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Wüest M. 51 Wykes M. 82 Yamaguchi M. 17 Ybarra G. 129 Yubero F ...

Wüest M. 51 Wykes M. 82 Yamaguchi M. 17 Ybarra G. 129 Yubero F ...

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JUNE 28 WEDNESDAY AFTERNOON<br />

JS1-WeA-P.3 OPTICAL CHARACTERIZATION OF VACUUM EVAPORATED<br />

CdZnTe THIN FILMS DEPOSITED BY STACKED LAYER METHOD. G.G. Rusu, M. Rusu,<br />

M. Girtan. Faculty of Physics, “Al.I. Cuza” University, B-dul Carol I, No. 11, Iasi, Romania (e-mail:<br />

rusugxg@uaic.ro)<br />

The interest in the study of CdZnTe (CZT) alloys in thin films has been increased due to their important<br />

applications in technology of thin film devices as solar cells, photo-detectors, gamma-ray detectors,<br />

etc.<br />

Among other preparation techniques of CZT, the physical vapour deposition is often preferred. In<br />

such method, the evaporation of CdTe and ZnTe mixed powder or co-evaporation from dual CdTe<br />

and ZnTe sources are frequently used. An inconvenient of these procedures is the difficulty to control<br />

of Zn content in as evaporated CdZnTe films due to the vapour pressure difference between<br />

CdTe and ZnTe and to the lower sticking coefficient of Zn.<br />

To avoid this inconvenient, in present paper, a modified two source evaporation technique was used<br />

to prepare CdZnTe thin films. Namely, during film deposition, the film substrates, placed onto a rotating<br />

disk, passed successively with constant rate over the CdTe powder and metallic Zn evaporation<br />

sources respectively, separated between them by two glass cylinders. In this way, nanolayered<br />

CdTe/Zn structures with uniform Zn content were deposited. The structural and optical properties of<br />

as deposited CdZnTe films were investigated.<br />

Depending on the preparation conditions, both quasi-amorphous and oriented (111) polycrystalline<br />

films were obtained. Also, depending on Zn content and heat treatment, the value of optical band<br />

gap, E g , for studied films ranged between 1.48 eV and 1.63 eV.<br />

126

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