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A “Toolbox” for Forensic Engineers

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Failure of Storage Vessels 229<br />

Figure 7.11 Various designs of miner’s lamp battery cases, with the oldest at<br />

the right in aluminum (now banned because of the possibility of thermite sparks).<br />

The other lamps are made in polycarbonate, red filled at the right, and transparent<br />

at the center and left. The polycarbonate molding is at the extreme left.<br />

Number of Failed Batteries<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Normal Life<br />

of a Battery<br />

1 2 3<br />

Lifetime/Years<br />

Figure 7.12 Failure records of first design of polycarbonate battery case in U.K.<br />

coal mines.<br />

The crack here had started at the sharp corner at a small lip created by the<br />

joint in the tool surfaces. In other examples, cracks had started from no<br />

visible external stress raiser, but stripping the affected product showed that<br />

cracks could be initiated all too easily from very sharp internal corners (radii<br />

of curvature approximately 0.1 mm). What could be the cause of the several<br />

modes of failure?<br />

Polycarbonate is extremely strong in the <strong>for</strong>m of extruded sheet, finding<br />

use in safety shields and bullet-proof glazing. However, when it is injection<br />

molded into complex shapes, a lower molecular mass grade must be used in<br />

order to penetrate all the intricacies of the molding tool. It is almost universally<br />

true that polymer strength is very sensitive to molecular mass, falling

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