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Experimental Methods, Results and Discussion Benson, B.; Krause, D., Empirical Laws for Dilute Aqueous Solutions of Nonpolar Gases, J. Chem. Phys., (1976) 64: 689 Billet, T.; Morrison, T. J., J. Chem. Soc. (1948) 2033 Brunner, G.; Dohrn, R., High-Pressure Fluid-Phase Equilibria: Experimental Methods and Systems Investigated (1988–1993), Fluid Phase Equilib. (1995) 106: 213 Campbell, D. N.; Hickman, J. B., Solubility Characteristics of Some Binary Liquid Mixtures, J. Am. Chem. Soc. (1953) 75: 2879 Carnicer, J.; Gibanel, F.; Urieta, J.; Losa, C., Rev. Acad. Ciencias Zaragoza (1979) 34: 115 Chickos, J. S., The Strain Energy of Cyclotetradecane is Small, J. Org. Chem. (1992) 57 1897 Christov, M.; Dohrn, R., High-Pressure Fluid Phase Equilibria. Experimental Methods and Systems Investigated (1994–1999), Fluid Phase Equilibria 202 (2002) 153 Clever H. L., Battino R. in Solutions and Solubilities, Ed. M. R. J. Dack, J. Wiley and Sons, New York (1975) Chapter 7 Clever, H. L.; Battino, R., The Experimental Determination of Solubilities, Edited by G. T. Hefter and R. P.T. Tomkins, Wiley (2003) Chapter 2.1 Cook, M. W.; Hanson, D. N., Accurate Measurements of Gas Solubiliy, Rev. Sci. Instr., (1957) 28: 370 Costa, M.A.M.; Matos, H.A.S.; Nunes da Ponte, M.; Gomez de Azevedo, E.J.S., Binary and Ternary Phase Behavior of α-Pinene, Β -Pinene, and Supercritical Ethene, J. Chem. Eng. Data (1996) 41: 1104 Counsell, J. F.; Green, J. H. S.; Hales, J. L.; Martin, J. F.; Thermodynamic Properties of Fluorine Compounds.2. Physical and Thermodynamic Properties of Hexafluorobenzene, Trans. Faraday Soc. (1965) 61: 212 Crowder, G. A.; Taylor, Z. L.; Reed, T. M.; Young, J. A., Vapor Pressures and Triple Point Temperatures for Several Pure Fluorocarbons, J. Chem. Eng. Data (1967) 12: 481 Dias A. M. A., Freire. M. G., Coutinho J. A. P., Marrucho I. M., Solubility of Oxygen in Liquid Perfluorocarbons, Fluid Phase Equilibria (2004) 222: 325 Douslin, D. R.; Osborn, A.; Pressure Measurements in 0.01-30 Torr Range With an Inclined-Piston Gauge, J. Sci. Instrum. (1965) 42: 369 - 85 -
Experimental Methods, Results and Discussion Douslin, D. R.; Harrison, R. H.; Moore, R. T. Pressure-Volume-Temperature Relations of Hexafluorobenzene, J. Chem.Thermodynamics (1969) 1: 305 Duce, C.; Tinè, M. R.; Lepori, L.; Matteoli, E., VLE and LLE of Perfluoroalkane + Alkane Mixtures, Fluid Phase Equilibria (2002) 199: 197 Dunlap, R. D.; Murphy, C. J.; Bedford, R. G., Some Physical Properties of Perfluoro-nhexane, J. Am. Soc. (1958) 80: 83 Dymond, J.; Smith, E., The Virial Coefficients of Pure Gases and Mixtures, Oxford University Press, Oxford (1980) Edmonds B. (1972) Chemistry, University of Sheffield: Shefield Ermakov, G.; Skripov, V. Saturation line, critical parameters, and the maximum degree of superheating of perfluoro-paraffins Russian Journal of Physical Chemistry (1967) 41: 39 Evans F. D.; Tiley, P. F. Vapour Pressures and Critical Constants of Hexafluoro, Pentafluoo, Chloropentafluoro and Bromopentafluoro Benzene J. Chem. Soc. B-Physical Organic (1966) 2: 134 Evans F. D., Battino R., Solubility of Gases in Liquids. 3. Solubilities of Gases in Hexafluorobenzene and in Benzene, J. Chem. Thermodynamics (1971) 3: 753 Findlay, T. J. V. Vapor Pressures of Fluorobenzene from 5 Degrees C to 50 Degrees C, J. Chem. Eng. Data (1969) 14: 229 Fogg P.G.T., Gerrard W., Solubilities of Gases in Liquids, John Wiley & Sons Lda, England (1991) Fornari, R.; Alessi, P.; Kikic, I., High Pressure Fluid Phase Equilibria: Experimental Methods and Systems Investigated (1978–1987), Fluid Phase Equilib. (1990) 57: 1 Girard G., Density in Marsh K.N. ed., Recommended Reference Materials for the Realization of Physicochemical Properties, IUPAC, Blackwell, Oxford, Cap.2 (1987) Gjaldbaek, J. C., The Solubility of Hydrogen, Oxygen and Carbon Monoxide in Some Non- Polar Solvents, Acta Chemica Scandinavica (1952) 6: 623 Glew, D.; Reeves, L. Purification of perfluoro-n-heptane and perfluoromethylcyclohexane J. Phys. Chem. (1956) 60: 615 Gomes, M. F. C.; Deschamps, J.; Menz, D. H. Solubility of Dioxygen in Seven Fluorinated Liquids J. of Fluorine Chem. (2004) 125: 1325 Good, W. D.; Douslin, D. R.; Scott, D. W.; George, A.; Lacina, J. L.; Dawson, J. P.; Waddington, G. Thermochemistry and vapor pressure of Aliphatic Fluorocarbons. A - 86 -
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Ana Maria Antunes Dias Universidade
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o júri presidente Prof. Dr. Joaqui
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palavras-chave resumo perfluoroalca
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Contents Notation List of Tables Li
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Notation Abbreviations AAD EoS LCST
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List of Tables Table I.1 Average Bo
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Table III.6 Adjusted Binary Paramet
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Figure II.9 Comparison between corr
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Figure III.8 Temperature-density di
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Figure III.25 Vapor-phase mole frac
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I.1. Fluorine Properties General In
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Table I.2. Physicochemical Properti
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General Introduction order to compa
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General Introduction the numerous a
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General Introduction carbon dioxide
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General Introduction animals. That
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General Introduction Table I.3. Lit
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References General Introduction Ban
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General Introduction Hildebrand, J.
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General Introduction Rowinsky EK. N
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II. Part EXPERIMENTAL METHODS, RESU
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Experimental Methods, Results and D
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Page 47 and 48:
Page 49 and 50:
Table II.3. (continued) T K ρexp g
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ρ / g.cm-3 1.750 1.730 1.710 1.690
Page 53 and 54: Experimental Methods, Results and D
Page 55 and 56: I. 3. Vapour pressure I.3.1. Biblio
Page 57 and 58: I.3.2. Apparatus and Procedure Expe
Page 59 and 60: I.3.3. Experimental Results and Dis
Page 63 and 64: Table II.8. (continued) T K Pexp kP
Page 67 and 68: ΔH vap = TΔS vap 2⎛ d ln P ⎞
Page 69 and 70: I.4. Solubility at atmospheric pres
Page 79 and 80: x2 (T,P2) 7.0E-03 6.0E-03 5.0E-03 4
Page 81 and 82: L 2,1 0.70 0.60 0.50 0.40 0.30 285
Page 93 and 94: P / MPa 6 5 4 3 2 1 0 P / MPa 14 12
Page 95 and 96: II.6. Liquid - Liquid Equilibrium I
Page 101 and 102: 0 τ β Δ1 2Δ1 [ 1+ B τ + B τ +
Page 103: References Experimental Methods, Re
Page 111 and 112: III.1. Introduction Modeling Most c
Page 113 and 114: Modeling The pioneering work of Wer
Page 115 and 116: III.2. Soft-SAFT Model Modeling A S
Page 117 and 118: Modeling The equation of state is w
Page 119 and 120: Chain Term Modeling Originally Wert
Page 121 and 122: Modeling The model is easily extend
Page 123 and 124: ( ) ( ) ∑∑∑ 3 2 2 2 2 qq 32π
Page 125 and 126: Modeling HRT is a promising theory,
Page 127 and 128: ( ρ) ρ , 0 ≤ ρ ( ρ) 2 Modelin
Page 129 and 130: III.3. Application to Pure Compound
Page 131 and 132: Modeling From the optimised paramet
Page 133 and 134: T / K 400 350 300 250 200 150 100 5
Page 135 and 136: ln Pvap 1.0E+01 1.0E+00 1.0E-01 1.0
Page 137 and 138: Modeling Table III.2. Absolute Aver
Page 139 and 140: Modeling The correlation coefficien
Page 141 and 142: Pvap (MPa) 4.00 3.50 3.00 2.50 2.00
Page 143 and 144: Modeling The mixture parameters a a
Page 145 and 146: Modeling the assumptions made by th
Page 147 and 148: Modeling between oxygen and perfluo
Page 149 and 150: xSolute 5.5E-03 5.0E-03 4.5E-03 4.0
Page 151 and 152: Modeling previous work, dealing wit
Page 153 and 154: Modeling These results confirm that
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Modeling CO2 binary mixtures using
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Modeling average deviation (AAD) be
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P / MPa 14 12 10 8 6 4 2 0 0 0.2 0.
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Modeling Figures III.16, III.17 and
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Modeling calculations from the orig
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Table III.9. References for VLE exp
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P / MPa 20 18 16 14 12 10 8 6 4 2 0
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Modeling Finally, Figure III.24 pre
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III.4.4. VLE and LLE of Alkane and
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Modeling number of perfluro-n-alkan
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y C6F14 1.0 0.8 0.6 0.4 0.2 0.0 0.0
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P / MPa 0.08 0.07 0.06 0.05 0.04 0.
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P / MPa 0.12 0.10 0.08 0.06 0.04 0.
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Modeling approach based on the meth
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Modeling Blas, F. J.; Vega, L. F.,
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DIPPR, Thermophysical Properties Da
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Modeling Hildebrand, J. H.; Fisher,
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Modeling McCabe, C.; Jackson, SAFT-
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Modeling Poling, B.; Prauznitz, J.;
Page 193 and 194:
Modeling Wertheim, M. S., Fluids wi
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