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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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PLATINUM 365<br />

(xxiii) Dichlor<strong>on</strong>tiritoethylenediaminoamminohydroxide, [Pt(NH3) Cn(NO2)Ol2]-<br />

OH, <strong>and</strong> its isomerides.<br />

(xxiv) Trichlorotristribenzyloxyphosphines, [Pt{(C7H7)3PO}3Cl31Y, represented<br />

by the chloride,<br />

(xxv) Dihydroxynitratotriammines, [Pt(NH3)3(OH)2(N03)]Y, represented by<br />

the nitrate,<br />

(xxvi) HydroXydinitratotriatnmiries, [Pt(NH3)3(OH)(N03)2lY, represented by<br />

the bromide,<br />

(xxvii) Dinitratochlorotriammines, [Pt(NH3)3Cl(N03)2JY, represented by the<br />

chloride,<br />

(xxviii) Dinitratobromotriammines, [Pt(NH3)3Br(N03)2]Y, represented by the<br />

bromide,<br />

(xxix) Nitratodibromotrianbmines, [Pt(NH3)3Br2(NO3)JY, represented by the<br />

iodide,<br />

(xxx) tSulphatobromotriafnmines, [Pt(NH3J3Br(SO4)JY, represented by the<br />

bromide.<br />

5.~- The diammine family represented by the null valent group [Pt(NH3)2X4|.<br />

(i) Dtammineft, [Pt(NH3)2X4], represented by the cis- <strong>and</strong> trans-forms of<br />

(1) hydroxide ; (2) chloride ; (3) bromide ; (4) iodide ; (5) polyiodide<br />

; (6) sulphate ; (7) nitrate ; <strong>and</strong> (8) cyanide. Also (1) trimethyliodide<br />

; (2) nitritotrichloride <strong>and</strong> a double salt with silver<br />

nitrite ; (3) nitratotrichloride <strong>and</strong> a double salt with chloroplatinite<br />

; <strong>and</strong> (4) nitratotrihydroxide. Also the cis- <strong>and</strong> transforms<br />

of (1) dihydroxysulphate ; (2) dihydroxydinitrate ; (3)<br />

dihydroxyoxalate ; (4) trichlor<strong>on</strong>itrite ; (5) dichlorodinitrite ; (ft)<br />

dibromodinitrite ; (7) sulphatodinitrite ; <strong>and</strong> (8) dinitritodinitrate.<br />

There are also (1) hydroxychlorodinitrite ; <strong>and</strong> (2) ehlorodinitrit<strong>on</strong>itrate.<br />

(ii) Propylenediamines, [PtpnX4j, represented by the chloride,<br />

(iii) Ethylenediamines, Pten(N02)Cl2J.<br />

(iv) Ethylenediamines, [Pt enX4], represented by (1) trichlor<strong>on</strong>itrite; (2)<br />

the amidotrichloride ; (3) the amid<strong>on</strong>itritodichloride ; <strong>and</strong> (4) the<br />

ethyleneaminoimidotrichloride.<br />

(v) a.p-isobutylenediamines, [ Pt(C4H8(NH2) }2J[Pt or PdOl4J, etc.<br />

(vi) Bispyridines, [Ptpy2X4|, represented by cis- <strong>and</strong> trans-forms of (1)<br />

chloride ; (2) bromide ; (3) dibromodichloride ; (4) iodide ; <strong>and</strong><br />

(5) sulphate,<br />

(vii) Pyridinoammines, [Pt(NH3) PyX4J, represented by the trichlor<strong>on</strong>itrite.<br />

(viii) Bispicolines, [Pt(C0H7N)2X4J, represented by the chloride of a-, yS-,<br />

<strong>and</strong> y-picoline.<br />

(ix) Bislutidines, [Pt(C7H9N)2X4J, represented by the chloride,<br />

(x) Biscollidines, [Pt(C8H11N)2X4], represented by the chloride,<br />

(xi) Bisquinolines, [Pt(C9H7N)2X4], represented by the chloride,<br />

(xii) Bistetrahydroquinolines, [Pt(C9H11N)2X4J, represented by the chloride,<br />

(xiii) 3-fnethyl-2-amifi<strong>on</strong>iethyl-4:-ethylquinolines, [Pt(C33H14N.NI12)2J[ PtCl4 ].<br />

(xiv) Bi&propi<strong>on</strong>itriles, [Pt(C2H5CN)2X4J, represented by the chloride,<br />

(xv) Bisbenz<strong>on</strong>itriles, [Pt(C6H5CN)2X4J, represented by (1) chloride ; <strong>and</strong><br />

(2) bromide.<br />

(xvi) fip-dimethyldipyridyls, [Pt(C12H32N2)X4J, represented by the chloride,<br />

(xvii) Bis-4, b-dimethylpyrimidines, [Pt(C6H8N2)2X4J, represented by the<br />

chloride,<br />

(xviii) Bis-4:, 5-methylethylpyrimidines, [Pt(C7H10N2)2X4J, represented by the<br />

chloride,<br />

(xix) Bisjaborines, [Pt(C9H14Ng)2X4J, represented by the chloride,<br />

(xx) Bis-a-methylisoxctzols, LPt(CUH5NO)2X4], represented by the chloride.

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