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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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192 INORGANIC AND THEORETICAL, CHEMISTRY<br />

furnished 195-191 from the ratio (NH4)2PtCl6 : Pt ; 195-216 from 6AgCl : Pt ;<br />

195-245 from 6AgCl : (NII4J2PtCl6 ; 195-213 from 6Ag : Pt ; <strong>and</strong> 195-241 from<br />

6Ag : (NH4)2PtCl6. The analyses of amm<strong>on</strong>ium bromoplatinate furnished 195-206<br />

from the ratio (NH4J2PtBr6 : Pt ; 195-214 from 6AgBr : Pt ; 195-242 from<br />

6Ag : (NH4)2PtBr6 ; 195-220 from 6Ag : Pt; <strong>and</strong> 195244 from 6Ag : (NH4)2PtBr6.<br />

The best representative value from E. H. Archibald's determinati<strong>on</strong>s is 195-22.<br />

The internati<strong>on</strong>al st<strong>and</strong>ard for the best representative value of the atomic<br />

weight of platinum for 1931 is 3 95-2, <strong>and</strong> representative values were discussed by<br />

F. W. Clarke, L,- Meyer <strong>and</strong> K. Seubert, J. I). v<strong>on</strong> der Plaats, W. M. Watts,<br />

T. W. Richards, W. A. Noyes, G. D. Hinrichs, <strong>and</strong> A. Vurtheim.<br />

C. T. Heycock <strong>and</strong> F. H. Neville 4 discussed the molecular state of platinum<br />

in alloys with cadmium, lead, <strong>and</strong> bismuth ; <strong>and</strong> E. O. v<strong>on</strong> Lippmann estimated<br />

30 to 4O atoms per molecule. W. C Roberts-Austen added that experiments <strong>on</strong><br />

the diffusi<strong>on</strong> of platinum suggested that the molecules are more complex than those<br />

of silver, or gold. The relati<strong>on</strong>s between the elements <strong>and</strong> their at. wts. were discussed<br />

by G. Osann, M. Gerber, F. Sanford, <strong>and</strong> C. A. Martius ; the relati<strong>on</strong>s<br />

between the at. wts. <strong>and</strong> the affinities of the elements, by E. D<strong>on</strong>ath <strong>and</strong> J. Mayrhofer,<br />

P. Pfeiffer, <strong>and</strong> F. Gramp ; between the at. wts. <strong>and</strong> the heats of reacti<strong>on</strong>,<br />

by M. Berthclot ; the relati<strong>on</strong>s between the at. wts. <strong>and</strong> the elastic c<strong>on</strong>stants,<br />

by J. Johnst<strong>on</strong> ; <strong>and</strong> the relati<strong>on</strong>s between the at. wts. <strong>and</strong> the colour of the<br />

elements, by M. C. Lea.<br />

The atomic number of platinum is 78. E. Amaldi, 5 A. J. Dempster, B. Fuchs<br />

<strong>and</strong> H. Kopfermann, H. Kopfermann <strong>and</strong> K. Krebs, B. Jaeckel <strong>and</strong> H. Kopfermann,<br />

F. Allis<strong>on</strong> <strong>and</strong> E. J. Murphy, <strong>and</strong> B. Veiikatesachar <strong>and</strong> L. Sibaiya reported<br />

that platinum has five isotopes of atomic mass 192, (193), 194, 195, <strong>and</strong> 196 with<br />

the relative abundances, for the 192, 194, 195, <strong>and</strong> 196 isotopes are, respectively,<br />

2, K), 13, 16 ; J. H. Bartlett studied the subject. The atomic disrupti<strong>on</strong> of<br />

platinum by the bombardment of

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