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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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10 INORGANIC AND THEORETICAL. CHEMISTRY<br />

surface-deposits, wore not swept away. They were c<strong>on</strong>centrated later <strong>on</strong> in the<br />

alluvia—perhaps at the time of the most intense glaciati<strong>on</strong>, probably in the Pleistocene.<br />

The basic igneous rocks, from which the platinum is derived, are exposed in the<br />

form of disc<strong>on</strong>tinuous elliptical outcrops near the summits of the Urals, particularly<br />

<strong>on</strong> the western side of the mountains. These outcrops attain larger dimensi<strong>on</strong>s in<br />

the northern <strong>and</strong> central TJrals than farther south. The process of c<strong>on</strong>centrati<strong>on</strong> of<br />

platinum in the gravels has clearly extended over a very l<strong>on</strong>g period of time, <strong>and</strong><br />

it is probable that the richer gravels have been rec<strong>on</strong>c<strong>on</strong>trated, perhaps several<br />

times.<br />

According to L. Duparo <strong>and</strong> co-workers, the deposits are essentially of magmatic<br />

origin. The structure of the rock is in the nature of c<strong>on</strong>centric b<strong>and</strong>ings ; the felspathie<br />

rocks at the outer edge grachially grade into the intermediate stage of pyroxenes,<br />

until the central tlunite is reached, composed of olivine <strong>and</strong> chromite. The richness<br />

of the gravels is in proporti<strong>on</strong> to the size of the dunite deposits, <strong>and</strong> to the extent of<br />

erosi<strong>on</strong> of these rocks. Platinum ore derived from a pyroxenite source usually<br />

c<strong>on</strong>tains high percentages of platinum <strong>and</strong> palladium, but low percentages of osmium<br />

<strong>and</strong> ir<strong>on</strong>. The reserves in 1916 wore sufficient for about twelve years, provided<br />

that the same methods of working <strong>and</strong> rate of extracti<strong>on</strong> were employed during that<br />

period.<br />

According to A. D. Lumb, platinum is c<strong>on</strong>centrated in channels of the Rivers Iss, Veeya,<br />

<strong>and</strong> Tura ; north of these, the metal is obtained from beds of the Rivers Sognovki, Kythymi,<br />

<strong>and</strong> Mala Kosva ; <strong>and</strong>, al<strong>on</strong>g with gold, in the systems comprised in the Rivers Vagran,<br />

Lobva, Niasma, Liabia, Aktai, Emorlo, Talits, <strong>and</strong> Ivdevi. In the south, platinum is<br />

worked <strong>on</strong> the tributaries of the Rivers Tagil, Salda, Imiaura, <strong>and</strong> Tura. In the Nizhni -<br />

Tagilsk district, the richest placers are iix the valleys of the Rivers Visim, Martian, Sisim,<br />

Chaush, <strong>and</strong> Cherna, <strong>and</strong> farther south, al<strong>on</strong>g with gold, in the gravels of Nevian, Verkhne-<br />

Isot, 13il<strong>on</strong>ibaov, Alapaov, Sysert. Kyshtym, <strong>and</strong> Mias, <strong>and</strong> in the Rivers Tanalyk, Sakmar,<br />

<strong>and</strong> Urtazym. There are smaller deposits in Nikolae-Pavdinsk, Rastos, <strong>and</strong> Systersk.<br />

The placer deposits are derived from country rock made up of serpentine gabbro, diallage,<br />

<strong>and</strong> olivenite <strong>and</strong> the associated minerals are chiefly quartz, zirc<strong>on</strong>, ilmenite, chromite,<br />

magnetite, spinel, <strong>and</strong> native gold <strong>and</strong> palladium. The crude platinum usually includes<br />

iridium, rhodium, ruthenium, <strong>and</strong> ir<strong>on</strong>. A. A. Losch, A. Karpinsky, <strong>and</strong> A. Jvrassnopolsky<br />

discussed the occurrence of platinum in Bissersk, -where a 2-kgrm. nugget of platinum was<br />

found. In additi<strong>on</strong> to what has been previously stated, the Ural deposits were discussed<br />

by C. Blomoke, G. Rose, A. Inostranzeff, I. Koifman, A. G. Betochtin, V. P. Mishin,<br />

G. Padalka, E. P. Moldavantzeff, P. P. Pihpenko, G. A. Dod<strong>on</strong>off, A. Breithaupt,<br />

A. N. Zavaritzky, J. «J. Berzelius, C Zerr<strong>on</strong>nor, A. v<strong>on</strong> Lasaulx, P. V. Jeremojeff,<br />

G. Schuler, P. Iieyschlag <strong>and</strong> co-workers, A. P. Stahl, M. v<strong>on</strong> Engolhardt, J. Podoroff.<br />

L>. Serdyuch<strong>on</strong>ko, <strong>and</strong> C. Hmtze vide supra. A. Solit<strong>and</strong>er reported the presence of<br />

platinum in the auriferous s<strong>and</strong>s in the north of Filml<strong>and</strong>.<br />

The occurrence of traces of platinum in the auriferous s<strong>and</strong>s of the River "Ivalo, in<br />

Lapl<strong>and</strong>, was noted by A. K. Nordenskjold, 1 " <strong>and</strong> P. .T. Wiik, <strong>and</strong> at Vaske, <strong>and</strong> Tanna-Juk,<br />

by J. H. Langer. The occurrence of traces of platinum in the nickeliferous pyrrhotitc of<br />

Smal<strong>and</strong> in Sweden was discussed by J. H. L. Vogt, 17 L. de Launay, <strong>and</strong> P* M. Stapff.<br />

J. H. Li. Vogt,* 8 <strong>and</strong> G. Lunde <strong>and</strong> M. Johns<strong>on</strong> also described the presence of traces of<br />

platinum in the nickel ores of Norway ; <strong>and</strong> G. vom Rath, in the silver of K<strong>on</strong>igsberg.<br />

J. PT. Vogel 19 roportod traces of platinum in Portugal. According to L. N. Vauquelni,^ 0<br />

platinum occurs in Spain in the silver mines of Guadalcanal, Estremadura, although<br />

J. J. Berzolius had doubts <strong>on</strong> this subject. A. Orio reported traces of platinum to be<br />

associated with the pyrites of Asturia. According to A. D. Lumb, the metal lias also been<br />

noted at R<strong>on</strong>da, Malaga, in the alluvial deposits al<strong>on</strong>g the Rivers Verde <strong>and</strong> Guadaiza.<br />

The deposits are derived from serpentine <strong>and</strong> peridotite rocks. The pay gravels c<strong>on</strong>tain<br />

8 grms. of platinum per t<strong>on</strong>. The metal has also been reported in the other parts but<br />

not in payable quantities. It occurs principally in the northern districts, <strong>and</strong> in the<br />

Rivers Minho, Luna, SiI, Orbigo, Gallego, Cinea, Darro, <strong>and</strong> lower Jenil, where it occurs<br />

in the c<strong>on</strong>centrate s<strong>and</strong>s accompanied by magnetite, ilmenite, zirc<strong>on</strong>, <strong>and</strong> frequently gold.<br />

S. P. de Rubies, K. Rubio, L. Duparc <strong>and</strong> A. Grosset, T. C. Earl, F. Gillman, <strong>and</strong> D. y Orueta<br />

<strong>and</strong> S. P. de Rubies discussed the occurrence of platinum in Spain.<br />

Asia.—The Uralian deposits in Asia have been indicated in c<strong>on</strong>necti<strong>on</strong> witli the<br />

Russian deposits. R. Helmhackor 21 reported the presence of platinum in the auriferous<br />

s<strong>and</strong>s of Altai ; <strong>and</strong> it has also been reported in Armenia—Batum <strong>and</strong> Sasun—by L. do<br />

Launay, 82 but n<strong>on</strong>e was found by A. G. Betochtin in the peridotites of Gokoha. J. P. Kemp,<br />

<strong>and</strong> N. Nakovnik reported it in Siberia—in Baikal, Balkash, <strong>and</strong> Jenissei. K. Jimbo, <strong>and</strong><br />

T. Wada observed that in Japan, the metal occurs in the auriferous s<strong>and</strong>s of the province of<br />

Ishakari, <strong>and</strong> the Yubari River of Iburi ; in the Rivers Yubari-garva, Pechau, <strong>and</strong> other<br />

rivers in the province of Hokkaido where gold <strong>and</strong> iridosmium are associated with the<br />

platinum. It is also found in the gold <strong>and</strong> ir<strong>on</strong> s<strong>and</strong>s of the Nishi-Mikawa, in the province<br />

of Sado. E. de Hautpiek menti<strong>on</strong>ed the occurrence of platinum in the auriferous gravels<br />

in the Uryanchai district of M<strong>on</strong>golia, <strong>on</strong> the Russian border of China. L. de Launay<br />

found that the metal also occurs in the auriferous s<strong>and</strong>s of Rigal, in the Philippines. Traces

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