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Itinerant Spin Dynamics in Structures of ... - Jacobs University

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Appendix C: Cooperon and <strong>Sp<strong>in</strong></strong> Relaxation 139<br />

<strong>in</strong> s<strong>in</strong>glet-triplet representation by us<strong>in</strong>g the transformation U ST ,<br />

⎛ ⎞ ⎛ ⎞ ⎛ ⎞<br />

|⇈〉 |⇄〉 0 √2 1<br />

−√ 1 2<br />

0<br />

|↑↓〉<br />

|⇈〉<br />

1 0 0 0<br />

U ST ≡<br />

⊗<br />

=<br />

, (C.18)<br />

⎜<br />

⎝ |↓↑〉 ⎟ ⎜<br />

⎠ ⎝ |⇉〉 ⎟ ⎜ 1<br />

⎠ ⎝ 0 √2 √2 1<br />

0 ⎟<br />

⎠<br />

|〉 |〉 0 0 0 1<br />

it can be seen that the s<strong>in</strong>glet term has positive contribution to the conductivity <strong>in</strong> contrast<br />

to the triplet terms which have a different sign: Transform<strong>in</strong>g Λ us<strong>in</strong>g U ST we get<br />

⎛ ⎞<br />

−1 0 0 0<br />

U ST ΛU −1<br />

ST = 0 1 0 0<br />

, (C.19)<br />

⎜<br />

⎝ 0 0 1 0 ⎟<br />

⎠<br />

0 0 0 1<br />

where we can immediately extract the signs.<br />

C.2 <strong>Sp<strong>in</strong></strong>-Conserv<strong>in</strong>g Boundary<br />

In the follow<strong>in</strong>g we set γ g = 1. In order to generate a f<strong>in</strong>ite system, we need to<br />

specify the boundary conditions. These can be different for the sp<strong>in</strong> and charge current.<br />

Here we derive the sp<strong>in</strong>-conserv<strong>in</strong>g boundary conditions. Let us first recall the diffusion<br />

current density j at position r as derived from a classical picture <strong>in</strong> Sec.2.3.4, which is given<br />

by<br />

j si (r,t) = 〈vs k i (r,t)〉−D e ∇s i (r,t),<br />

(C.20)<br />

where s k i is the part <strong>of</strong> the sp<strong>in</strong>-density which evolved from the sp<strong>in</strong>-density at r − ∆x<br />

mov<strong>in</strong>g with velocity v and momentum k. Us<strong>in</strong>g the Bloch equation<br />

∂ŝ<br />

∂t = ŝ×B SO(k)− 1ˆτ s<br />

ŝ,<br />

we rewrite the first term <strong>in</strong> Eq.(C.20) yield<strong>in</strong>g the total sp<strong>in</strong>-diffusion current as<br />

(C.21)<br />

j si = −τ〈v F [B SO (k)×S] i<br />

〉−D e ∇s i .<br />

(C.22)<br />

In Sec.3.4.1 we consider specular scatter<strong>in</strong>g from the boundary with the condition that the<br />

sp<strong>in</strong> is conserved, so that the sp<strong>in</strong> current density normal to the boundary must vanish<br />

n·j si | ±W/2 = 0,<br />

(C.23)

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