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General Chemistry Principles, Patterns, and Applications, 2011

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13. A new element is believed to have been discovered by a team of Russian <strong>and</strong> American scientists, although<br />

its existence is yet to be independently confirmed. Six atoms of element 117, temporarily named<br />

ununseptium, were created by smashing together isotopes of calcium with the element berkelium. Give the<br />

following:<br />

a. the complete electron configuration of this element<br />

b. the valence electron configuration<br />

c. the number of unpaired electrons in the valence shell<br />

Chapter 7<br />

The Periodic Table <strong>and</strong> Periodic Trends<br />

In , we presented the contemporary quantum mechanical model of the atom. In using this model to describe the<br />

electronic structures of the elements in order of increasing atomic number, we saw that periodic similarities in<br />

electron configuration correlate with periodic similarities in properties, which is the basis for the structure of the<br />

periodic table. For example, the noble gases have what is often called filled or closed-shell valence electron<br />

configurations. These closed shells are actually filled s <strong>and</strong> psubshells with a total of eight electrons, which are<br />

called octets; helium is an exception, with a closed 1s shell that has only two electrons. Because of their filled valence<br />

shells, the noble gases are generally unreactive. In contrast, the alkali metals have a single valence electron outside a<br />

closed shell <strong>and</strong> readily lose this electron to elements that require electrons to achieve an octet, such as the halogens.<br />

Thus because of their periodic similarities in electron configuration, atoms in the same column of the periodic table<br />

tend to form compounds with the same oxidation states <strong>and</strong> stoichiometries. ended with the observation that, because<br />

all the elements in a column have the same valence electron configuration, the periodic table can be used to find the<br />

electron configuration of most of the elements at a glance.<br />

Crookes’s Spiral Periodic Table, 1888. Created by Sir William Crookes (1832–1919), the spiral represents<br />

the relationships between the elements <strong>and</strong> the order of evolution of the elements from what he believed to be primal<br />

matter.<br />

In this chapter, we explore the relationship between the electron configurations of the elements, as reflected in their<br />

arrangement in the periodic table, <strong>and</strong> their physical <strong>and</strong> chemical properties. In particular, we focus on the<br />

Saylor URL: http://www.saylor.org/books<br />

Saylor.org<br />

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