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J Bagh College Dentistry <strong>Vol</strong>. <strong>21</strong>(1), 2009 The effect of amalgam…<br />

mechanism for such adhesive to amalgam is<br />

micro-mechanical type that depends on the film<br />

thickness of the adhesive. Hand condensation<br />

effect may be more obvious than the mechanical<br />

condensation under these circumstances.<br />

Similarly, for the control groups, there was no<br />

bonding mechanism between the amalgam and<br />

dentin just the micro-mechanical adaptation<br />

enhanced by heavy hand condensation. This<br />

attribution is supported by the classic studies and<br />

recent reports about the hand condensation<br />

effects and the bonding mechanism of recent<br />

dentin bonding agents to amalgam (14).<br />

Sweeney (15) , Jorgensen (16) , and Mjor (17)<br />

contributed to such researches. Some of them<br />

found that the hand condensation performed<br />

better in reducing porosities at amalgam / dentin<br />

interface and it had better adaptability. Others<br />

reported that there were some kinds of<br />

mechanical interlocking between amalgam<br />

particles and dentin irregularities even that the<br />

self-sealing criteria of amalgam was not started<br />

yet .<br />

The Syntac adhesive / primer has 4-META<br />

and HEMA co-monomers that may bond the<br />

amalgam chemically and micro-mechanically.<br />

This “real” bonding may show the obvious effect<br />

of mechanical condensation to enhance the<br />

bonding of amalgam to dentin. This explanation<br />

is supported by the findings of Chapman &<br />

Crim (12) , which had already mentioned.<br />

The Use of Dentin Bonding Agents. For both<br />

types of condensation techniques and under the<br />

conditions of this study, there was highly<br />

significant difference between the different types<br />

of adhesives used on the one hand, and between<br />

the groups with the bonding treatment and that<br />

without bonding treatment (controls) on the<br />

other. These results are in agreement with several<br />

studies. Zardiackas & Stoner (2) , Shimizu et a1 (3) ,<br />

and Varga et a1 (4) showed that the bonding of<br />

amalgam to tooth structure was possible under<br />

laboratory conditions with higher over the<br />

unbonded one .<br />

In addition, numerous clinical studies had<br />

reported favorable results, which were obtained<br />

when using amalgam bonding approach. Those<br />

studies were done by Summitt et a1 (18) , Setcos et<br />

a1 (19) , and Belcher & Stewart (35) . These results<br />

support the finding obtained by this about the<br />

bonding of amalgam to dentin by using dentin<br />

adhesive systems and with higher TBS than that<br />

of the controls.<br />

The differences in the bond strengths different<br />

generations of dentin binding agents have been<br />

shown in various studies.<br />

Under the circumstances of this study, the<br />

Syntac adhesive showed higher TBS to dentin than<br />

the Scotchbond Multi-Purpose. This finding is in<br />

agreement with that of Retief et a1 (14) , although the<br />

TBS values were higher than those of this study.<br />

However, Chappell & Eick (22) and Holtan et a1 (23)<br />

found that the Scotchbond Multi-Purpose had<br />

significantly better bond strength between the<br />

amalgam and dentin than the Syntac and<br />

Scotchbond Multi-Purpose may be due to the<br />

different chemistries of these bonding systems ,<br />

although some similarities do exist. The similarity<br />

found in the pretreatment procedure in using the<br />

same chemical composition etchants 9355<br />

phosphoric acid). The Scotchbond Multi-Purpose<br />

primer contains HEMA and polyalkenoata copolymer<br />

and the adhesive contains BIS-GMA and<br />

HEMA (14) . The Syntac-one bottle-contains 4-<br />

META and HEMA (24) . Examinations with an<br />

electron microscope have shown that the<br />

hydrophilic monomers connect with both organic<br />

dental hard tissue by forming ion complexes with<br />

calcium ions of enamel and dentin and hydrogen<br />

bridges with collagen fibers of dentin (25) . This<br />

complicated connection may be the reason for such<br />

higher TBS values obtained in this study over the<br />

Scotchbond Multi-Purpose.<br />

REFERENCES<br />

1. Fayyad MA, Ball PC. Cavity sealing ability of lathecut,<br />

blend and spherical amalgam alloys: a laboratory<br />

study. Oper Dent 1984; 9: 86-93.<br />

2. Zardiackas LD, Stoner GE. Tensile and shear adhesion<br />

of amalgam to tooth structure using selective<br />

interfacial amalgamation. Biomaterials 1983; 4: 9-13.<br />

3. Shimizu A, Ui T, Kawakami M. Bond strength<br />

between amalgam and tooth hard tissues with<br />

application of fluoride, glass ionomer and adhesive<br />

resin cement in various combinations. Dent Mater<br />

1986; 5: 225-32.<br />

4. Varga J, Matsumura H, Masuhara E. Bonding of<br />

amalgam filling to tooth cavity with adhesive resin.<br />

Dent Mater 1986; 5: 158-64.<br />

5. Staninec M, Holt M. Bonding of amalgam to tooth<br />

structure: tensile adhesion and microleakage tests. J<br />

Prosthet Dent 1988; 59: 397-402.<br />

6. Edgren BN, Denehy GE. Microleakage of amalgam<br />

restorations using Amalgambond and copalite. Am J<br />

Dent 1992; 5: 296-8.<br />

7. Clinical Research Associates: Adhesives: Silver<br />

amalgam. Clinical Research Associates Newsletter.<br />

1994; 18: 2-3 cited by Ratananakin T, Denehy GE,<br />

Vargas MA. Effect of condensation techniques on<br />

amalgam bond strengths to dentin. Oper Dent 1996;<br />

<strong>21</strong>: 191-5.<br />

8. Philips RW. Dental amalgam alloys: Amalgam<br />

structures and properties and Chapter 18, Dental<br />

amalgam: Technical condensations. In skinner’s<br />

science of Dental Materials, 9 th ed. Philadelphia : W.<br />

B. Saunders Company , P. 303-25 and 327-47, 1991.<br />

9. Craig R G. Restorative Dental Materials. 8 th ed. St.<br />

Louis: C. V. Mosby , P. <strong>21</strong>4-47, 1990.<br />

Restorative Dentistry 36

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