A Comprehensive Treatise on Inorganic and Theoretical Chemistry

PLATINUM 359
the potassium salt ; (4) hydrosulphite and the potassium and sodium
salts ; (5) hydronitrite and the sodium salt ; (6) hydrocyanide and
the potassium salt ; (7) hydrothiocyanate.
(xci) Bisocanthogenates, [Pt(S.CS.OC2Hg)2X2J.
(xcii) Dithiocyanates, [PtA2(SCN)2], e.g. dithiocyanatodiammine* [Pt(NH3)2-
(SCN)2], with cis- and trans-forms, and a complex with silver
nitrate ; dithiocyanatobispyridine, IPt Py2(SCN)2] ; and dithiocyanatoethylenediamine,
[Pt en(SCN)2].
(xciii) HydroxyZamineammines, [Pt(NH3)(NH2OH)X2], represented by the
chloride,
(xciv) Dinitrito-complexes, [PtA2(N02)2], e.g. dinitritodihydroxylamine,
[Pt(NH2OH)2(N02)2J, and its isomerides ; dinitritodiammine,
[Pt(NH3)2(N02)2] ; dinitritohydroxylaminoammines, [Pt(NH3)-
(NH2OH)(N02)2J ; dinitritopyridinoammine, [Pt(NH3) py(N02)2J ;
dinitritohydroxylaminopyridine, [Pt(NH2OH) py(N02)2 j; dinitritoethylenediamine,
[Pt en(N02)2].
(xcv) Chloronitrito-comple&es, [PtA2(NO2)Cl], e.g. chloronitritodihydroxylamine,
[Pt(NH2OH)2(NO2)Cl] ; chloronitritohydroxylaminoammine,
[Pt(NH3)(NH2OH)(NO2)ClJ ; cnloronitritohydroxylaminopyridine,
[ Pt py(NH2OH)(N02)ClJ ; chloronitritopyridinoaminine,
[Pt(NH3) Py(NO2)C 1 I] ; chloronitritoethylenediamine, [Pt en(N02)-
CJ] ; and chloronitritodiammine, [Pt(NH3)2(N02)C] |.
(xcvi) Ethylamineammines, [Pt(NH3)(C2H5NH2)X2J, represented by the
(1) chloride ; (2) bromide ; and (3) iodide,
(xcvii) Diftiethylarnineanimines, [Pt(NH3)((CH3)2NH)X2J, represented by the
bromide,
(xcviii) Uimethylanilinoamnnines, Pt(NH3) (( CH3) 2[C6H5N)C12].
(xcix) Anilineatnmines, [Pt(NH3)(C2H5NH2)X2], represented by the iodide,
(c) PyridinecLmmines, [Pt(NH3)(C5H5N)X2I, represented by the cis- and
trans-forms of the chloride ; and (2) the hydrosulphitochloride.
(ci) His-m-tolylenediamtTies, [Pt(C7H10N2)2 JX2, represented by (1)
chloride ; (2) sulphate ; and (3) dithionate.
(cii) EthyleneamVniries, [Pt(NH3)(C2H4)X2I, represented by the chloride,
(ciii) Ethylsulphineavrhmines, [Pt(NH3)((C2H5)2S)X2, rex>resented by the
cis- and trans-forms of the iodide,
(civ) Ethylatninehydroxyla?nines, [Pt(NH2OH)(C2H5NH2)X2], represented
by the oxide,
(cv) JPyridinehydroxylamines, [Pt(NH2OH)(C5H5N)X2], represented by the
chloride,
(cvi) Ethylenediethylamines, [Pt(C2H4)((C2H5J2NH)X2], represented by the
chloride,
(cvii) Ethyleneanilines, [Pt(C6H5NH2)(C2H4)X2], represented by the chloride,
(cviii) AnUinetrimethylphosphite, [Pt(C6H5NH2)(P(OCHg)2)X2], rej>resented
by the chloride,
(cix) Anilinetriethylphosphite, [Pt(C6H5NH2){P(OC2H5)3}X2], represented
by the cis- and trans-forms of (1) chloride ; and (2) bromide,
(ex) ToluidinetrimethylphospJiite, [Pt(C7H7NH2{P(OCH3)3}X2J, represented
by the chloride,
(cxi) Toluidinetriethylphosphate, [Pt(C7H7NH2)(P(OC2Hg)3)X2J, represented
by (1) hydroxide ; (2) cis- and trans-forms of the chloride ; and
(3) hydroxychloride.
(cxii) Pyridines, PtCl2^C5H11N.
(cxiii) Ethylenediarninebisethylenes, [Pt2 en(C2H4)2X4], represented by the
chloride,
(cxiv) Carbonylphenylhydrazines, [Pt(C6H5-N2H3)(CO)X2], represented by
the chloride.