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Itinerant Spin Dynamics in Structures of ... - Jacobs University

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40 Chapter 3: WL/WAL Crossover and <strong>Sp<strong>in</strong></strong> Relaxation <strong>in</strong> Conf<strong>in</strong>ed Systems<br />

which has its cause <strong>in</strong> the suppression <strong>of</strong> the triplet modes <strong>in</strong> Eq.(3.46), is <strong>in</strong>deed a direct<br />

measure <strong>of</strong> the sp<strong>in</strong> relaxation. Mathematically, there exists a unitary transformation<br />

H c = U CD H SD U † CD, (3.60)<br />

⎛ ⎞<br />

U CD =<br />

⎜<br />

⎝<br />

− 1 √<br />

2<br />

i √<br />

2<br />

0<br />

0 0 1<br />

1√<br />

2<br />

i √<br />

2<br />

0<br />

⎟<br />

⎠ , (3.61)<br />

with the accord<strong>in</strong>g transformation between sp<strong>in</strong>-density components s i and the triplet components<br />

<strong>of</strong> the Cooperon density ˜s,<br />

1<br />

√<br />

2<br />

(−s x +is y ) = ˜s ⇈ , (3.62)<br />

s z = ˜s ⇉ , (3.63)<br />

1<br />

√ (s x +is y ) = ˜s . 2<br />

(3.64)<br />

This is a consequence <strong>of</strong> the fact that the four-component vector <strong>of</strong> charge density ρ =<br />

(ρ + + ρ − )/2 and sp<strong>in</strong>-density vector S are related to the density vector ˆρ with the four<br />

components 〈ψ † αψ β<br />

〉/ √ 2, where α,β = ±, by a unitary transformation.<br />

Relation to the Diffuson<br />

The classical evolution <strong>of</strong> the four-component density vector ˆρ is by def<strong>in</strong>ition<br />

governed by the diffusion operator, the Diffuson. The Diffuson is related to the Cooperon<br />

<strong>in</strong> momentum space by substitut<strong>in</strong>g Q → p−p ′ and the sum <strong>of</strong> the sp<strong>in</strong>s <strong>of</strong> the retarded<br />

and advanced parts, σ and σ ′ , by their difference. Us<strong>in</strong>g this substitution, Eq.(3.48) leads<br />

thus to the <strong>in</strong>verse <strong>of</strong> the Diffuson propagator<br />

H d :=<br />

ˆD<br />

−1<br />

= Q 2 +2Q SO (Q y˜Sx −Q x˜Sy )+Q 2<br />

D (˜S SO y 2 + ˜S x 2 ), (3.65)<br />

e<br />

with ˜S = (σ ′ −σ)/2, which has the same spectrum as the Cooperon, as long as the timereversal<br />

symmetry is not broken. In the representation <strong>of</strong> s<strong>in</strong>glet and triplet modes the<br />

diffusion Hamiltonian becomes<br />

⎛ √<br />

2Q 2 SO<br />

+Q 2 2Q SO Q − 0 − √ ⎞<br />

2Q SO Q +<br />

√ 2Q SO Q + Q 2 SO<br />

H d =<br />

+Q2 0 0<br />

. (3.66)<br />

⎜<br />

⎝ 0 0 Q 2 0 ⎟<br />

− √ ⎠<br />

2Q SO Q − 0 0 Q 2 SO<br />

+Q 2

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