A Comprehensive Treatise on Inorganic and Theoretical Chemistry
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A Comprehensive Treatise on Inorganic and Theoretical Chemistry

A Comprehensive Treatise on Inorganic and Theoretical Chemistry

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278 INORGANIC AND THEORETICAL CHEMISTRY<br />

chloride, [Pt(C7H9NHa)a(P(OCH3)8)8JCla ; platinous bistoluidineblsetbylphosphitoehloride,<br />

LPt(C7H7NHg)8(P(OC 8H6M8]Cl8 ; A. Rosenheim <strong>and</strong> W. Levy, P. Schutzenberger,<br />

P. Schutzenberger <strong>and</strong> C. F<strong>on</strong>taine, <strong>and</strong> C. H. Herty <strong>and</strong> R. O. IS. Davis, platinous<br />

cbloroethylphosphltodiamminoehloride, [Pt(NHs)8{P(OC8H8)s}Cl]Cl; platinous chloroethylphosphltodiamminochloroplatinate,<br />

[Pt(NH8)a)P(OCaH5)8)ClJPtCl8 ; <strong>and</strong> also complexes<br />

[Pt(NH8)a{F(OCaH6)8)JCla, or [Pt(NH8)3(P(OC8H5)8)JPtCl6 ; D. Cochin prepared platinous<br />

chloroethylphosphltobisanilinochloride, [Ft(C6HgNH8)2(P(OC2H6)8)ClJCl; <strong>and</strong> platinous<br />

chloroethylphosphitobistoluidinechloride, [Pt(C7H7NHj)8(F(OC8Hg)8)ClJCl. A. Rosenheim <strong>and</strong><br />

co-workers, <strong>and</strong> P. Schutzenberger, platinous dichloroblsmetnylphosphite, [Pt(P(OCH3)3)aCl8] ;<br />

platinous dichlorobisethylphosphlte, [Pt(P(OCgH6),}aCl8] ; A. Rosenheim <strong>and</strong> W. Levy,<br />

platinous dichloroblsphenylphosphite, [Pt(P(OC6H6)a)2Cla] ; I>. Cochin, platinous dlehloranilinemethylphosphlte,<br />

[Pt(C6H6NH2)(P(OCHj)8)CIg] ; D. Cochin, <strong>and</strong> A. Rosenheim <strong>and</strong> W. Levy,<br />

platinous dlchloroanillnethylphosphite, IPt(C6HgNH2)(P(OC2Hg)3)Cl2), in its trans- <strong>and</strong><br />

cis-forms; platinous dlchlorotoluidinemethylphosphite, [Pt(C7H7NHa)(P(OCH8)3)ClaJ;<br />

P. Schtitzenberger <strong>and</strong> M. G. Saillard, M. G. Saillard, <strong>and</strong> G. Quesneville, platinous<br />

dlehlorotoluidinethylphosphite, [Pt(C7H7NH8)(P(OC2Hg)8)Cl2J ; in the trans- <strong>and</strong> cisforms,<br />

<strong>and</strong> P. Schtitzenberger, platinous chlorohydroxytoluidinethylphosphite, [Pt(C7H7NH2)-<br />

(P(OCaH6)3}(OH)Cl]. A. Rosenheim <strong>and</strong> W. Levy prepared platinous dichloropyridinethylphosphlte,<br />

(Pt(C6H6NJ(P(OC8Hg)8)Cl8, in its trans- <strong>and</strong> cis-forms ; G. Quesneville,<br />

platinous hydroxychlorophosphoanilidephosphoxyanilide, [Pt(P(C8H6N)8)(PO(C8H6N))(OH)ClJ ;<br />

platinous hydroxychiorophosphoanilidephosphoxytoluidide,LPt(P(C7H8N)3)(PO(C7H8N)}( OH)Cl];<br />

P. Schtitzenberger <strong>and</strong> C. F<strong>on</strong>taine, platinous tetrachloroethylenebisethylphosphlte,<br />

[Pt8(C3H4)(P(OC8Hg)3)8C14J ; platinous dlchlorocarb<strong>on</strong>ylethylphosphite, Pt(CO)(P(OCaH6)8}Clal;<br />

platinous dlchlorophosphorustrioxidethylphosphite, [Pt(P(OH)3)(P(OC2Hg)3)Cl2; platinous<br />

dichlorophosphorustrichloridethylphosphite, [Pt(PCl3)(P(OC2Hg)3)Cl8] ; <strong>and</strong> platinous dichloromethylphosphitoethylphosphite,<br />

[Pt(P(OCH3)8)(P(OC8H5)3)]Cl2 ; P. Schutzenberger <strong>and</strong><br />

C. F<strong>on</strong>taine, P. Schutzenberger, <strong>and</strong> O. W. Gibbs, platinous dichlorotribydroxyphosphorous<br />

acid, [Ft(P(OH)3)Cl2J2; platinous chlorooxypentahydroxyphosphite, [Pt(P(OH)3)Cl(OP(OH)2)I2 ;<br />

<strong>and</strong> platinous chlorodioxytrihydroxyphosphite, [Pt(P(OH)8)Cl(OPO)J8 ; P. Schtitzenberger,<br />

<strong>and</strong> C. F<strong>on</strong>taine, platinous dichloromethylphosphlte, [Pt(P(OCH3)8)Cla)2 ; P. Schutzenberger<br />

<strong>and</strong> C. F<strong>on</strong>taine, <strong>and</strong> A. Rosenheim <strong>and</strong> W. Lowenstamm, platinous dichloroethylphosphite,<br />

[Pt(P(OC2Hg)3)Cl2J2; IX Cochin, platinous diehloroethylphosphitechloroplatinite,<br />

[Pt(P(OC2HB)3)Cl2]2.2PtCl2 ; K. Pomey, platinous dichloropropylphosphite, [Pt(P(OC6H7J3)-<br />

Cl8J8; P. Schiitzenbergor'<strong>and</strong>C. F<strong>on</strong>taine, platinous dichlorom<strong>on</strong>oallylphosphite, [I»t(P(OH)2-<br />

(OC3H5)JCl2J8 ; platinous dichlorodisilverphosphite, [Pt(P(OH)(OAg)2)Cl2J2, <strong>and</strong> some complex<br />

salts ; platinous dlchlorotrisilverphosphite, [Pt(P(OAg)3)Cl2J2 ; <strong>and</strong> platinous tetrachloroleadphosphite,<br />

[Pt2(P2(O2Pb)8)Cl4J.5H2O, <strong>and</strong> a basic salt. G. Quesneville prepared platinous<br />

bisphosphaminodiamminechloride, [Pt(NH3)2(P(NHa)3)2JCla, as a double salt with amm<strong>on</strong>ium<br />

chloride ; <strong>and</strong> platinous ehlorophosphamlnediamminoehloride, [Pt(NH3)2(P(NH2)3)ClJCl, as<br />

a double salt associated with amm<strong>on</strong>ium chloride ; <strong>and</strong> it also occurs as a lieptahydrate.<br />

G. Quesneville reported platinous hydroxychlorophosphotrianilide, [Pt(P(C6H6N)3)(OH)ClJ,<br />

platinous hydroxychlorophosphotritoluidide, [PtI(C7H8N)3)(OH)Cl; anilinium phosphotrianilidetrichloroplatinite,<br />

[Pt(P(C6H6N)8)Cl3JH(C6H6NH2) ; <strong>and</strong> toluidinium phosphotritoluididetrichloroplatinite,<br />

[Pt(P(C7H8N)3)Cl3JH(C7H7NH2).<br />

A. Cahours<strong>and</strong>H. Gal prepared platinous quatertriethylarsinechloride, [Pt(As(C2H8)3)4JCl2 ;<br />

platinous trans-dlchlorobistriethylarsine, [Pt(As(CaH5)8)8Cl2J ; <strong>and</strong> platinous cis-dlchlorobistriethylamine.<br />

K. A. Jensen measured the dipole moments of cia- <strong>and</strong> tmn«-compounds with<br />

the phosphines, arsines, <strong>and</strong> stibines; <strong>and</strong> he prepared platinous dichlorobistributylarsine,<br />

[Pt((C4H B)3As)2Cl2]. R. Bunsen prepared platinous dichloroxycacodyl, [Pt(As(CH3)40)Cl8J,<br />

<strong>and</strong> the cacodyl compounds were studied by K. A. Jensen <strong>and</strong> E. Frederiksen. A. W. Hofmann,<br />

<strong>and</strong> K. A. Jensen prepared platinous dicbioroblstriethylstiblne, [Pt(Sb(CaH6)8)aCl2] ;<br />

<strong>and</strong> K. A. Jensen, platinous dichloroblstributylstibine, [Pt((C4H9)3Sb)2Cl8J; <strong>and</strong> platinous<br />

dlchlorobistrlphenylstibine, [Pt{(C6H6)3Sb)2Cl2], <strong>and</strong> he measured their dipole moments.<br />

Chloroplatiilites.—L. N. Vauquelin, 10 <strong>and</strong> G. Magnus prepared amm<strong>on</strong>ium<br />

chloroplatinite, (NH4]I2PtCl4, by evaporating a mixed soln. of platinous chloride<br />

<strong>and</strong> amm<strong>on</strong>ium chloride in hydrochloric acid, <strong>and</strong> drying the crystals at 100°.<br />

M. Peyr<strong>on</strong>e saturated a soln. of platinous chloride in hydrochloric acid with<br />

amm<strong>on</strong>ium carb<strong>on</strong>ate, evaporated the soln. to dryness <strong>on</strong> a water-bath, washed<br />

the reddish residue repeatedly with alcohol to remove the amm<strong>on</strong>ium chloride,<br />

exposed the product in air so as to remove all traces of alcohol, dissolved the<br />

product in boiling water, <strong>and</strong> filtered the hot liquid. When the liquid is allowed<br />

to cool slowly, prismatic crystals are deposited. L». F. Nils<strong>on</strong> obtained the salt<br />

by adding amm<strong>on</strong>ium chloride to the mother-liquors obtained in the preparati<strong>on</strong><br />

of very soluble chloroplatinites. J. Thomsen added hydrochloroplatinic acid to a<br />

hot soln. of potassium chloroplatinite, added amm<strong>on</strong>ium chloride to the filtered<br />

liquid, <strong>and</strong> evaporated the liquid for crystallizati<strong>on</strong>. P. Berthier added amm<strong>on</strong>ium

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