CHEM02200704003 Nilamadhab Pandhy - Homi Bhabha National ...

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Chapter 4 The chromium, and oxygen profile for 304L SS passivated in 0.6 M nitric acid are shown in Fig. 4.12a-b. The chromium profile for 304L SS passivated in 0.6 M nitric acid showed the presence of Cr(OH) 3 peak around 577.7 eV, however the intensity was much less as compared to Cr 2 O 3 around 576.8 eV (Fig. 4.12a). Similarly, the oxygen profile for 304L SS passivated in 0.6 M nitric acid also showed peak for Cr(OH) 3 , but the intensity of Cr 2 O 3 peak around 531.1 eV was much higher as compared to Cr(OH) 3 peak (Fig. 4.12b). The chromium, and oxygen profile for 304L SS passivated in 1 M nitric acid are shown in Fig. 4.13a-b. At 1 M nitric acid concentration the peak positions for chromium and oxygen were by and large similar to that of as polished condition. Chromium profile showed the presence of Cr 2 O 3 , and elemental chromium at their characteristics binding energy (Fig. 4.13a). However, no detectable peak for chromium hydroxide was observed in chromium region. The oxygen profile revealed the presence of Fe 2 O 3 , Cr 2 O 3 and presence of Cr(OH) 3 (Fig. 4.13b) at their usual position as seen in case of as polished specimen. Intensity (Arbitrary units) Cr2p 3/2 (0.6 M HNO 3 ) Cr 0 Cr 2 O 3 Cr(OH) 3 580 578 576 574 572 Binding energy (eV) Fig. 4.12a: XPS profile of Cr2p 3/2 of 304L SS passivated in 0.6 M HNO 3 .
Chapter 4 Intensity (Arbitrary units) O1s (0.6 M HNO 3 ) Fe 2 O 3 Cr 2 O 3 Cr(OH) 3 535 534 533 532 531 530 529 528 527 Binding energy (eV) Fig. 4.12b: XPS profile of O1s of 304L SS passivated in 0.6 M HNO 3 . Intensity (Arbitrary units) Cr2p 3/2 (1 M HNO 3 ) Cr 0 Cr 2 O 3 580 578 576 574 572 Binding energy (eV) Fig. 4.13a: XPS profile of Cr2p 3/2 of 304L SS passivated in 1 M HNO 3 .
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2.3 Effect of alloying elements on
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4 C H A P T E R 4 73 # $%&' 4.1 In
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6.2.3.2 Open circuit potential vs.
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eprocessing can be recovered, and c
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The ex-situ study of passive film w
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Fig.3.10: Schematic of electrical e
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Fig.6.11: Polarization study of unc
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AISI: American Institute of Steel I
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Chapter 1 C H A P T E R 1 Spent Nuc
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Chapter 1 1.3 Challenges in spent n
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Chapter 1 corrosion resistance. The
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Chapter 1 choice of zirconium is du
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C H A P T E R2
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Chapter 2 temperature, (c) higher i
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Chapter 2 Chromium in excess of 12
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Chapter 2 2. 3 Effect of alloying e
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Chapter 2 The twins are identified
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Chapter 2 and at temperature around
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Chapter 2 of adsorption of oxygen o
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Chapter 2 transpassive dissolution
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Chapter 2 healing chromium oxide fi
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Chapter 2 their segregation to the
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Chapter 2 is intimately related to
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Chapter 2 in nature because the dis
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C H A P T E R3
Page 58 and 59: Chapter 3 3.1.1.2 Specimen preparat
Page 60 and 61: Chapter 3 ionized. However, differe
Page 62 and 63: Chapter 3 various industrial applic
Page 64 and 65: Chapter 3 In the present investigat
Page 66 and 67: Chapter 3 3.1.3.2 Atomic force micr
Page 68 and 69: Chapter 3 present on the surface fo
Page 70 and 71: Chapter 3 necessary condition is th
Page 72 and 73: Chapter 3 Y m is the sputter yield.
Page 74 and 75: Chapter 3 Fig. 3.7: Schematic of X-
Page 76 and 77: Chapter 3 rate of 10Å/min using 5
Page 78 and 79: Chapter 3 different doses of nitrog
Page 80 and 81: Chapter 3 The modulus of electroche
Page 82 and 83: Chapter 3 equivalent circuit as sho
Page 84 and 85: Chapter 3 reference electrode with
Page 86 and 87: Chapter 3 for understanding the pas
Page 88 and 89: C H A P T E R4
Page 90 and 91: Chapter 4 encountered by all materi
Page 92 and 93: Chapter 4 pitting, and intergranula
Page 94 and 95: Chapter 4 The ridged structure, and
Page 96 and 97: Chapter 4 nitric acid is that the b
Page 98 and 99: Chapter 4 Potential (V) Vs Ag/AgCl
Page 100 and 101: Chapter 4 4.2.3 In-situ electrochem
Page 102 and 103: Chapter 4 The surface morphologies
Page 104 and 105: Chapter 4 a b c d Opening up of gra
Page 106 and 107: Chapter 4 Intensity (Arbitrary unit
Page 110 and 111: Chapter 4 Intensity (Arbitrary unit
Page 112 and 113: C H A P T E R5
Page 114 and 115: Chapter 5 elements, and often impar
Page 116 and 117: Chapter 5 5.2 Results and discussi
Page 118 and 119: Chapter 5 Presence of oxygen is due
Page 120 and 121: Chapter 5 was an increase in marten
Page 122 and 123: Chapter 5 formation of Cr 2 N was a
Page 124 and 125: Chapter 5 electrochemical environme
Page 126 and 127: Chapter 5 N + Dose E corr (mV vs. A
Page 128 and 129: Chapter 5 layer capacitance (C dl )
Page 130 and 131: Chapter 5 correlation between surfa
Page 132 and 133: Chapter 5 boundary dissolution was
Page 134 and 135: Chapter 6 C H A P T E R 6
Page 136 and 137: Chapter 6 193]. As a single phase c
Page 138 and 139: Chapter 6 particles range from 8×1
Page 140 and 141: Chapter 6 Results revealed that in
Page 142 and 143: Chapter 6 The change over from capa
Page 144 and 145: Chapter 6 The impedance parameters
Page 146 and 147: Chapter 6 Conc. Substrate condition
Page 148 and 149: Chapter 6 6.6a-d. The uncoated spec
Page 150 and 151: Chapter 6 (55.18°) respectively, w
Page 152 and 153: Chapter 6 OCP shifted in noble dire
Page 154 and 155: Chapter 6 The high phase angle over
Page 156 and 157: Chapter 6 Fig. 6.10d: Log f vs. Log
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Chapter 6 Fig. 6.11b: Polarization
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Chapter 6 Covalent aspect of lattic
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Chapter 6 As compared to uncoated s
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Chapter 6 6.2.3.2 Open circuit pote
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Chapter 6 Similarly, the plots for
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Chapter 6 for the duplex coating, a
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Chapter 6 Fig.6.16b: Polarization s
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Chapter 6 6.2.3.5 Morphological exa
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Chapter 7 C H A P T E R 7 The cha
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Chapter 7 1. Surface morphology exa
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Chapter 7 6 Duplex Ti-TiO 2 coated
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Chapter 7 EC-SPM study on effect
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[1] Baldev Raj, U. Kamachi Mudali,
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[37] G. Okamoto, T. Shibata, Corros
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[79] M. Moens, M. Van Craen, F.C. A
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[117] R.E.Williford, C.F.Windisch J
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[157] N. Mottu, M. Vayer, R. Erre,
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[197] M. Metikos Hukovic, M. Ceraj
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[19] H. H. Uhlig, Corros Sci, 19 (1
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[57] J. F. Ziegler, J. P. Biersack,
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[97] I. Betova, M. Bojinov, V. Kara
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[139] V. Ashworth, R. P. M. Procter
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[176] G. Frankel, G. Grundmeier, H.
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List of publications 1. Referred
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CHEM02200704003 Nilamadhab Pandhy - Homi Bhabha National ...

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