A Comprehensive Treatise on Inorganic and Theoretical Chemistry

PLATINUM 315
Imidoazolyl-zi-mereaptan, [PtJHS-C]Sr(C8H^CH3)CH -. CH.N :}8C14] ; platinic tetraehlorobls-
*-m-xylylimidoazolyl-/x-mercaptan, '[Pt{HS.C.3Sr.CaH8(CH3)8.CH : CH.IST :}aCl4] ; and platinic
tetrachlorobis - v - a -naphthylimidoazoly 1 - ^ - mercaptan, [Pt(MS .C.INrc10H7.CH: CH.N :> aCl4].
P. C. Ray and co-workers described platinum methylmercaptidochloride, PtCl(CH3)2S2.H20 ;
platinum mereaptldochloride, PtCl(C2Ms)2S2, and platinum mercaptldobromide, PtBr(C8H6)2S2,
in which it is assumed that the platinum is quinquivalent vide supra, the valency of
platinum ; and also Pt6Cl(R2S 2)4, in which only one platinum atom is quinquivalent.
F. W. Semmler prepared platinic disulphovlnylsulphlnevinylchloroplatlnate, 3[Pt{(C2Ha)2S}-
S2].2C8H3CLPtCl4 ; F. W. Semmler, and T. Wertheim, platinic disulphoallyl-sulphlneallylchloroplatinate,
3[Pt{(C3HB)2S>S8].2C8H6CLPtCl4 ; and C. H. Keutgen, platinic tetrachlorodlallylhexasulphine,
Pt{ (C3H 5) 2S JCl4].
C. JL,. Jackson ld described platinic tetrachlorobisdimethylselenine, [PtJ(CH8)2So>2C]4] ;
C. TL,. Jackson, platinic bistrimethylselenonlumchloride, 2(CH3)3SeCl.PtCl4 ; J. Petren,
platinic tetrachloroblsdiethylselenlne, Pt{(C2H6)2Se}2Cl4] ; A. F. W. Schimper, and L. von
Pieverling, platinic triethylselenoniumchloride, 2(C2H6J3SeCLPtCl4; J. Petren, platinic
tetrachlorodiethylseleninediethylsulphine, Pt{(CaH6)2S}{(C2H6)2So>Cl4] ; J. Petren, platinic
tetrachloroblsdiethylselenlne, [Pt{(C2HB)2Se}2Cl4J ; C. L. Jackson, platinic tetrachlorobisdibenzylselenlne,
[Pt{(C6H6.CH2)8Se}8Cl4] ; and platinic bisdimethylbenzylselenoniumchloride,
2(CHa)2(C7H7)SeCLPtCl4. A. Cahours described platinic bistrimethyltelluroniumchloride,
2(CHa)3TeCLPtCl4.
A. Cahours and A. W. Hofmann 17 described platinic bistrimethylphosphinehydrochloride,
2(CH3J3P-HCLPtCl4 ; A. Cahours and A. W. Hofmann, A. Partheil and A. van Haaron,
and J. N. Collie, platinic bistetramethylphosphoniumchloride, 2(CH3J4PCLPtCl4 ; A. W. Hofmann,
platinic bisethylphosphinehydrochloride, 2(C2H5)PH2-HCLPtCl4 ; and platinic bisdiethylphosphinehydrochloride,
2(C2H6J2PH.HCLPtCl4 ; E. Drechsel and E. Finkelstein, and
A. Cahours and A. W. Hofmann, platinic bistriethylphosphinehydrochloride, 2(C2H5)3P.HCL
PtCl4 ; Q. Sella, A. Cahours and A. W. Hofmann, platinic bistetraethylphosphoniumchloride,
2(C2Hg)4PCLPtCl4 ; A. Cahours, platinic bistrimethylethylphosphoniumchloride,
2(CH3J8(C2H6)PCLPtCl4 ; J. N. Collie, platinic bisdimethyldiethylphosphoniumchloride,
2(CH3)2(C2H5)2PCLPtCl4 ; A. W. Hofmann, and A. Cahours and A. W. Hofmann, platinic
blsmethyltriethylphosphoniumchloride, 2(CH3)(C8Hg)8PCLPtCl4 ; J. N. Collie, platinic
bistriethylpropylphosphonlumchloride, 2(C2Hg)3(C3H7)PCLPtCl4 ; R. H. Piekard and
J. TCenyon prepared trimethyloxyphosphoniumchloroplatinate, 4(CH3J3PO-H 2PtCl« ; and
a similar compound was obtained by J. A. Collie : triethyloxyphosphoniumehloroplatinate,
4(CaH6)3PO.H8PtCl6 ; and tripropyloxyphosphoniumchloroplatinate, 6(C8H7J3PO-H2PtCl6 ;
A. Cahours and A. W. Hofmann, platinic bistrimethylamylphosphoniumchloride,
2(CHa)3(C6H11)PCLPtCl4 ; J. N. Collie, and A Cahours and A. W. Hofmann, platinic bistriethylamylphosphoniumchloride,
2(C2Hg)3(C6H11)PCLPtCl4 ; A. W. Hofmann, platinic Mstriethylallylphosphoniumchloride,
2(C2H6J3(C3H6)PCLPtCl4 ; and J. N. Collie, platinic bisethyltrlbenzylphosphoniumchloride,
2(C2H6)(C7H7)3PCLPtCl4. F. Fleissner, E. A. Letts and
J. N. Collie, and R. H. Piekard and J. Konyon described platinic triehlorotrisbenzyloxyphosphinechloride,
rPt{(C7H7)3PO}3Cl8JCL
E. Pomey, and A. Rosenheim and W. LOweustamm described platinic tetrachlorobistriethylphosphite,
rPt,'P(OCaH5)3}2Cl4] ; A. Michaelis, platinic tetrachlorobis-p-dimethyloxyphosphinebenzoate,
[Pt{(CH3)8PO(CeH4.COOH)}2Cl4] ; E. Pomey, platinic tetrachlorotriethylphosphite,
[Pt{P(OC2H6)3}Cl4] ; A. Rosenheim and W. LOwenstamm, and A. Rosenheim and W. Levy,
platinic tetrachlorotriethylphosphate, [Pt{OP(OC2H6)3}Cl4J2. P. Sehiitzenberger, and P. Schiitzenberger
and C. Fontaine described a number of ill-defined complexes with phosphorus
compounds.
W. M. Dehn and B. R. Wilcox 18 described platinic bisdimethylarsinehydrochloride,
2(CH8)2AsH.HCLPtCl4 ; E. Amort, A. Partheil and E. Amort, and E. Mannheim, platinum
bistetramethylarsoniumchloride, 2(CH3)4AsCLPtCl4, or [(CH8)3AsCl]8PtCl4 ; E. Amort,
A. Partheil and E. Amort, E. Mannheim, and H. Landolt, platinic bistetraethylarsoniumchloride,
2(C2H5J4AsCLPtCl4, or [(C2H6J4AsCIl2PtCl4 ; A Cahours, platinic bisdimethyldiethylarsoniumchloride,
2(CH3J2(C2H6J2AsCLPtCl4 ; E. Mannheim, E. Amort, and
A. Partheil and E. Amort, platinic bistetra-n-propylarsoniumchloride, 2(C3H7)4AsCLPtCl4,
and platinic bistetra-I-propylarsoniumchloride, or [(C3H7)3AsCl]8PtCl4 ; E. Mannheim,
E. Amort, and A. Partheil and E. Amort, platinic bistetrabutylarsonlumehloride,
2(C4H8J4AsCLPtCl4, or [As(C4H9J3AsCl]8-PtCl4; A. Partheil and E. Amort, A. Gronovor,
and A. Michaelis and U. Paetow, platinic bistetrabenzylarsonlumehloride, 2As(C7H7)4CLPtCl4,
or [(C7H7J8AsCl]2PtCl4-H2O ; and A. Michaelis and XJ. Paetow, platinic bismethyltribenzylarsoniumchloride,
2(CH8)(C7H7J8AsCLPtCl4.
H. Landolt described platinic blstetramethylstiboniumchloride, 2(CH8J4SbCLPtCl4 ;
R. Lowig, platinic quatertetraethylstlboniumchloride, 4(C8H6)4SbC1.3PtCl4 ; A. Partheil and
E. Mannheim, and G. B. Buckton, platinic bistetraethylstiboniumchloride, 2(CaH6)4SbCLPtCl4;
A. Partheil and E. Mannheim, platinic bistetrapropylstiboniumchloride, 2(C3H7J4SbCLPtCl4 ;
and Gr, T. Morgan and V. E. Yarsley obtained platlnous trimethylstibinochloroplatinate,
[Pt{(CH8)8Sb}4]PtCl..