A Comprehensive Treatise on Inorganic and Theoretical Chemistry

PLATINUM 357
(xxxix) Bisdiethylsulphines, [Pt((C2H5)2S}2X2J, represented by cis- and transforms
of (1) hydroxide; (2) chloride and chloroplatinite ; (3)
bromide ; (4) iodide ; (5) sulphate ; (6) nitrite ; (7) nitrate ; (8)
phosphate; (9) oxalate; (1O) chromate ; and (11) diehromate.
(xl) Methylelhylsulphines, [PtI(CH3)(C2Hs)S)2X2], represented by the
iodide,
(xli) ZHethylaminoethylsulphines, [Pt(C2H5)2S.(C2H5)2NHJX2, represented
by the chloride,
(xlii) Sisdipropylsulphin.es, [Pt((C3H7)2S}2X2J, with normal and iso-propyl
cis- and trans-forms of (1) hydroxide ; (2) chloride, double salts
with mercuric, stannous, and platinous chloride, and hydroxychloride
; (3) bromide ; (4) iodide and iodoplatinite ; (5) chloroiodide
; (6) sulphate ; (7) thiosulphate ; (8) nitrite ; (9) nitrate and
hydroxynitrate ; (1O) oxalate ; (11) cyanide ; (12) thiocyanate ;
and (13) chromate.
(xliii) Bisbutylsulphines, [Pt((C4H9)2S}2X2], represented by the normal, iso-.
and secondary butyl cis- and trans-forms of (1) hydroxide ; (2)
chloride and complexes with chloroform and with carbon disulphide
; (3) bromide ; (4) iodide ; (5) sulphide ; (6) sulphate ;
(7) nitrite ; (8) nitrate ; (9) chloronitrate ; and (1O) chromate.
(xliv) Bis-iso-amylsulphines, [PtI(C5H1J)2SI2X2J, represented by the (1)
chloride ; and (2) iodide,
(xlv) Bisbenzylsulpkines, [Pt(C6H5.CH2)2S}2X2J, represented by (1) chloride,
and a complex with chloroform ; (2) bromide, and complexes with
ethyl alcohol, and with chloroform ; (3) iodide ; (4) sulphate - (5)
nitrite and complex with chloroform ; and (6) hydroxynitrate.
(xlvi) Ethylenedisulphines, [Pt((C2H4)2S2}X2J, represented by (1) hydroxide ;
(2) chloride ; (3) bromide ; (4) iodide ; (5) sulphate ; (6) hydroxysulphate
; (7) nitrite ; (8) nitrate ; (9) oxalate ; (1O) cyanide ;
(11) thiocyanate ; (12) chromate ; and (13) permanganate.
(xlvii) Divriethyldilhioethylerieglycols, [Pt(CH3.S.C2H4.S.CH3)X2], represented
by (1) chloride ; and (2) nitrate,
(xlviii) Diethyldithioethyleneglycols, [Pt(C2H5-S-C2H4-S-C2H5)X2], represented
by (1) chloride ; (2) bromide ; (3) nitrite ; and (4) nitroprusside.
(xlix) JDipropylthioefhyleneglycols, [Pt(C3H7-S-C2H4S-C3H7)X2J, represented
hy (1) chloride ; and (2) nitrite.
(1) Dibutylthioethyleneglycols, [Pt(C4H9-S-C2H4-S-C4II0)X2), represented
D y (1) chloride ; and (2) nitrite.
(Ii) Diethylpropylenesulphines, Pt(C2H5.S.C3H6.S-C2H5)X2J, represented
by (1) chloride ; and (2) nitrite,
(lii) Dipropylpropylenesulphines, [Pt(C3H7.S.C3H6.S.C3H7)X2J, represented
by the chloride,
(liii) Z>^AyWi«*io^d^yfotJpAwe«,[Pt(C2H5.S.CH8.CH(OH).CH2.S.C2H6)-
X2J, represented by (1) chloride ; and (2) nitrate,
(liv) Bisethylthioglycollic acid, [Pt(CH2.S-C2H5.COOH)2X2 J, represented
by the cis- and trans-forms of the chloride.
(Iv) BisethylmethyUkioglycollate, [Pt(CH2.S.C2H5.COOCH3)2X2J, represented
by (1) the cis- and trans-forms of the chloride, and (2)
oxalate,
(lvi) Bisthioglycollic acid, [Pt(S(CH2.COOH)2}2X2J, represented by (1)
chloride ; (2) bromide ; (3) iodide, and a complex with the potassium
salt ; (4) cyanide ; and (5) thiocyanate.
(lvii) Bis sodiumthiogly collate, [Pt(S(CH2.COONa)2J2X2], represented by the
nitrite,
(lviii) B ispotassiu^ntkioglycollate, [Pt(S(CH2.COOK)2J2X2], represented by
(1) chloride ; (2) bromide ; and (3) iodide.