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Experimental Methods, Results and Discussion Pierotti, R. A. J., Solubility of Gases in Liquids, Phys. Chem. (1963) 67: 1840 Piñeiro, M. M.; Bessières, D.; Gacio, J. M.; Guirons, H. S.; Legido, J. L., Determination of high-pressure liquid density for n-perfluorohexane and n-perfluorononane, Fluid Phase Equilibria (2004) 220: 125 Poling, B.; Prauznitz, J.; O’Connell, J., The properties of Gases and Liquids, McGraw- Hill, New York (2001) 5 th edition Prausnitz, J.; Lichtenthaler, R.; Azevedo, E., Molecular Thermodynamics of Fluid-Phase Equilibria, Prentice Hall, New Jersey (1999) 3 rd Edition Reiss, H.; Frisch, H. J.; Helfand, E.; Lebowitz, J. L., Aspects of the Statistical Thermodynamics of Real Fluids, J. Chem. Phys. (1960) 32: 119 Riess, J. C., Oxygen Carriers ("Blood Substitutes")-Raison d'Etre, Chemistry, and Some Physiology, Chem. Rev. (2001) 101: 2797 Roy, S.; Behar, E.; Ungerer, P., Vapour-Liquid Equilibrium Data for Synthetic Hydrocarbon Mixtures. Application to Modelling of Migration from Source to Reservoir Rocks, Fluid Phase Equilibria (1997) 135: 63 Sengers, J. M. H. L.; Greer, W. L; Sengers, J. V. Scaled Equation of State Parameters for Gases in the Critical Region, J. Phys. Chem. Ref. Data (1976) 5: 1 Serra, M. C. C.; Palavra, AM. F. Solubility of 1-Butene in Water and in a Medium for Cultivation of a Bacterial Strain, J. of Solution Chemistry (2003) 32: 527 Sousa, H. C.; Rebelo, L. P. N., (Liquid + Liquid) Equilibria of (polystyrene + nitroethane). Molecular Weight, Pressure, and Isotope Effects, J. Chem. Thermodynamics (2000) 32: 355 Skurts, C. M.; Reese, H. R., The Solubility of Oxygen in Aqueous Fluorocarbon Emulsions J. Fluorine Chem. (1978) 11: 637 Stiles, V.; Cady, G. Physical Properties of Perfluoro-n-hexane and Perfluoro-2methylpentane, J. Am. Chem. Soc. (1952) 74: 3771 Takagi, T.; Sakura, T.; Tsuji, T.; Hongo, M., Bubble Point Pressure for Binary Mixtures of Difluoromethane with Pentafluoroethane and 1,1,1,2-tetrafluoroethane, Fluid Phase Equilibria (1999) 162: 171 Thomsen, E.; Gjaldbaek, J., The Solubility of Hydrogen, Nitrogen, Oxygen and Ethane in Normal Hydrocarbons, Acta Chemica Scandinavica, (1963) 17: 127 Vosmansky, J.; Dohnal, V., Gas Solubility Measurements with an Apparatus of the Ben- Naim-Baer Type, Fluid Phase Equilibria (1987) 33: 137 - 89 -
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Ana Maria Antunes Dias Universidade
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o júri presidente Prof. Dr. Joaqui
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palavras-chave resumo perfluoroalca
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Contents Notation List of Tables Li
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Notation Abbreviations AAD EoS LCST
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List of Tables Table I.1 Average Bo
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Table III.6 Adjusted Binary Paramet
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Figure II.9 Comparison between corr
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Figure III.8 Temperature-density di
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Figure III.25 Vapor-phase mole frac
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I.1. Fluorine Properties General In
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Table I.2. Physicochemical Properti
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General Introduction order to compa
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General Introduction the numerous a
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General Introduction carbon dioxide
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General Introduction animals. That
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General Introduction Table I.3. Lit
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References General Introduction Ban
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General Introduction Hildebrand, J.
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General Introduction Rowinsky EK. N
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II. Part EXPERIMENTAL METHODS, RESU
Page 43 and 44:
Experimental Methods, Results and D
Page 45 and 46:
Page 47 and 48:
Page 49 and 50:
Table II.3. (continued) T K ρexp g
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ρ / g.cm-3 1.750 1.730 1.710 1.690
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Page 55 and 56:
I. 3. Vapour pressure I.3.1. Biblio
Page 57 and 58: I.3.2. Apparatus and Procedure Expe
Page 59 and 60: I.3.3. Experimental Results and Dis
Page 61 and 62: Experimental Methods, Results and D
Page 63 and 64: Table II.8. (continued) T K Pexp kP
Page 67 and 68: ΔH vap = TΔS vap 2⎛ d ln P ⎞
Page 69 and 70: I.4. Solubility at atmospheric pres
Page 79 and 80: x2 (T,P2) 7.0E-03 6.0E-03 5.0E-03 4
Page 81 and 82: L 2,1 0.70 0.60 0.50 0.40 0.30 285
Page 93 and 94: P / MPa 6 5 4 3 2 1 0 P / MPa 14 12
Page 95 and 96: II.6. Liquid - Liquid Equilibrium I
Page 101 and 102: 0 τ β Δ1 2Δ1 [ 1+ B τ + B τ +
Page 103 and 104: References Experimental Methods, Re
Page 107: Experimental Methods, Results and D
Page 111 and 112: III.1. Introduction Modeling Most c
Page 113 and 114: Modeling The pioneering work of Wer
Page 115 and 116: III.2. Soft-SAFT Model Modeling A S
Page 117 and 118: Modeling The equation of state is w
Page 119 and 120: Chain Term Modeling Originally Wert
Page 121 and 122: Modeling The model is easily extend
Page 123 and 124: ( ) ( ) ∑∑∑ 3 2 2 2 2 qq 32π
Page 125 and 126: Modeling HRT is a promising theory,
Page 127 and 128: ( ρ) ρ , 0 ≤ ρ ( ρ) 2 Modelin
Page 129 and 130: III.3. Application to Pure Compound
Page 131 and 132: Modeling From the optimised paramet
Page 133 and 134: T / K 400 350 300 250 200 150 100 5
Page 135 and 136: ln Pvap 1.0E+01 1.0E+00 1.0E-01 1.0
Page 137 and 138: Modeling Table III.2. Absolute Aver
Page 139 and 140: Modeling The correlation coefficien
Page 141 and 142: Pvap (MPa) 4.00 3.50 3.00 2.50 2.00
Page 143 and 144: Modeling The mixture parameters a a
Page 145 and 146: Modeling the assumptions made by th
Page 147 and 148: Modeling between oxygen and perfluo
Page 149 and 150: xSolute 5.5E-03 5.0E-03 4.5E-03 4.0
Page 151 and 152: Modeling previous work, dealing wit
Page 153 and 154: Modeling These results confirm that
Page 155 and 156: Modeling CO2 binary mixtures using
Page 157 and 158: Modeling average deviation (AAD) be
Page 159 and 160:
P / MPa 14 12 10 8 6 4 2 0 0 0.2 0.
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Modeling Figures III.16, III.17 and
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Modeling calculations from the orig
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Table III.9. References for VLE exp
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P / MPa 20 18 16 14 12 10 8 6 4 2 0
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Modeling Finally, Figure III.24 pre
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III.4.4. VLE and LLE of Alkane and
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Modeling number of perfluro-n-alkan
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y C6F14 1.0 0.8 0.6 0.4 0.2 0.0 0.0
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P / MPa 0.08 0.07 0.06 0.05 0.04 0.
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P / MPa 0.12 0.10 0.08 0.06 0.04 0.
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Modeling approach based on the meth
Page 183 and 184:
Modeling Blas, F. J.; Vega, L. F.,
Page 185 and 186:
DIPPR, Thermophysical Properties Da
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Modeling Hildebrand, J. H.; Fisher,
Page 189 and 190:
Modeling McCabe, C.; Jackson, SAFT-
Page 191 and 192:
Modeling Poling, B.; Prauznitz, J.;
Page 193 and 194:
Modeling Wertheim, M. S., Fluids wi
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