A Comprehensive Treatise on Inorganic and Theoretical Chemistry

PLATINUM 355
(xv) Chlorotrimethylsulphines, LIM(CHa)2S)3Cl]X, represented by the
chloroplatinate.
(xvi) Chlorotrisethylsulphines, [Pt{(C2H5)2S)3Cl]X, represented by the
chloride,
(xvii) SulpJiatotrisethylsulphines, [PtI(C2Hs)2S)3SO4.
(xviii) Nitritotrisethylsulphines, [Pt{(C2H5)2S)3N03]X, rej>resented by the
nitrate,
(xix) Sulphatobutylsulphines, [Pt{(C4H9)2S)3S04].
(xx) Chloroethylenesulphin.es, [Pt2{(C2H4)2S2)3Cl2]X2, rej>resented by the
chloride,
(xxi) C hlorotrisethylsulphines,\^Pt{(C2H5) 2B)3Cl |X,represented by the chloride,
(xxii) SulpJiatotrisethylsulphines, [Pt{ (C2H5J2Se)3]SO4.
(xxiii) Chloroanilinediammines, [Pt(NH3)2(06H5NH2)ClJX, represented by
the chloride and chloroplatinite.
(xxiv) Chlorophosphaminediammine, [Pt(NH3)2(C6H5NH2)ClJX, represented
by the double salt with ammonium chloride,
(xxv) Chlorocarbonyldiarnmines, [Pt(NH3)2(CO)Cl|X, represented by the
chloride,
(xxvi) ChloroethylsulpJiinediammines, [Pt(NH3)2{(C2H5)2S)Cl]X, represented
by the (1) chloride and chloroplatinite ; and (2) ethylmercaptide.
(xxvii) lodoethylenesulphinertiammines, [ Pt(NH3)2{(C2H4)2S2}1 JX, represented
by the iodide, and the iodochloroplatinite.
(xxviii) Chlorodiamminoethylphosphites, [Pt(NH3)2{P(OC2H5)3)Cl]X, represented
by the chloride and the chloroplatinite.
(xxix) Chlorobisanilineethylphosphite, [Pt(C6H5NH2)2{P(OC2H5)3)Cl]X, represented
by the chloride,
(xxx) Chlorobistoluidineethylphosphite, [Pt(C7H9N)2{P(OC2H5)3)ClJX, represented
by the chloride.
4.—The diammine family represented by the null-valent group [PtA2X2].
(i) Diammines, [Pt(NH3)2X2], illustrated by various cis- and trans-forms
of (1) oxide ; (2) hydroxide ; (3) chloride and double salt with
ammonium chloride ; (4) hydroxy chloride ; (5) bromide ; (6)
iodide ; (7) chlorosulphite ; (8) sulphite-doubJe salts with the
sulphites of ammonium, sodium, copper, silver, barium, zinc, lead,
uranyl, manganese, cobalt, and nickel, chlorosulphites, and ammonium
chlorosulphites ; (9) chlorohydrosulphite ; (10) sulphate ;
(11) nitrite, and nitritoplatinite ; (12) nitrate ; (13) chlorocarbonate
; (14) thiocarbonate ; (15) chlorothiocarbonate ; (16)
oxalate ; (17) cyanide and cyanoplatinite ; (18) thiocyanate and
the double salt with silver thiocyanate ; (19) mercaptides and
chloromercaptides, iodomercaptides, and sulphatomercaptides ;
(20) xanthogenate ; and (21) ethylthioglycolate ; and nitratoethylthiogly
colate.
(ii) Dihydrazines, | Pt(N2H4)2X2], represented by the chloride,
(iii) Ditiydroxylatnines, [Pt(NH2OH)2X2], represented by various cis- and
trans-forms of the (1) oxide ; (2) hydroxide ; and (3) chloride,
(iv) Hydroxylaminoammines, [Pt(NH3)(NH2OH)X2], represented by the
chloride,
(v) Bismethylamines, [Pt(CH3NH2)2X2], represented by the (1) chloride ;
and (2) bromide,
(vi) Bisethylamines, [Pt(C2H5NH2)2X2], represented by the cis- and transforms
of (1) chloride ; and (2) bromide,
(vii) Bisdiethylamines, [Pt{(C2H5)2NH)2Cl2], and also a complex with
acetone, PtCl2(C2H5)2NH.(CH3)2CO.
(viii) Bispropylamines, [Pt(C3H7NH2)2X2], represented by (1) chloride ;
and (2) iodide.