A Comprehensive Treatise on Inorganic and Theoretical Chemistry

More documents

Recommendations

Info

346 INOKGANIC AND THEORETICAL, CHEMISTRY SeUk. Forh., 145, 1868 ; H. Topsoe and C. Christiansen, Ann. Chim. Phys., (5), 1. 42, 1874 ; Danske Selsk. Skrift., (5), 9. 623, 1873. 29 W. Crookes, Journ. Chem. Soc, 17. 112, 1864 ; Chem. News, 9. 37, 1864 ; G. Engel, Centr. Min., 285, 1934; Zeil. Krist., 90. 341, 1935; M. Hebberling, Liebig'a Ann., 184. 11, 1865; F. Kuhlmann, Chem. News, 58. 1037, 1864 ; L,. F. Nilson, Journ. prakt. Chem., (2), 15. 266, 1877 ; (2), 16. 269, 1877 ; Nova Acta Upsala, (3), 9. 15, 1877 ; Oefvers. Akad. Fork., 33. 7, 1876; W. F. Salra-Horstmar, Pogg. Ann., 99. 638, 1856; Journ. prakt. Chem., (1), 70. 121, 1857 ; A. Welkow, Her., 1. 304, 1874 ; G. Werthcr, Journ. prakt. Chem., (1), 92. 197, 1864. 80 C. Benedicks, Ze**. anorg. Chem., 22. 393, 190O ; P. T. Cleve, Bull. Soc. Chim., (2), 21. 118, 197, 247, 345, J874 ; (2), 48. 162, 359, 1885 ; Compt. Rend., 91. 427, 188O ; 97. 94, 1883 ; Zeit. anorg. Chem., 82. 129, 1902 ; F. T. Frerichs and E. F. Smith, Liebig's Ann., 191. 331, 1878; M. Holtzmann, Journ. prakt. Chem., (1), 84. 76, 1861 ; Phil. Mag., (4), 22. 216, 1861 ; S. John, Brhang. Akad. Stockholm, 2. 6, 1874 ; Bull. Soc. Chim., (2), 21. 534, 1874 ; J. C. G. de Marignae, Arch. Sciences Geneve, (2), 46. 193, 1873 ; Ann. Chim. Phys., (4), 30. 45, 1873 ; L.. F. Nilson, Ber., 9. 1056, 1876 ; Bull. Chim. Phys., (2), 27. 206, 1877 ; C. von Scheele, Zei*. anorg. Chem., 18. 352, 1898. 31 K. Birnbaum, Zeit. Chem., (2), 3. 520, 1867 ; L. F. Nilson, Oefvers. Akad. Forh., 38. 7, 187« ; Nova Acta Upsala, (3), 9. 15, 1877 ; Journ. prakt. Chem., (2), 15. 181, 1877 ; W. Peters, Zeit. anorg. Chem., 77. 176, 1912 ; Ber., 42. 4831, 1909 ; P. Rohland, ib., 16. 306, 1898 ; H. TopHue, Danske Selsk. Forh., 144, 1868 ; Arch. Sciences Geneve, (2), 45. 223, 1872. 32 P. T. Olevo, Oefvers. Akad. Forh., 18. 169, 1861 ; Svenska Akad. Handl., 6. 4, 1866; G. O. Higley, Journ. Arner. Chem. Soc., 26. 613, 1904; S. M. Jorgensen, Journ. prakt. Chem., (2), 20. 129, 1879 ; (2), 30. 15, 1884 ; L. F. Nilson, ib., (2), 15. 281, 1877 ; (2), 16. 267, 1877 ; Bull. Soc. Chim., (2), 27. 210, 1877 ; Oefvers. Akad. Forh., 33. 7, 1876 ; Nova Acta Upsala, (3), 9. 79, 1877 ; P. Pfeiffer and P. Koch, Zeit. anorg. Chem., 56. 294, 1907 ; P. Pfeiffer and T. Ci. Undo, Ber., 37. 4282, 1904 ; W. J. Sell, Proc. Roy. Soc, 33. 269, 1882 ; 45. 343, 1889 ; Ii. F. Weinland, Ber., 41. 3237, 1908 ; R. F. Weinland and F. Biittner, Zeit. anorg. Chem., 75. 368, 1912 ; R. F. Weinland and P. Rinkelacker, Ber., 42. 3009, 1909 ; R. F. Weinland and E. Gussmann, ZHt. anorg. Chem., 67. 18O, 1910; A. Werner, Ber., 41. 3461, 1908. 33 P. A. von Bonsdorff, Fogg. Ann., 17. 250, 1829; 19. 337, 183O ; H. St. C. Deville and J. S. tttas, Proves Verb. Comite Internat. Poids Mesures, 160, 1878 ; E. Herlinger, Zeit. Krtst., 62. 454, 1925; I.. F. Nilson, Oefvers. Akad. Forh., 33. 7, 1876 ; Nova Acta Upsala, (3), 9. 15, 1877 ; Journ. jtrakt. Chem,., (2), 16. 261, 1877 ; L. Pauling, Zeit. Krist., 72. 49O, 1930 ; W. Peters, Ber., 42. 4829, 1909 ; Zeit. anorg. Chem., 11. 177, 1912 ; H. Topsoe, Danske SeUk. Forh., 148, 1868; Arch. Sciences Geneve, (2), 35. 58, 1868; (2), 45. 223, 1872; H. Topsoe and C. Christiansen, Ann. Chim. Phys., (5), 1. 42, 1874 ; Danske Schrift., (5), 9. 623, 1873. 84 A. G. Bergman, Journ. Russ. Phys. Chem. Soc., 56. 177, 1925 ; P. A. von Bonsdorff, Pogg. Ann., 17. 25O, 1829 ; 19. 337, 1830 ; C. D. Braun, Untersuchungen uber ammoniakalische KobaUverbindungen, Gottingen, 14, 1862 ; J. N. Bronsted and A. Petersen, Journ. Amer. Chem. Soc, 43. 2269, 1921 ; F. Claudet, Journ. Chem. Soc., 4. 359, 1852 ; F. Ephraim and W. Fliigel, Helvetica Ch%m. AcUi, 1. 726, 1924 ; W. Gibbs, Proc. Amer. Acad., 11. 17, 1876 ; W. Gibbs and F. A. Genth, Amer. Journ. Science, (2), 23. 245, 329, 1857 ; E. Herlinger, Zeit. Krist., 62. 154, 1925 ; F. M. Jager, %b., 39. 544, 1904 ; S. M. Jorgensen, Danske Skrift., 6, 1865 ; Zeit. anorg. Chem., 5. 189, 1894; 16. 194, 1898; Journ. prakt. Chem., (2), 18. 229, 1878; (2), 31. 55,1885; (2), 35. 425, 1887 ; (2), 39. 12, 1889 ; (2), 41. 457, 189O ; (2), 42. 216, 1890 ; L.Pauling, Zeit. Krist., 72. 49O, 1930 ; W. Peters, Ber., 42. 4829, 1909 ; Zeit. anorg. Chem., 11. 178, 1912 ; J. B. RogojHky, Journ. prakt. Chem., (1), 56. 496, 1852 ; Ann. Chim. Phys., (3), 41. 451, 1854 ; H. Steinmetss, Zett. Krist., 57. 252, 1922; H. Topsoe, Danske Selsk. Forh., 151, 1868; Arch. Sciences Geneve, (2), 35. 58, 1869 ; H. Topsoe and C. Christiansen, Ann. Chim. Phys., (5), 1. 42, 1874 ; Danske Skrift., 9. 623, 1873 ; G. Vortmann, Ber., 15. 1897, 1882 ; A. Werner, Liebig's Ann., 886. 19O, 1912; A. Werner and R. Feenstra, Ber., 39. 1544, 1906 ; A. Werner and R. Frohlieh, ib., 40. 2232, 1907 ; A. Werner and J. Furstenberg, Biebig's Ann., 375. 102, 191O ; A. Werner and G. Jantseh, Ber., 40. 4432, 1907 ; A. Werner and E. Kindseher, Liebig's Ann., 375. 82, 191O ; A. Werner and A. Klein, Zeit. anorg. Chem., 14. 38, 1897 ; A. Werner, H. Kuh and P. Wiist, Ber., 47. 1973, 1914 ; A. Werner and G. Lindenberg, Liebig's Ann., 386. 271, 1912 ; A. Werner and A. Miolati, Zeit. phys. Chem., .14. 517, 1894. 36 W. Biltz, Zeit. anorg. Chem., 115. 241, 1921 ; P. A. von Bonsdorff, Pogg. Ann., 17. 25O, 1829 ; 19. 337, 1830 ; E. Herlinger, Zeit. Krist., 62. 154, 1925 ; N. S. Kurnakoff, Zeit. anorg. Chem., 22. 467, 1900 ; Journ. Russ. Phys. Chem. Soc., 31. 688, 1899 ; L. Pauling, Zeit. Krist., 72. 490, 1930 ; W. Peters, Ber., 42. 4829, 1909 ; Zeit. anorg. Chem., 11. 178, 1912 ; H. Topsoe, Danske Selsk. Forh., 15O, 1868 ; Arch. Sciences Geneve, (2), 35. 58, 1869 ; (2), 45. 223, 1872. 3 « I. Bellucei, AtU Accad. Bincei, (5), 11. ii, 241, 274, 1902 ; Gazz. Chim. IUd., 88. i, 145, 1903 ; M. Blondel. Ann. Chim. Phys., (8), 6. 81, 1905 ; M. Boll, Compt. Rend., 156. 138, 1913; P. T. Cleve, Bull. Soc. Chim., (2), 21. 118, 197, 247, 345, 1874 ; (2), 43. 162, 359, 1885 ; Compt. Rend., 91. 427, 1880 ; 97. 94, 1883 ; Zett. anorg. Chem., 32. 129, 1902 ; J. W. Dobereiner, Pogg. Ann., 28. 180, 1833 ; F. A. Genth, Biebig's Ann., 80. 276, 1851 ; Nordamerikan Monatsber., 2. 8, 1851 ; J. F. W. Herschel, Phil. Mag., (3), 1. 58, 1832 ; W. Hittorf and H. Salkowsky, Zeit. phys. Chem., 28. 548, 1899 ; I. Jacobsen, Compt. Rend., 149. 755, 1909; S. M. Jorgensen, Journ. prakt. Chem., (2), 16. 345, 1877; (2), 25. 407, 1882; (2), 46. 226, 1892 ; E. Johannsen, IAebig's Ann., 155. 208, 187O ; P. Klason, Ber., 28. 1484,
PLATINUM 347 1895 ; A. Miolati, Zeit. anorrj. Chem., 22.445, 190O ; A. Miolati and I. Bellucci, Atti Accad. Lincei, (5), 9. 51, 97, 1900 ; Oazz. Chim. Ital., 30. ii, 567, 19OO ; Zeit. anorg. Chem., 26. 209, 1901 ; 83. 258, 1903 ; A. Miolati and XJ. Pendini, ib., 33. 264, 1903 ; S. A. Norton, Journ. prakt. Chem , (2), 2. 469, 1870 ; (2), 5. 365, 1872 ; L. Pigeon, Ann. Chim. Phys., (7), 2. 433, 1894 ; W. Pullinger, Journ. Chem. Soc., 61. 422, 1892 ; F. Roiff, Zeit. anorg. Chem., 208. 321, 1832 ; A. Rosenheim and W. Lowenstamm, ib., 37. 404, 1803 ; O. Ruff and W. Jeroch, Ber., 46. 925, 1913 ; L.. N. Vauquelin, Ann. Chim. Phys., (2), 5. 264, 1817 ; Ann. Phil., 12. 28, 1878 ; G. Vortmann, Monatsh., 6. 436, 1885 ; G. Vortmann and O. Blasberg, Ber., 22. 2654, 1889 ; F. Weiss and F. Doboreiner, Liebig's Ann., 14. 18, 1835. 87 E. Davy, Phil. Trans., 107. 136, 1817 ; Ann. Phil., 7. 468, 1816 ; 9. 229, 1817 ; Quart. Journ. Science, 3. 131, 1817; Phil. Mag., (1), 49. 146, 1817 ; Schueigger's Journ., 19. 91, 1816; J. W. Dobereiner, Gilbert's Ann., 72. 194, 1822 ; A. F. de Fourcroy and L. N. Vauquelin, Gehlen's Juurn., 1. 348, 1806 ; Ann. Chim. Phys., (1), 48. 177, 1803 ; F. von Meyer, Journ. prakt. Chem., (2), 18. 305, 1878 ; J. L. Proust, Ann. Chim. Phys., (1), 49. 177, 1804 ; Oehlen's Journ., 1. 347, 1806. § 23. The Platinum Ammines The platinum ammines are here arranged as in the analogous cases of the chromic and cobaltic ammines. There is a long list in the Platiake of W. Loewenstein in L. Gmelin and K. Kraut, Handbuch der anorganischen Ch&mie (Heidelberg, 5. iii, 429, 1915). F. Reitzenstein, 1 and I. 1. TscherniaefE studied the complex salts. For the complexes with platinum monochloride, vide supra. The mechanism of the linkage of the co-ordinated molecules with the central atom of the nucleus has not been fully explained. In one version of the electronic theory, the linkage is attributed to the transfer of a pair of electrons by each co-ordinated molecule as donor. This furnishes an outer ring or shell of electrons exceeding the stable octet. Kings or shells with 12 and 18 electrons are assumed to form stable rings or shells in complexes in which the co-ordination number is 6 or 8. To overcome the difficulty, some of the linkages formed by the electrons are assumed to be singlets ; or else they are attributed to dijjole valency, thus, in a compound of the type [M(NH3)TOjX„, the negative charge on the electrons will be greatest at the corners of the usual octet, and -weakest at the centres of the faces of the corresponding cube since the positive charge of the central atom will there be greatest. In other words, the central atom will be surrounded by an electric field with six positive poles corresponding with the faces of the cube—Fig. 87. Tetrahedron — 4 Octahedron — 6 Cube — 8 iT/as. 87 to 89.—Arrangement for Molecules with Co-ordination Numbers, 4, 6, and 8. Consequently, when the central atom is approached by a dipole molecule, like water or ammonia, the negative portion—oxygen or nitrogen as the case may be —is attached to one of the six mid-points of the faces of the cube—dotted in Fig. 88--so that the six molecules will be arranged about the central atom at the corners of a regular octahedron. As previously indicated, P. Stoll (1926;, and R. W. G. WyckofE (1931), have shown that in the crystal lattices of compounds like K2[PtCl6], Rb2[PdBr6], [Ni(NHa)6]Cl2, [Co(NHg)6]I3, and (NH4)2[SiF6J, the ammonia molecules or the halogen atoms in the square brackets are arranged at the corners of an octahedron surrounding the central atom. This shows the origin of the co-ordination number 6. In this co-ordination, the " neutral " molecules are attached by the negative portions to the positive surface of the central atom. The electrical field is concentrated in the " neutral " molecules so that the electronegative X-atoms
Page 1 and 2:
A COMPREHENSIVE TREATISE ON INORGAN
Page 3 and 4:
A COMPREHENSIVE TREATISE ON INORGAN
Page 5:
PREFACE THE publication of this, th
Page 9 and 10:
AB BRE VIATIONS • aq. -• aqueou
Page 11 and 12:
CHAPTER LXXIV PLATINUM § 1. The Hi
Page 13 and 14:
PLATINUM 3 resembled the white meta
Page 15 and 16:
PLATINUM 5 § 2. The Occurrence of
Page 17 and 18:
PLATINUM i The platinum and iridosm
Page 19 and 20:
PLATINUM 9 few places where its pre
Page 21 and 22:
PLATINUM 11 of platinum have been n
Page 23 and 24:
PLATINUM 13 platinum was reported b
Page 25 and 26:
Russia. Colombia Borneo United Stat
Page 27 and 28:
PLATINUM 17 Fogg. Ann., 34. 379, 18
Page 29 and 30:
PLATINUM 19 1834 ; Journ. prakt. Ch
Page 31 and 32:
PLATINUM 21 U.S. Oeol. Sur., 64, 18
Page 33 and 34:
PLATINUM 23 centrates, 90 per cent,
Page 35 and 36:
PLATINUM 25 the electric smelting o
Page 37 and 38:
PLATINUM 27 mixed iridium and plati
Page 39 and 40:
PLATINUM 29 sulphide ores. The drie
Page 41 and 42:
PLATINUM 31 and the filtrate is tre
Page 43 and 44:
PLATINUM 33 • R. A. Cooper and F.
Page 45 and 46:
PLATINUM 35 and K. A. Dologoff, Jou
Page 47 and 48:
PLATINUM 37 with hydrochloric acid
Page 49 and 50:
PLATINUM 39 sodium dioxide ; the co
Page 51 and 52:
PLATINUM 41 present, may persist fo
Page 53 and 54:
PLATINUM 43 by filtration of the ho
Page 55 and 56:
PLATINUM 45 is not likely to contai
Page 57 and 58:
PLATINUM 47 •were also devised by
Page 59 and 60:
PLATINUM 49 zation "were made. O. L
Page 61 and 62:
PLATINUM 51 platinio chloride disso
Page 63 and 64:
PLATINUM 53 22. 57, 1898 ; A. Gerha
Page 65 and 66:
PLATINUM 55 soln. F. Henrich examin
Page 67 and 68:
PLATINUM 57 hydrogen is oxidized to
Page 69 and 70:
PLATINUM 59 KoIl. Zeit., 1. 162, 19
Page 71 and 72:
PLATINUM 61 by the decomposition of
Page 73 and 74:
PLATINUM 63 hammered metal ; P. Mus
Page 75 and 76:
PLATINUM 65 respectively, 17,021, a
Page 77 and 78:
PLATINUM 67 C. E. Guye and H. Schap
Page 79 and 80:
PLATINUM 69 Acta, 4. 3, 1931 ; H. J
Page 81 and 82:
PLATINUM 71 10-5 ; E. Becquerel, 7-
Page 83 and 84:
PLATINUM 73 of magnesite by the oxy
Page 85 and 86:
PLATINUM 75 after the twentieth ign
Page 87 and 88:
PLATINUM 77 1 J. P. Andrews, Phil.
Page 89 and 90:
PLATINUM 79 F. R. Caldwell and H. T
Page 91 and 92:
PLATINUM 81 Observations were also
Page 93 and 94:
PLATINUM 83 E. Ii. Nichols investig
Page 95 and 96:
PLATINUM 85 G. T. Globe, P. Joye, G
Page 97 and 98:
PLATINUM 87 metal in two forms, fir
Page 99 and 100:
PLATINUM 89 increases ; but for fil
Page 101 and 102:
PLATINUM 91 F. Ehrenhaft, Phys. Zei
Page 103 and 104:
PLATINUM 93 Spectres electriques, P
Page 105 and 106:
PLATINUM 95 Ann. Phys., (5), 6. 391
Page 107 and 108:
PLATINUM 97 Sowjetunion, 5. 645, 19
Page 109 and 110:
PLATINUM 99 Li. C. van Atta, R. S.
Page 111 and 112:
PL.ATINUM 101 S. Bidwell studied th
Page 113 and 114:
PLATINUM 103 against a soln. of sod
Page 115 and 116:
PLATINUM 105 and the platinoplatini
Page 117 and 118:
PLATINUM 107 W. Beetz found the rel
Page 119 and 120:
PLATINUM 109 and V. N. Uspenskaya,
Page 121 and 122:
PLATINUM 111 of chlorine in hydroch
Page 123 and 124:
PLATINUM 113 then more slowly, reac
Page 125 and 126:
PLATINUM 115 affect the optical pro
Page 127 and 128:
PLATINUM 117 per sq. cm., and the c
Page 129 and 130:
PLATINUM 119 platinum to the cold m
Page 131 and 132:
PLATINUM 121 K. Noll, 0-37 ; W. H.
Page 133 and 134:
PLATINUM 123 Observations on the ma
Page 135 and 136:
PLATINUM 125 (4), 42. 150, 1871 ; W
Page 137 and 138:
PLATINUM 127 Zeit. phys. Chem., 4.
Page 139 and 140:
PLATINUM 129 trockenen festen Elekt
Page 141 and 142:
PLATINUM 131 F.. 1. Spitalsky and V
Page 143 and 144:
PLATINUM 133 durch Elektrolyse, Han
Page 145 and 146:
PLATINUM 135 Rev. MU., 7. 348, 1910
Page 147 and 148:
H8 3-65 8-65 PLATINUM 137 and hydro
Page 149 and 150:
PLATINUM 139 Fig. 18. A. Sieverts a
Page 151 and 152:
PLATINUM 141 by formaldehyde. The a
Page 153 and 154:
PLATINUM 143 platinum, and hence in
Page 155 and 156:
20° Oil O PLATIlTOM 145 of oxygen,
Page 157 and 158:
PLATINUM 147 gas, by J. Bischof, 6
Page 159 and 160:
PLATINUM 149 dioxide. R. Wright and
Page 161 and 162:
PLATINUM 151 aq. soln. of chloric a
Page 163 and 164:
PLATINUM 153 (ii) The condensed fil
Page 165 and 166:
PLATINUM 155 mediate compound forme
Page 167 and 168:
PLATINUM 157 exposure to sulphuric
Page 169 and 170:
PLATINUM 159 G. M. Schwab and H. Sc
Page 171 and 172:
PLATINUM 161 num. at 200°. O. J. W
Page 173 and 174:
PLATINUM 163 observed that in a mix
Page 175 and 176:
PLATINUM 165 E. C. "Phillips, P. Sa
Page 177 and 178:
PLATINUM 167 fumaric acid, and redu
Page 179 and 180:
PLATINUM 169 diminishes the resista
Page 181 and 182:
PLATINUM 171 studied the reduction
Page 183 and 184:
PLATINUM 173 resorcinol soln., redu
Page 185 and 186:
PLATINUM 175 Akad. Wien, 104. 1171,
Page 187 and 188:
PLATINUM 177 A. L. Ferguson and G.
Page 189 and 190:
PLATINUM 179 H. G. Tanner and G. B.
Page 191 and 192:
PLATINUM 181 39. 25, 1904 ; F. Weig
Page 193 and 194:
PLATINUM 183 E. Mitseherlich, Pogg.
Page 195 and 196:
PLATINUM 185 strong and T. P. Hildi
Page 197 and 198:
PLATINUM 209, 1933; C. F. Schonbein
Page 199 and 200:
PLATINUM 189 prakt. Chem., (1), 17.
Page 201 and 202:
PLATINUM 191 and examples were also
Page 203 and 204:
PLATINUM 193 16. 357, 1877 ; (2), 2
Page 205 and 206:
PLATINUM 195 K. Honda and T. Ishiga
Page 207 and 208:
PLATINUM 197 he assumed that the in
Page 209 and 210:
^55 ^S so -SJ 40 § ^ 35 PLATINUM 1
Page 211 and 212:
PLATINUM K. Hradecky observed that
Page 213 and 214:
PLATINUM 203 of platinum, from 1000
Page 215 and 216:
PLATINUM 205 susceptibility, in Fig
Page 217 and 218:
PLATINUM 207 T. Cooper prepared a p
Page 219 and 220:
PLATINUM 209 of a portion of the su
Page 221 and 222:
PLATINUM 211 •which are easily po
Page 223 and 224:
PLATINUM 213 or g=O-O38360+O-O52536
Page 225 and 226:
PLATINUM 215 by exposure to air ; a
Page 227 and 228:
PLATINUM 217 soln. are formed. E. I
Page 229 and 230:
PLATINTJM alloyed with a small prop
Page 231 and 232:
PLATINUM 221 platinum-ruthenium all
Page 233 and 234:
PLATINUM 223 A. TJ. Day and R. B. S
Page 235 and 236:
PLATINUM 225 A. Sieverts and co-wor
Page 237 and 238:
PL.ATINUM 227 and H. Gonnington, th
Page 239 and 240:
PLATINUM 229 REFEBBNCBS. 1 A. Brest
Page 241 and 242:
PLATINUM 231 O. Fromra, Ber., 27. 6
Page 243 and 244:
PLATINUM Zeit. phys. Chem., 67. 672
Page 245 and 246:
PLATINUM 235 § 17. The Lower Oxide
Page 247 and 248:
PLATINUM 237 IJ. Mond and co-worker
Page 249 and 250:
PLATINUM 239 H. Alexander prepared
Page 251 and 252:
PLATINUM 241 of hydrates, as !L. Wo
Page 253 and 254:
PLATINUM 243 platinic chloride ; C.
Page 255 and 256:
PLATINUM 245 and, better still, pot
Page 257 and 258:
PLATINUM 247 metallic platinum and
Page 259 and 260:
PLATINUM 249 Ze.it. phya. Chem., 28
Page 261 and 262:
PLATINUM 251 § 21. Platinum Mono-,
Page 263 and 264:
PLATINUM 253 and L. T. Bourland fou
Page 265 and 266:
PLATINUM 255 oxide. The chloroplati
Page 267 and 268:
PLATINUM 257 and the adsorption of
Page 269 and 270:
PLATINUM presence of a large excess
Page 271 and 272:
PLATINUM the cold soln. from the pl
Page 273 and 274:
PLATINUM 263 more soluble than is t
Page 275 and 276:
PLATINUM 265 cis-salt into the tetr
Page 277 and 278:
PLATINUM 267 platinous nitrosodichl
Page 279 and 280:
PLATINUM hydrochloric acid, and tre
Page 281 and 282:
PLATINUM 271 chloride, [Ptpyn4]Cla.
Page 283 and 284:
PLATINUM 273 platlnous propylenedla
Page 285 and 286:
PLATINUM 275 with chloroform, descr
Page 287 and 288:
PLATINUM 277 trans- and cis-forms ;
Page 289 and 290:
PLATINUM 279 sulphite to a soln. of
Page 291 and 292:
PLATINUM 281 platinic acid to hydro
Page 293 and 294:
PLATINUM 283 The ruby-red, rhombohe
Page 295 and 296:
PLATINUM 285 also obtained. A. Wern
Page 297 and 298:
PLATINUM 287 REFERENCES. 1 M. C. Le
Page 299 and 300:
PLATINUM 289 and G. H. Wyatt, ib.,
Page 301 and 302:
PLATINUM 291 Bend., 161. 563, 1916
Page 303 and 304:
PLATINUM 293 hydrate at 215° in va
Page 305 and 306: PLATINUM 295 and K. Meyer studied t
Page 307 and 308: PLATINUM 297 brown coloration, prod
Page 309 and 310: PLATINUM 299 heirn and W. Levy obse
Page 311 and 312: PLATINUM 301 Dam observed that a dr
Page 313 and 314: PLATINUM 303 platinum is warmed wit
Page 315 and 316: PLATINUM 305 redaction proceeds ver
Page 317 and 318: PLATINUM 307 minochloroplatinite in
Page 319 and 320: PLATINUM 309 soluble in water ; and
Page 321 and 322: PLATINUM 311 W. Rudneff, A. Hies, a
Page 323 and 324: PLATINUM 313 F. W. O. de Coninck, H
Page 325 and 326: PLATINUM 315 Imidoazolyl-zi-mereapt
Page 327 and 328: PLATINUM 317 yellow colour is produ
Page 329 and 330: PLATINUM 319 and found that the X-r
Page 331 and 332: PLATINUM 321 when the salt is reduc
Page 333 and 334: PLATINUM 323 1OO grms. of soln., at
Page 335 and 336: PLATINUM 325 According to Li. N. Va
Page 337 and 338: PLATINUM 327 Ag2PtCl6, by melting s
Page 339 and 340: PLATINUM 329 two component chloride
Page 341 and 342: PLATINUM 331 tetramminochloroplatin
Page 343 and 344: PLATINUM 333 M. Slondel also obtain
Page 345 and 346: PLATINUM 335 to a cold, cone. soln.
Page 347 and 348: PLATINUM 337 insufficient quantity
Page 349 and 350: PLATINUM 339 AUi Accad. Lincei, (5)
Page 351 and 352: PLATINUM 341 Platinbasen, Konigsber
Page 353 and 354: PLATINUM 343 Zeit. Kryst., 14. 141,
Page 355: PLATINUM 345 15. 130, 1897 ; A. Wer
Page 359 and 360: PLATINUM 349 where • denotes the
Page 361 and 362: PLATINUM 351 (xiii) Quaterbutylamin
Page 363 and 364: PLATINUM 353 (lix) Bispropylatnined
Page 365 and 366: PLATINUM 355 (xv) Chlorotrimethylsu
Page 367 and 368: PLATINUM 357 (xxxix) Bisdiethylsulp
Page 369 and 370: PLATINUM 359 the potassium salt ; (
Page 371 and 372: PLATINUM 361 (x) Oxymesityls, [Pt(C
Page 373 and 374: PLATINUM 363 (xii) Diiodotetrammine
Page 375 and 376: PLATINUM 365 (xxiii) Dichlorontirit
Page 377 and 378: (liv) (Iv) (lvi) (lvii) (lviii) (li
Page 379 and 380: PLATINUM 369 (vii) Pentachlorodimet
Page 381 and 382: PLATINUM 371 mass by water, a littl
Page 383 and 384: PLATINUM 373 bromic acid, and cryst
Page 385 and 386: PLATINUM 375 is eliminated at a low
Page 387 and 388: PLATINUM 377 of platinous bromide a
Page 389 and 390: PLATINUM 379 H. Topsoe prepared cop
Page 391 and 392: PLATINUM 381 of sodium hydroxide in
Page 393 and 394: PLATINUM 383 dichlorodibromobisamid
Page 395 and 396: PLATINUM 385 the action of dry ammo
Page 397 and 398: PLATINUM 387 4©. 2585, 1907 ; .Ze*
Page 399 and 400: PLATINUM 389 colours the salt orang
Page 401 and 402: PLATINUM 391 acid. The trigonal cry
Page 403 and 404: PLATINUM 393 Bindefestigkeit der ne
Page 405 and 406: PLATINUM 395 absence of air, the so
Page 407 and 408:
PLATINUM 397 product is then washed
Page 409 and 410:
PIiATINUM 399 platinum black. The p
Page 411 and 412:
PLATINUM 401 tetramminosulphate, an
Page 413 and 414:
PLATINUM 403 hydroxytetramminosulph
Page 415 and 416:
PLATINUM 405 tion of brown flecks,
Page 417 and 418:
PLATINUM 407 »1. L>elepine, Compt.
Page 419 and 420:
PLATINUM 409 of ammonium carbonate
Page 421 and 422:
PLATINUM 411 soln. of platinic nitr
Page 423 and 424:
PLATINUM 413 and "when the mixture
Page 425 and 426:
PLATINUM 415 P. T. CIeve, E. A. Had
Page 427:
PLATINUM 417 H2PO4.2H2O, to be form
Page 430 and 431:
420 GENERAL INDEX Acqua toff ana, 9
Page 432 and 433:
422 GENERAL, INDEX Allactite, 9. 4,
Page 434 and 435:
424 Aluminium dimetasilicate ammoni
Page 436 and 437:
426 GENERAL, INDEX Aluminium-sodium
Page 438 and 439:
428 GENERAL, INDEX Ammonium amidose
Page 440 and 441:
43O Ammonium chromic selenate, 10.
Page 442 and 443:
432 GENERAL, INDEX Ammonium, diphos
Page 444 and 445:
434 GENERAL, INDEX Ammonium hydroxy
Page 446 and 447:
436 GENERAL, INDEX Ammonium nickel
Page 448 and 449:
438 GENERAL, INDEX Ammonium potassi
Page 450 and 451:
440 GENERAL, INDEX Ammonium tetrava
Page 452 and 453:
442 GENERAL INDEX Amphoteric oxides
Page 454 and 455:
444 GENERAIL, INDEX Antimony fluoni
Page 456 and 457:
446 GENERAL, INDEX Arcanum duplicat
Page 458 and 459:
448 GENERAL, INDEX Arsenic white, 9
Page 460 and 461:
450 Aureus bromide, 3. 605, 606 bro
Page 462 and 463:
452 GENERAL, INDEX Barium chloride
Page 464 and 465:
454 Barium lead calcium fluoboryl d
Page 466 and 467:
456 Barium salts, catalysis by, 1.
Page 468 and 469:
458 GENERA Bayldonite, 7. 491 ; 9.
Page 470 and 471:
46O GENERAL, INDEX Beryllium perehl
Page 472 and 473:
462 GENERAL, INDEX Bismuth nitrate
Page 474 and 475:
464 GENERAL INDEX Bleischweiff, 7.
Page 476 and 477:
466 GENERAL INDEX Bose's swarm theo
Page 478 and 479:
468 Butyl tetraehloroforrate, 14. 1
Page 480 and 481:
470 GENERAL INDEX Cadmium hexadecab
Page 482 and 483:
472 GENERAL. Cadmium tetramminobrom
Page 484 and 485:
474 GENERAL, INDEX Caesium hydroxyp
Page 486 and 487:
476 GENERAL, INDEX Cainosite, 5. 51
Page 488 and 489:
478 GENERAL, INDEX Calcium dihydrop
Page 490 and 491:
480 GENERAL, INDEX Calcium metaplum
Page 492 and 493:
482 GENERAL INDEX Calcium sodium ma
Page 494 and 495:
484 Caporeianite, 6. 738 soda, 6. 7
Page 496 and 497:
486 GENERAL, INDEX Cathode, 1. 03 r
Page 498 and 499:
488 GENERAL, INDEX Cerous hydrosulp
Page 500 and 501:
49O GENERAL INDEX Cbloridizing roas
Page 502 and 503:
492 GENERAL INDEX Chromic ca.rbaTni
Page 504 and 505:
494 GENERAL, INDEX Chromic hoxacarb
Page 506 and 507:
496 GENERAL INDEX Chromic sulphate
Page 508 and 509:
498 GENERAL, INDEX Chromium monopho
Page 510 and 511:
500 GENERAL, INDEX Chrysitine, 7. 6
Page 512 and 513:
502 GENERAL, INDEX Cobalt e?>-dinit
Page 514 and 515:
504 GENERAL INDEX Cobalt potassium
Page 516 and 517:
506 GENERAL INDEX Cobaltic aquomtri
Page 518 and 519:
608 GENERAL, INDEX Cobaltic brornob
Page 520 and 521:
510 GENERAL, INDEX Cobalt ic chloro
Page 522 and 523:
U- INDEX 512 GBNERi Cobaltic trans-
Page 524 and 525:
514 GENERAL INDEX Co bait ic dinitr
Page 526 and 527:
516 Cobaltic hydronitritoimidoctamm
Page 528 and 529:
518 GENERAL, INDEX Cobaltic mercuri
Page 530 and 531:
52O GENERAL, INDEX Cobaltic phospha
Page 532 and 533:
522 GENERAL, INDEX Co foal tic tric
Page 534 and 535:
524 (Jobaltous decamminoiodide, 14.
Page 536 and 537:
526 GENERAL INDEX Cobaltyl sodium s
Page 538 and 539:
528 GENERAL, INDEX "Cookeite, 2. 42
Page 540 and 541:
53O GENERAL, INDEX Copper hexahydro
Page 542 and 543:
532 GENERAL INDEX Copper potassium
Page 544 and 545:
AX, INDEX 534 GENER. Copper ionic h
Page 546 and 547:
536 GENERAL INDEX Cupric dihydrotet
Page 548 and 549:
538 GENERAL INDEX Cuprosic sodium t
Page 550 and 551:
540 GEISTER^ Cuprous triamminochlor
Page 552 and 553:
542 GENERAL, INDEX Diaquobisethylen
Page 554 and 555:
544 GENERAL. INDEX Dihydroxytetraio
Page 556 and 557:
54:6 GENERAL INDEX Diuranyl ammoniu
Page 558 and 559:
548 GENERAL INDEX Electrical discha
Page 560 and 561:
550 GENERAL Erbium, 5. 696 ammonium
Page 562 and 563:
552 GENERAL, I]STDEX F Facellite, 6
Page 564 and 565:
554 GENERAT, INDEX Ferric felspar,
Page 566 and 567:
556 GENERAL INDEX Ferric sodium hyd
Page 568 and 569:
558 GENERAL , INDEX Ferrous chlorat
Page 570 and 571:
56O GENERAL INDEX Ferrous rubidium
Page 572 and 573:
562 Fluorine action chlorine, 2. 11
Page 574 and 575:
564 GENERAL, INDEX Gadolinium nitra
Page 576 and 577:
see Germanomolybdic acid, 11. 605 G
Page 578 and 579:
568 GENERAL INDEX Gold nickel palla
Page 580 and 581:
57O GENERAL INDEX Gun metals, 7. 34
Page 582 and 583:
572 GENERAL, INDEX Hepatopyrites, 1
Page 584 and 585:
574 Hydrates, 1. 397, 498 chemical,
Page 586 and 587:
576 GENERAL. INDEX Hydrogen chlorob
Page 588 and 589:
578 GENERAI. INDEX Hydrogen peroxid
Page 590 and 591:
580 GENERAL INDEX Hydroxylamine iso
Page 592 and 593:
582 GENERAL INDEX Indium chloroplat
Page 594 and 595:
584 GENERA] Iridic sulphate, 15. 78
Page 596 and 597:
586 GENERAL, INDEX Iridoua hydroxid
Page 598 and 599:
588 GENERAL INDEX Iron germanium al
Page 600 and 601:
59O GENERAL, INDEX Iron, reactions
Page 602 and 603:
592 GENERAL Jacinta la bella, 6. 71
Page 604 and 605:
594 GENERAL INDEX KoM, 9. 341 Kohle
Page 606 and 607:
596 GENERAL, INDEX (hexa)lanthanum
Page 608 and 609:
598 GENERAL INDEX Lead, cobaltic tr
Page 610 and 611:
600 GENERAL INDEX Lead hydrazine th
Page 612 and 613:
602 GENERi Lead platinum alloys, 16
Page 614 and 615:
604 GENERAL INDEX (hexa)lead- tetra
Page 616 and 617:
606 GENERAL INDEX Lithium bromobisa
Page 618 and 619:
608 GENERAL INDEX Lithium platinum
Page 620 and 621:
6IO GENBRAT, INDEX Magalaea sitiens
Page 622 and 623:
612 GENERAL, INDEX Magnesium diboro
Page 624 and 625:
614 Magnesium periodate, 2. 414 per
Page 626 and 627:
616 GENERAL, INDEX Magnetism, 18. 2
Page 628 and 629:
618 GENERAL, INDEX Manganese hydroa
Page 630 and 631:
620 GENERAL, INDEX Manganic ammoniu
Page 632 and 633:
622 GENERAL INDEX ManganouR hydro x
Page 634 and 635:
624 GENERAL, INDEX Masrite, 12. 530
Page 636 and 637:
626 GENEKAL INDEX Mercuric calcium
Page 638 and 639:
628 Mercuric iodotrisulphate, 4. 97
Page 640 and 641:
63O GENERAL, INDEX Mercuric tetramm
Page 642 and 643:
632 GENERAL INDEX Mercurous selenat
Page 644 and 645:
634 Metals, influence of planets on
Page 646 and 647:
636 GENERAL, INDEX Mineral yellow,
Page 648 and 649:
638 GENERAL INDEX Molybdenum iron a
Page 650 and 651:
64O GENERAL INDEX Monometaphoaphate
Page 652 and 653:
642 GENERAL, INDEX Neon, properties
Page 654 and 655:
644 GENERAL, INDEX Nickel copper co
Page 656 and 657:
646 Nickel metantimonate hexahydrat
Page 658 and 659:
648 Nickel tetramminodinitrite, 8.
Page 660 and 661:
65O Nigrica fabilis, 5. 713 Nigrine
Page 662 and 663:
652 GENERAL INDEX Nitroxan, 8. 212
Page 664 and 665:
654 GENERAL. INDEX Orthochromic aci
Page 666 and 667:
656 GENERAL, INDEX Oxyacids of chlo
Page 668 and 669:
658 Oxygen action sulphur trioxide,
Page 670 and 671:
66O OENEKAIi INDEX Fallacious diars
Page 672 and 673:
662 GENBRAI Ci INDEX Parameters top
Page 674 and 675:
664 GEJNERAL, Permanganous molybdat
Page 676 and 677:
666 GENERAL, INDEX Phosphon yellow
Page 678 and 679:
668 GENERAL, INDEX Phototropic reac
Page 680 and 681:
670 GENERAL, INDEX Platinio bisethy
Page 682 and 683:
672 GENERAL INDEX !Platinic brornon
Page 684 and 685:
674 Pla.tin.ic diiodobispyridinedia
Page 686 and 687:
676 GENERAL. INDEX Platinic tetrach
Page 688 and 689:
678 GENERAL, Platinous bis-a-amidop
Page 690 and 691:
680 GBNEKAL INDEX Platinous bisprop
Page 692 and 693:
682 GENERAL, INDEX Platinous diammi
Page 694 and 695:
684 GENERAL Platinous diohloroethyl
Page 696 and 697:
686 GENERAL. Platinous dithiophenyl
Page 698 and 699:
Platinous pr opy lenediaminodiammin
Page 700 and 701:
690 Flatinous tetramminooarbonate,
Page 702 and 703:
692 GENERAL INDEX Platinum films, 1
Page 704 and 705:
694 GENERAL INDEX Plumbic hexoxydis
Page 706 and 707:
696 GENERAL INDEX Potassium ammoniu
Page 708 and 709:
698 GENERAL, INDEX Potassium cerous
Page 710 and 711:
700 GENERAL INDEX Potassium dibromo
Page 712 and 713:
702 GENERAL INDEX Potassium ferrous
Page 714 and 715:
704 GENERAL INDEX Potassium iodoper
Page 716 and 717:
706 GENERAL, INDEX Potassium molybd
Page 718 and 719:
708 GENERAL Potassium perdiborate,
Page 720 and 721:
71O GENEKAL, INDEX Potassium stront
Page 722 and 723:
712 GENERAL, INDEX Potassium trimol
Page 724 and 725:
714 GENERAL INDEX Praseodymium fluo
Page 726 and 727:
716 GBNBRAJ \ INDEX Pyridine molyfo
Page 728 and 729:
718 GENERAL, INDEX Radium azide, 4.
Page 730 and 731:
720 GENERAL INDEX Rhaphilite, 6. 82
Page 732 and 733:
722 GENERAL INDEX Rhodium tricarbon
Page 734 and 735:
724 GENERAL INDEX Rubidium cuprous
Page 736 and 737:
726 Rubidium pyridinetriehloroplati
Page 738 and 739:
728 GENERAL, INDEX Ruthenium nitros
Page 740 and 741:
730 GENERAL, INDEX Samarous chlorid
Page 742 and 743:
732 GENERAL. INDEX Selenatouranic a
Page 744 and 745:
734 GENERAL INDEX Silia X-radiogram
Page 746 and 747:
736 GENEBAL INDEX Silver amminofluo
Page 748 and 749:
738 GENERAL, INDEX Silver fluotitan
Page 750 and 751:
740 GENERAL INDEX Silver phosphatoh
Page 752 and 753:
742 GENERAL, INDEX (hepta)silver te
Page 754 and 755:
744: GENERAL INDEX Sodium ammonium
Page 756 and 757:
746 Sodium chlorosmate, 15. 72O chl
Page 758 and 759:
748 GENERAL INDEX Sodium dioxytetra
Page 760 and 761:
750 GENERAL, Sodium hydroxide purif
Page 762 and 763:
752 GENERAL, Sodium nickelous hexam
Page 764 and 765:
754 Sodium praeodymium electrolytic
Page 766 and 767:
756 Sodium thiosulphate pentahy dra
Page 768 and 769:
758 GENERAL INDEX Solubility ion. t
Page 770 and 771:
76O GENERAL INDEX Spraying, Scoop's
Page 772 and 773:
762 GENERAL, INDEX Stannous nickel
Page 774 and 775:
764 GENERAL INDEX Strcmtia labrador
Page 776 and 777:
766 GENERAL INDEX Strontium nitride
Page 778 and 779:
768 GENERAL INDEX Sulphates, acid,
Page 780 and 781:
770 GENERAL INDEX Sulphuryl halides
Page 782 and 783:
772 GENERAL. INDEX Telgstein, 6. 42
Page 784 and 785:
774 GENERAL INDEX Tetramethylammoni
Page 786 and 787:
776 GENERAIi INDEX Thallochabazite,
Page 788 and 789:
778 GENEKAL Thallous triamminoiodid
Page 790 and 791:
780 GENERAL INDEX Thorium lead, 7.
Page 792 and 793:
782 GENEBAIi INDEX Tin manganeside,
Page 794 and 795:
784 GENERAL INDEX Titanium sulphoch
Page 796 and 797:
786 GENERAL INDEX Triethoxymonosila
Page 798 and 799:
788 Tungsten fluorides, 11. 837 gol
Page 800 and 801:
79O GENERAL Undercooling, 1. 450 (J
Page 802 and 803:
792 GENERAL INDEX Uranous hexoxytet
Page 804 and 805:
794 Uranyl salts, 12. 6O selenate,
Page 806 and 807:
796 GENERAL INDEX Vanadium oxydifor
Page 808 and 809:
798 Vitriolstein, 10. 351 Vitriolum
Page 810 and 811:
800 GENERAL Wavellite, pseudo-, 5.
Page 812 and 813:
802 GENERAL INDEX Youngite, 7. 797
Page 814 and 815:
804 GENERAL INDEX Zinc azide basic,
Page 816 and 817:
806 Zinc hydrotetrathionate, 10. 61
Page 818 and 819:
808 GENERAL Zinc properties, physic
Page 820 and 821:
810 GENERAL INDEX Zirconium analyti
Page 822:
PRINTED IN ENGLAND BY WTLLIAM CLOWE
show all

A Comprehensive Treatise on Inorganic and Theoretical Chemistry

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?