EurOCEAN 2000 - Vlaams Instituut voor de Zee

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TITLE: ASSESSMENT OF ANTIFOULING AGENTS IN COASTAL ENVIRONMENTS : ACE CONTRACT NO: MAS3-CT98-0178 COORDINATOR: Prof. James Readman Centre for Coastal and Marine Sciences Plymouth Marine Laboratory Prospect Place, The Hoe, Plymouth, PL1 3DH, UK Tel: +44 (0) 1752 633460 Fax: +44 (0) 1752 633101 E-mail: jwre@ccms.ac.uk PARTNERS: Dr. Bert van Hattum Institute for Environmental Studies Vrije Univeristy De Boelelaan 1115 NL 1081 HV Amsterdam Netherlands Phone: 31-20-4449555 Fax: 31-20-4449553 E-mail: bvanhattum@ivm.vu.nl Dr. Damia Barcelo CID-CSIC Department of Environmental Chemistry Jordi Girona 18-26,08034 Barcelona, Spain Phone: 34-93-4006118 Fax: 34-93-204-59-04 E-mail: dbcqam@cid.csic.es Prof. T. A. Albanis University of Ioannina Laboratory of Industrial Chemistry Ioannina 45110, Greece Phone: 30-651-98348 Fax: 30-651-44836 E-mail: talbanis@cc.uoi.gr Dr. Bo Riemann National Environmental Research Institute P.O.Box 358 DK-4000 Roskilde, Denmark Tel: +45-46301200 Fax: +45-46301114 E-mail: bri@dmu.dk 466 Prof. Hans Blanck Botanical Institute Göteborg University Box 461 SE405 30 Göteborg, Sweden Phone: 46-31-773 26 09 Fax:46-31-773 26 26 E-mail: hans.blanck@fysbot.gu.se Kim Gustavson DHI- Institute of Water and Environment Agern Allé 11 2970 H¢rsholm, Denmark Tel: 45-45169200 Fax: 45-45169292 E-mail: kig@vki.dk Dr. J. Tronczynski Institut Français de Recherche pour l’Exploitation de la Mer (IFREMER) Centre de Nantes, Laboratoire de Chimie des Contaminants et de Modélisation Rue de l’Ile d’Yeu B.P. 21105, 44311 Nantes Cedex 3, France Phone: 33-2-40-37-41-36 Fax: 33-2-40-37-40-75 E-mail: jtronczy@ifremer.fr INDUSTRIAL PARTNER: Rohm & Haas
ASSESSMENT OF ANTIFOULING AGENTS IN COASTAL ENVIRONMENTS (ACE) MAS3-CT98-0178 (February 1999 – February 2002) James W. Readman Centre for Coastal and Marine Sciences – Plymouth Marine Laboratory, Plymouth, U.K. SUMMARY In 1989 the European Community introduced a directive to restrict the use of TBT-based antifouling paints on boats under 25m. This, in combination with other National and International legislation, has provoked paint manufacturers and chemical companies to develop and vend a range of agents for new antifouling paints for the “small boat” market and as an addition to TBT-based formulations to enhance efficacy for larger vessels. Examples of the types of compounds being used or promoted include: 2,3,5,6-tetrachloro-4- (methyl sulphonyl) pyridine; 2-methylthio-4-tertiary-butylamino-6-cyclopropylamino-striazine (IRGAROL 1051); cuprous thio cyanate; 2,4,5,6-tetrachloro iso phthalo nitrile; 4,5dichloro-2-n-octyl-4-isothiazolin-3-one (SeaNine 211); dichlorophenyl dimethylurea (Diuron); 2-(thiocyanomethyl thio)benzthiazole; zinc pyrithione; 4-chloro-meta-cresol; arsenic trioxide; cis 1-(3-chloroallyl)-3,5,7-triaza-1-azonia adamantane chloride; zineb; dichlofluanid; folpet; thiram; oxy tetracycline hydrochloride; ziram and maneb. This list includes compounds which are known to be highly toxic (e.g. cyanides, arsenicals) or to act as endocrine disrupters (e.g. zineb, maneb, ziram)(Colborn et al., 1993) but negligible data concerning contamination, (potential) effects and risks of these compounds in the coastal and marine environment are available. This project has the objective to provide information and tools which enable environmental managers at national and international levels to address the issue of antifouling agents in a systematic and effective manner. The following activities are underway: • a survey of antifouling agents and products being used and marketed; • an assessment of geographical patterns of usage; • a database is being established with environmental and toxicological properties of these compounds using information from literature and data generated in the project; • suitably sensitive analytical techniques to measure environmental levels are being developed; • extent of contamination of European coastlines is being assessed; • fates and effects in (semi-) field conditions are being investigated; • models to predict future concentrations levels and effects in selected European coastal zones will be developed using the data obtained; • products will be compared regarding environmental properties (fates, toxicity etc.) and effects using different scenario’s for usage. Partners involved include experts in analytical/environmental chemistry, ecotoxicology, modelling and risk assessment with considerable experience in marine science. They represent several EU States which cover a large proportion and diverse EU coastal areas. An industrial perspective is included through the participation of an antifouling biocide manufacturer. 467
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OFFICE FOR OFFICIAL PUBLICATIONS OF
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EurOCEAN 2000 The European Conferen
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TABLE OF CONTENTS (Volumes I - II)
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Integrated nitrogen model for europ
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II.1.2 Mehtods for monitoring, fore
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III.2.2 Oceanographic measurement a
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380
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382
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Jan van de Graaff Delft University
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dimensional near-field hydrodynamic
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ISVA, turbulence under spilling bre
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Most important results until now: W
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TITLE : PREDICTION OF COHESIVE SEDI
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394 PREDICTION OF COHESIVE SEDIMENT
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processes of CBS. This is particula
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liquefaction (e.g. induced by wave
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TITLE : COASTAL STUDY OF THREE-DIME
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COASTAL STUDY OF THREE-DIMENSIONAL
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morphological change. Their predict
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O’Connor B.A., and Nicholson J. (
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Professor F Seabra-Santos Universid
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The INDIA Project brings together m
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412 (CCMS-POL, USC) and bed sonar e
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Prof. D. Myrhaug (NTNU) Norwegian U
Page 50 and 51: project is focussed on relevant pra
Page 52 and 53: Modelling results for the flat bed
Page 54 and 55: engineering firms (coastal engineer
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Page 58 and 59: Luigi Alberotanza Inst. for the Stu
Page 60 and 61: All three sites are equipped with i
Page 62 and 63: 2.3 Assessment of methods for the i
Page 64 and 65: TITLE : OPERATIONAL MODELLING FOR C
Page 66 and 67: ‰ B. Model investigations on oper
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Page 70 and 71: TITLE: A USER-FRIENDLY TOOL FOR THE
Page 72 and 73: EUROWAVES OVERVIEW A quick illustra
Page 74 and 75: Figure 1 An example of the EUROWAVE
Page 76 and 77: Figure 4 Example output field for s
Page 78 and 79: 444 EUROPEAN RADAR OCEAN SENSING He
Page 80 and 81: Figure1: WERA current field. Figure
Page 82 and 83: information in maps has proven to b
Page 84 and 85: Universidad Politecnica de Cataluny
Page 86 and 87: esources, such as in ship routing.
Page 88 and 89: Data Analysis The basic idea of adv
Page 90 and 91: implemented in system analyses and
Page 92 and 93: Dr. Claude Millot CNRS LOB/COM B.P.
Page 94 and 95: MEDITERRANEAN FORECASTING SYSTEM PI
Page 96 and 97: ADCP and line three mooring consist
Page 98 and 99: 464 MeteoFrance ftp site Ocean forc
Page 102 and 103: INTRODUCTION Antifouling paints are
Page 104 and 105: e.g. diuron was detected in Swedish
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Page 108 and 109: TITLE: SCOUR AROUND COASTAL STRUCTU
Page 110 and 111: Conference among others, and will b
Page 112 and 113: TOPIC 2.4. SEDIMENT TRANSPORT/SCOUR
Page 114 and 115: TITEL: VALIDATION OF LOW LEVEL ICE
Page 116 and 117: Ice compressive strength tests were
Page 118 and 119: subsequent inclined shear failure.
Page 120 and 121: 486 Fig. 1 Fig. 2
Page 122 and 123: ir. M. Willems FC/FH - Flanders Hyd
Page 124 and 125: jetty and the armour layer. Out of
Page 126 and 127: Both the Zeebrugge and the Petten s
Page 128 and 129: alternative methods for the evaluat
Page 130 and 131: PORTUGAL Dr. César Andrade Centro
Page 132 and 133: Dr. Yolanda Foote Centre for Enviro
Page 134 and 135: cliff erosion and the life span of
Page 136 and 137: BIOLOGICAL PROCESSES ESPED recognis
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Page 144 and 145: 510 AUTOMATIC IDENTIFICATION AND CH
Page 146 and 147: complexity of the data. Once traine
Page 148 and 149: INTEGRATING IDENTIFICATION AND CHAR
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TITLE: SEDIMENT IDENTIFICATION FOR
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518 SEDIMENT IDENTIFICATION FOR GEO
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The way to sense the marine environ
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6. Data processing and inversion (L
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TITLE: TRANSMISSION OF ELECTROMAGNE
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526 Attenuation dB/m 10 4 10 3 10 2
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Figure 2 Spectral response for wave
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TITLE: IMPROVED MICROSTRUCTURE MEAS
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IMPROVED MICROSTRUCTURE MEASUREMENT
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committee proposed the new establis
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of the profiler. Thus, the ACC98 se
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Figure 3b: Measurements of and diss
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TITLE: APPLICATIONS OF 3-DIMENSIONA
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2. OBJECTIVES The first objective o
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to demonstrate a capability for col
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546 ADIAC: DIATOMS GO DIGITAL M. Ba
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SLIDE SCANNING FOR DIATOM LOCALIZAT
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performance of normal PCs and the a
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TITLE : SUBSEA TOOLS APPLICATION RE
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554 SUBSEA TOOLS: A CRAFT PROJECT T
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RESULTS The deliverable is a multi-
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TITLE: DINOFLAGELLATE CATEGORISATIO
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1998) has simplified the developmen
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Fig. 3: Example specimen images 562
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REFERENCES Culverhouse PF, Ellis RE
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566
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INTRODUCTION 568 LOTUS Long Range T
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DESIGN OF EXPERIMENTAL EQUIPMENT Th
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Figure 2: Complex base-band impulse
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ACKNOWLEDGEMENTS This work is funde
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576 THE SEISCAN INITIATIVE: SEISMIC
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een fed through to the scanning cen
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Data scanned At the time of writing
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The digital transcription forms an
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584 SUMMARY OF SWAN PROJECT OBJECTI
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Apart from suffering from ISI, a mu
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TITLE : LONG-RANGE SHALLOW-WATER RO
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OBJECTIVES Present communication sy
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RESULTS OF THE DATA ANALYSIS Analys
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TITLE : UNDERWATER DIVING INTERPERS
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Orientation The electrical field ap
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[6] Virr LE (1987) « Role of elect
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TITLE : ELECTROACOUSTIC PROTOTYPE F
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specimen of bottlenose dolphin capt
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REFERENCES Cameron, G. 1999. Report
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606
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608 HIGH RESOLUTION IN SITU HOLOGRA
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due to thermal expansion. The power
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612 200 mm stages with optics and C
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III.1.4 Submarine geotechnics 615
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TITLE : GROUTED OFFSHORE PILES FOR
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Solution One solution to this probl
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technology. Harbour works, wharves,
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• A major characterisation progra
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VERY HIGH RESOLUTION MARINE 3D SEIS
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Monaco harbour (France) A very comp
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End-users highlighted the current,
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C. Smith Institute of Marine Biolog
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package for Automatic Mobile Invest
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The operation of ARAMIS The typical
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• ROV landing on the sea bottom t
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EURODOCKER - A UNIVERSAL DOCKING -
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RESULTS: EURODOCKER SYSTEM DESCRIPT
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THE PROTOTYPE The Construction of t
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TITLE : LIGHTWEIGHT COMPOSITE PRESS
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OBJECTIVES: The aim of the project
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TITLE : ADVANCED SYSTEM INTEGRATION
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651 Differential GPS - Reference St
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Figure 3.a The DELFIM ASC Figure 3.
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place vertically in the framework o
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[8] A. Pascoal, . P. Oliveira, C. S
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Eng. J.-M.Coudeville ORCA Instrumen
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THE GEOSTAR PROTOTYPE GEOSTAR proto
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CONCLUSIONS GEOSTAR 2 is a project
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goals of the project and results of
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III.2.2. Oceanographic measurement
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TITLE : GAS HYDRATE AUTOCLAVE CORIN
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initially most important parameters
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3.4 Finalization of delayed tasks i
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Dr. Margaret Yelland Southampton Oc
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RESULTS FROM THE FIRST PROJECT PERI
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Taylor,P. K. and M. J. Yelland, 199
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TRACE METAL MONOTORING IN SURFACE M
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THE FLUORESCENCE SIGNAL OBTAINED WH
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The reaction of 6-mercaptopurine, l
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TITLE : OCEAN TOMOGRAPHY OPERATIONA
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The OCTOPUS project has been runnin
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Fig. 2: Typical TOMOLAB input: Tomo
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The establishment of a data bank fo
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TITLE: SPECTROSCOPY USING OPTICAL F
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The overall objective of the SOFIE
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devoted to investigate the behaviou
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TITLE : DEVELOPMENT AND TEST OF AN
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in-situ (Nitrate, Nitrite, Ammonia,
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Apart from the measurements made in
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MANUFACTURE OF CALIBRATION SOLUTION
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einz-Detlef Kronfeldt, Heinar Schmi
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