</strong>tacts ; <strong>and</strong>

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