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Special Issue; Products for Industrial Machinery - NTN

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<strong>NTN</strong> TECHNICAL REVIEW No. 742006<br />

Use of oil is effective to decrease the friction<br />

coefficient. Until now, <strong>NTN</strong> had been attempting to<br />

lower the friction coefficient <strong>for</strong> sliding bearings by<br />

using an oil dispersion technique with a polymer alloy,<br />

<strong>for</strong> example. 3)<br />

However, conventional techniques had limitations<br />

because the addition of an excessive amount of oil<br />

can lead to deterioration in the mechanical strength<br />

and <strong>for</strong>mability of a sliding material. There<strong>for</strong>e, we<br />

developed a technique that adopted porous silica as<br />

an oil retaining material (oil-impregnated silica).<br />

Thereby, we attempted to increase the content of oil<br />

included in the resin while maintaining good<br />

mechanical characteristics and <strong>for</strong>mability of the<br />

resultant sliding resin material. 4)<br />

Compositions and frictional characteristics of<br />

materials prepared by blending different proportions of<br />

oil-impregnated silica into ultrahigh-molecular-weight<br />

polyethylene (UHMWPE) are summarized in Table 1<br />

and Fig. 3. Compared with the material blended with<br />

oil alone 2, the material blended with oil-impregnated<br />

silica 3 exhibited a lower dynamic friction coefficient<br />

though its oil content was equal to that of material 2.<br />

With an increase in the amount of oil-impregnated<br />

silica (material 4), the dynamic friction coefficient<br />

further decreased, reaching a level lower than a third<br />

the level obtained with a PTFE-based sliding material.<br />

Having undergone the test, the sliding surface of<br />

material 4 was inspected, and the oil-impregnated<br />

Table. 1 Composition of test specimens <strong>for</strong> sliding tests<br />

Material<br />

1<br />

2<br />

3<br />

4<br />

Composition (vol%)<br />

UHMWPE (100)<br />

UHMWPE (85)Silicone oil (15)<br />

UHMWPE (82)Oil-impregnated silica (18)<br />

UHMWPE (70)Oil-impregnated silica (30)<br />

1:5 porous silica to silicone oil ratio<br />

silica exposed on the sliding surface was found as a<br />

result (Fig. 4). In addition, the static oil seepage from<br />

material 4 at room temperature and 15 MPa conditions<br />

was measured. As shown in Fig. 5, the oil seepage<br />

increased as the time elapsed and reached 6% in 100<br />

hours. Assuming that only the oil near the surface layer<br />

seeped out this level of leakage is too great.<br />

From these findings, we estimated the low friction<br />

mechanism of this material as shown in Fig. 6. In<br />

other words, we believe the following theory about the<br />

mechanism. Since the oil-impregnated silica serves as<br />

the load bearing point, solid-to-solid contact is<br />

inhibited, making it easier <strong>for</strong> an oil film to <strong>for</strong>m.<br />

Seepage wt%<br />

Fig. 4 Surface of the material 4 after sliding test<br />

8.00<br />

6.00<br />

4.00<br />

2.00<br />

Pressure: 15 MPa<br />

Room temperature<br />

Oil-impregnated<br />

silica<br />

10m<br />

0.00<br />

0<br />

20 40 60 80 100<br />

Time h<br />

Fig. 5 Relationship between loading time and oozed oil<br />

amount from the material 4<br />

Dynamic friction coefficient<br />

0.30<br />

0.25<br />

0.20<br />

0.15<br />

0.10<br />

0.05<br />

0.00<br />

Two test runs<br />

UHMWPE<br />

100%<br />

UHMWPE<br />

15%<br />

silicone oil<br />

Test rig: oscillating ring-on-disk<br />

Specific pressure: 15MPa<br />

Velocity: 0.1m/s<br />

Counterpart material: SUS304 (Ra 0.1m)<br />

Characteristic to be measured:<br />

dynamic friction coefficient 5 minutes later<br />

Silicone oil added<br />

Porous silica added<br />

Increased amount added<br />

UHMWPE<br />

3% porous silica<br />

15% silicone oil<br />

UHMWPE<br />

5% porous silica<br />

25% silicone oil<br />

PTFE<br />

Oil film<br />

Resin material<br />

Transfer of oil<br />

Counterpart material<br />

Oil-impregnated<br />

porous silica<br />

Operating mechanism of oil-impregnated silica (estimated)<br />

Load-bearing point – decrease in true contact area<br />

Oil supply source – decrease in shear strength<br />

Low <br />

Fig. 3 Friction properties of the materials filled with oilimpregnated-silica<br />

Fig. 6 Estimated mechanism of low friction of the<br />

developed material<br />

-110-

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