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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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PL.ATINUM 227<br />

<strong>and</strong> H. G<strong>on</strong>ningt<strong>on</strong>, the hydrogen-oxygen reacti<strong>on</strong>. W. A. Nemiloff discussed the<br />

microstructure of the alloys. W. A. Nemiloff's observati<strong>on</strong>s <strong>on</strong> the Brinell's<br />

2400<br />

2300°<br />

2200°<br />

2100<br />

2000<br />

mod<br />

I /<br />

/<br />

/<br />

/<br />

1800°<br />

\l770°<br />

1700<br />

0 20 40 BO 8O Wf)<br />

Per cent of Iridium<br />

KiG. 73. The Liquidus<br />

Curvn of !Platinurnlridium<br />

Alloys.<br />

/<br />

?34 20<br />

/<br />

Ff<br />

C<br />

/ 7/<br />

r<br />

10 \/—\<br />

^ ^ 2 »<br />

300<br />

250<br />

200' j<br />

"J<br />

150 *<br />

1001 i<br />

c<br />

50<br />

20 40 60<br />

100<br />

KiG. 74.<br />

Per cent of Indium<br />

The Tensile Strength <strong>and</strong> Hardness<br />

Platinurn-Iridium Alloys.<br />

of<br />

hardness are summarized in Fig. 74, <strong>and</strong> the same diagram gives the tensile strength<br />

of the alloys in kgrms. per sq. mm.—vide Table IV.<br />

J. Weerts obtained the dimensi<strong>on</strong>s a of the parameters<br />

of the face-centred cubic lattice of the alloys shown in<br />

Fig. 75. F. Goldberger <strong>and</strong> O. Kienberger studied the<br />

streak as an indicati<strong>on</strong> of the compositi<strong>on</strong> of the alloy.<br />

W. Geibel observed that alloys made into wires 1 mm.<br />

diameter, had a breaking load, in kilograms, of<br />

«, 4 00, 1<br />

Iridium<br />

Load<br />

O<br />

24<br />

5<br />

40<br />

IO<br />

48<br />

15<br />

66<br />

2O<br />

81<br />

25<br />

98<br />

' 3-90<br />

Ar_<br />

« 3-8O1 20 40 60 80<br />

Atom, per cent. Pt<br />

100<br />

FIG. 75. The I-attice Parameter<br />

of the Ir-Pt Alloys.<br />

3O<br />

114<br />

35 per cent<br />

126 kgrms.<br />

K. Steinmann's results for the effect of annealing <strong>on</strong> the tensile strength are summarized<br />

in Fig. 76. K. B. Thews gave 40 kgrms. per sq. mm. for a 5 per cent,<br />

iridium alloy, <strong>and</strong> 100 kgrms. per sq.<br />

mm. for a 25 per cent, iridium alloy.<br />

E. M. Wise <strong>and</strong> J. T. Eash gave for<br />

the alloy with 20 per cent, iridium,<br />

reduced 50 per cent, by cold drawing,<br />

the ultimate strength 140,500<br />

lbs. per sq. in., proporti<strong>on</strong>al limit<br />

101,000 lbs. per sq. in., el<strong>on</strong>gati<strong>on</strong><br />

2-5 per cent, in 2 in., a reducti<strong>on</strong><br />

in area of 85 per cent. ; after a<br />

softening anneal at 1400°, the ultimate<br />

strength was 93,500 lbs. per sq.<br />

in. ; proporti<strong>on</strong>al limit, 59,5CX) lbs.<br />

per sq. in. ; el<strong>on</strong>gati<strong>on</strong>, 20 per cent,<br />

in 2 ins., <strong>and</strong> reducti<strong>on</strong> of area, 88<br />

per cent. F. E. Carter gave for<br />

Brineirs hardness, H, Erics<strong>on</strong>'s ductility<br />

test in mm.; <strong>and</strong> the resistance, R ohms per milli<strong>on</strong> feet<br />

Iridium<br />

H$ Hard<br />

^Annealed .<br />

fHard<br />

DuctilityjAnnealed|l<br />

-R . .<br />

.<br />

.<br />

.<br />

.<br />

uoo°<br />

1200°<br />

O<br />

97<br />

47<br />

7-8<br />

12-2<br />

12-2<br />

6O<br />

5<br />

170<br />

110<br />

71<br />

10-7<br />

10-7<br />

12O<br />

0° 200° 400" 600° 800° 1000T 1200 1400<br />

Fio. 76. The Effect of the Annealing Temperature<br />

<strong>on</strong> the Tensile Strength.<br />

IO<br />

22O<br />

150<br />

71<br />

100<br />

10-4<br />

16O<br />

15<br />

280<br />

190<br />

70<br />

9-7<br />

10-2<br />

185<br />

2O<br />

33O<br />

230<br />

70<br />

9O<br />

9-7<br />

2OO<br />

25<br />

37O<br />

270<br />

4-1<br />

80<br />

7-8<br />

2lO<br />

3O per cent<br />

4OO<br />

31O<br />

—<br />

20<br />

210

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