A Comprehensive Treatise on Inorganic and Theoretical Chemistry

PLATINUM 311
W. Rudneff, A. Hies, and P. Groth, two modifications of the compound with tertiary amyl.
A. W. Hofmann, A. Ries, and J. A. Io Bel studied platinic bisdiamylaminehydrochloride,
2(C5HiX)2]SrII-HCLPtCl4, with n-amyl ; R. T. Plimpton, and R. D. Silva, the compound
•with inactive iso-amyl, and R. T. Plimpton, the compound with active iso-amyl.
A. W. Hofmann studied platinic blstriamylaminehydrochloride, 2(C5H11J3]Sr-HCLPtCl4,
with n-amyl ; R. T. Plimpton, and R. D. Silva, with inactive iso-amyl ; and R. T. Plimpton,
with active iso-amyl. A. W. Hofmann described platinic bistetramylammonlumchloride,
2(C5H11J4NCLPtCl4 ; R. Stormer and V. von Lepel, platinic bismethyl-i-amylaminehydrochloride,
2(CH3)(C5H11)ISrH-HCLPtCl4 ; J. A. Ie Bel, and A. Ries, platinic bistrimethylamylammoniumchloride,
2(CHj)3(C5H11)NCLPtCl4, with active amyl ; H. and A. Malbot,
O. Schmiedeberg and E. Harnack, J". A. Ie Bel, A. Ries, and P. Groth, with iso-amyl.
J. A. Ie Bel, A. Ries, and P. Groth studied platinic bisethyl-i-amylaminehydrochloride,
2(CaH5)(C5H11)NH-HCLPtCl4, with n-amyl, and A. Durand, with inactive amyl.
A. W. Hofmann described platinic bisdiethyl-i-amylaminehydroehloride, 2(CaH5)2(C5H11)N.
HCLPtCl4, also platinic bistriethyl-i-amylammoniumchloride, 2(C2H1J)8(C5H11)NCLPtC]4;
and platinic bismethylethyl-1-amylaminehydrochloride, 2(CH3)(C2H5)(C5H11)N-HCLPtCl4 ;
S. B. Schryver and J. N. Collie, platinic bismetbyldietnylamylammoniumchloride,
2(CH3)(C2H5)2(C5H1 J)NCLPtCl4 ; with inactive n-amyl, and i-amyl ; and J. A. Ie Bel,
and P. Groth, platinic methylethylpropyl-i-amylammoniumchloride, 2(OH3)(C2H6)(C3H7)-
(C5H11)NCLPtCl4.
A. Cahours and A. W. Hofmann, H. Malbot, and C. Liobermann and C. Paal described
platinic bisallylaminehydrochloride, 2(C3H5)NH2-HCLPtCl4 ; A. Cahours and A. W. Hofmann,
and H. Malbot, platinic bistriallyaminehydrochloride, 2(C3H5)3N.HCLPtCl4 ; and
platinic bistetrallylammoniumchloride, 2(C3Hg)4NCLPtCl4 ; J. Weiss, H. and A. Malbot,
and A. Partheil, platinic bistrimethylallylammoniumchloride, 2(CH3)3(C3H5)NCl.PtCl4 ;
A. Rinne, and C. Liebermann and C. Paal, platinic bisethylallylaminehydrochloride,
2(C2H6)(C3H5)NH-HCLPtCl4 ; A. Riniie, and C. Liobermann and C. Paal, platinic bisdiethylallylamlnehydrochloride,
2(C2H6)a(C3H5)N.HCLPtCl4 ; F. Reboul, platinic bistriethylallylammoniumchloride,
2(C2H5)3(C3H5)NCLPtCl4 ; C. Liebermann and C. Paal, platinic
bispropylallyaminehydrochloride, 2(C3H7)(C3HJNH-HCLPtCl4 ; and P. Grotli, and C. Liobermann
and C. Paal, platinic bisdipropylallylaminehydrochloride, 2(C3H7)J8(C3H5)N-HCLl 3 ICl4.
N. S. Kurnakoff, 4 and A. Schleicher and co-workers prepared platinic dichlOTObisethylenediaminechloride,
[Pt(C2H4(NH 2)2}2C12]C12, and platinic dichlorobisethylenediaminechlorocuprate,
[Pt{CaH4(NHa)2}aCl2JCuCl4, as well as a complex with platinous bisethylenediaminet-hlorocuprate
vide supra. P. M. Jager studied the crystals of the first-named salt.
W. Schacht, and C. Neuberg prepared platinic ethylenediaminehydrochloride, C2H4(NHj)2.
2HCLPtCl4 ; J. Lifschitz and K. Rosenbohm studied the optical properties of platinic
trisethylenediaminochloride, fPt On3]Cl4.2*5 aq. A. P. Smirnoff obtained platinic trispropylenediaminochloride,
[Pt(C3H6NaH4)3JCl4.HaO, in its racemic, and dextro-, and lajvo-forms.
A. Werner, platinic tetrachloropropylenediamine, [Pt{C3H6(NHa)2}Cl4J ; A. Werner, platinic
dichlorobispropylenediaminechloride, LPt{C3H6(NH2)2}2Cl2]Cl2 ; and A. W. Hofmann, platinic
propylenediaminehydrochloride, C3H6(NH2)2.2HCl.PtCl4. L. A. Tschugaoff and co-workers
prepared platinic chloroamidotetramminoehloride, [Pt(NH3)4(NH2)ClJCl2 ; and P. C Mann, platinic
tetrachloro-££'£' -triaminopropanemonohy drochlorlde, [Pt(NH2-CH2-CHNH2-CH2-NH2)-
(HCl)Cl4J-H2O ; and platinic tetrachloro-#8'/3''-triaininopropanemonohydrochloroplatinate,
TPt(NH2-CH2-CHNH2-CH2NH2)(HCl)I2PtCl4-H2O ; platinic dichloro-/3/3'£"-triaminotriethylaminochloride,
[PtN(C2H4.NH2)3Cl2JCl2, platinic diehloro-j8j803''-trlaminotriethylaminoehloroplatinate,
[PtN(C2H4.NH2)3Cl2JPtCl6.2H20 ; and also 3PtCl4.2N(C2H4.JSlH2)3.6HCL10H2O.
I. 1. Tscherniaoff and A. N. Federova prepared platinic dichloroethylenediaminodiammine,
[Pt(NHs)2enCl2ICl2 ; and platinic nitritochloroethylenediaminodiammine, [Pt(NHj)2On-
(NO2)ClJCl2. The former reacts reversibly -with aq. ammonia to form a mixed pentammine,
[Pt(NH3)3 en ClJX3, and hexamine, [Pt(NH3J4 enJX4. I. I. Tscherniaoff prepared three
of the four possible isomerides of platinic nitritodichloroethylenediaminomethylaminochloride,
[Pt en (CH8.NH2)(N02)C12JC1 ; and also the optical isomerides of platinic dinitritochloroethylenediaminomethylaminochloride,
[Pten(CH3.NH2)(N02)2ClJCl ; and of platinic
dinltritochloroethylenediaminopyridinochloride, [Ptenpy (NO2)2CJJCl ; I. I. Shukoif and
O. P. Shipulina studied the absorption of platinic trichloroamminoethylenediaminochloride,
[Pt(NH3) en Cl3JCl, by charcoal. F. G. Mann obtained platinic tetrachlorodiaminodiethylaminohydrochloride,
[Cl4Pt(HaN.C2H4)aNH.HClJ, the corresponding platinic tetrachlorodiaminodiethylaminohydrochloridechloroplatinate,
[Cl4Pt(H2N.CaH4)2NH.HClJ2PtCl4.H20, and
platinic trlchlorodiamlnodiethylamino, [PtCl3-(H2N.C2H4)2NHJ. F. G. Mann and W. J. Popo
prepared optically active platinum tetraehlorotriaminopropanemonohydrochloride,
CHa.NH2.HCl
Cl •
Cl\ • xNHa—CH
>Pt<
C 1X^ NH2-CH2
E. Fischer, 5 and E. Benouf prepared platinic bisdimethylhydrazinehydrochloride,
2(CH3)aN2Ha.HCLPtCI4 ; E. Fischer, platinic bisdiethylhydrazinehydrochloride, 2(C2H6)a-