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Table II.13. (continued). Experimental Methods, Results and Discussion T (K) P (bar) L2,1 (T,P) x2 x10 3 C10F18 288.85 1.015 0.414 4.14 0.99 291.08 1.002 0.408 4.00 0.99 293.94 1.009 0.410 4.01 0.99 299.82 1.019 0.407 3.96 0.99 306.31 1.016 0.412 3.92 0.99 311.61 1.017 0.417 3.91 0.98 313.20 1.007 0.408 3.77 0.98 289.58 1.020 1Br-C8F17 0.463 5.02 0.99 292.71 1.017 0.466 5.00 0.99 297.37 1.015 0.453 4.79 0.99 302.63 1.021 0.449 4.71 0.99 304.80 1.010 0.450 4.64 0.99 308.09 1.020 0.446 4.60 0.99 312.57 1.032 0.435 4.49 0.98 289.15 1.014 1H-C8F17 0.462 4.54 0.99 294.50 1.012 0.459 4.43 0.98 299.17 1.012 0.451 4.29 0.98 304.47 1.018 0.446 4.19 0.97 308.55 1.017 0.444 4.10 0.96 312.48 1.016 0.440 3.99 0.95 290.68 1.010 1H,8H-C8F16 0.399 3.76 0.99 290.82 1.019 0.400 3.80 0.99 297.97 1.011 0.409 3.78 0.99 307.99 1.009 0.411 3.69 0.98 - 59 - y2
x2 (T,P2) 7.0E-03 6.0E-03 5.0E-03 4.0E-03 3.0E-03 2.0E-03 1.0E-03 Experimental Methods, Results and Discussion 285 290 295 300 305 310 315 Figure II.11. Study of the effect of the chain on the solubility of oxygen in perfluoroalkanes. Oxygen’s mole fraction as a function of the temperature in perfluoro-n-hexane (♦), perfluoro-n- heptane (■), perfluoro-n-octane (▲) and perfluoro-n-nonane (●) at solute’s partial pressure. x2 (T,P2) 7.0E-03 6.0E-03 5.0E-03 4.0E-03 3.0E-03 2.0E-03 1.0E-03 Figure II.12. Study of the effect of the structure on the solubility of oxygen in perfluoroalkanes. Oxygen’s mole fraction as a function of the temperature in perfluorodecalin (∆), 1Br-perfluoro-n- octane (○), 1H-perfluoro-n-octane (□) and 1H,8H-perfluoro-n-octane (◊)at solute’s partial pressure. T/K 285 290 295 300 305 310 315 - 60 - T/K
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Ana Maria Antunes Dias Universidade
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o júri presidente Prof. Dr. Joaqui
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palavras-chave resumo perfluoroalca
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Contents Notation List of Tables Li
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Notation Abbreviations AAD EoS LCST
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List of Tables Table I.1 Average Bo
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Table III.6 Adjusted Binary Paramet
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Figure II.9 Comparison between corr
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Figure III.8 Temperature-density di
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Figure III.25 Vapor-phase mole frac
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I.1. Fluorine Properties General In
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Table I.2. Physicochemical Properti
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General Introduction order to compa
Page 27 and 28: General Introduction the numerous a
Page 29 and 30: General Introduction carbon dioxide
Page 31 and 32: General Introduction animals. That
Page 33 and 34: General Introduction Table I.3. Lit
Page 35 and 36: References General Introduction Ban
Page 37 and 38: General Introduction Hildebrand, J.
Page 39 and 40: General Introduction Rowinsky EK. N
Page 41 and 42: II. Part EXPERIMENTAL METHODS, RESU
Page 43 and 44: Experimental Methods, Results and D
Page 49 and 50: Table II.3. (continued) T K ρexp g
Page 51 and 52: ρ / g.cm-3 1.750 1.730 1.710 1.690
Page 55 and 56: I. 3. Vapour pressure I.3.1. Biblio
Page 57 and 58: I.3.2. Apparatus and Procedure Expe
Page 59 and 60: I.3.3. Experimental Results and Dis
Page 63 and 64: Table II.8. (continued) T K Pexp kP
Page 67 and 68: ΔH vap = TΔS vap 2⎛ d ln P ⎞
Page 69 and 70: I.4. Solubility at atmospheric pres
Page 77: Experimental Methods, Results and D
Page 81 and 82: L 2,1 0.70 0.60 0.50 0.40 0.30 285
Page 93 and 94: P / MPa 6 5 4 3 2 1 0 P / MPa 14 12
Page 95 and 96: II.6. Liquid - Liquid Equilibrium I
Page 101 and 102: 0 τ β Δ1 2Δ1 [ 1+ B τ + B τ +
Page 103 and 104: References Experimental Methods, Re
Page 111 and 112: III.1. Introduction Modeling Most c
Page 113 and 114: Modeling The pioneering work of Wer
Page 115 and 116: III.2. Soft-SAFT Model Modeling A S
Page 117 and 118: Modeling The equation of state is w
Page 119 and 120: Chain Term Modeling Originally Wert
Page 121 and 122: Modeling The model is easily extend
Page 123 and 124: ( ) ( ) ∑∑∑ 3 2 2 2 2 qq 32π
Page 125 and 126: Modeling HRT is a promising theory,
Page 127 and 128: ( ρ) ρ , 0 ≤ ρ ( ρ) 2 Modelin
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III.3. Application to Pure Compound
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Modeling From the optimised paramet
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T / K 400 350 300 250 200 150 100 5
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ln Pvap 1.0E+01 1.0E+00 1.0E-01 1.0
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Modeling Table III.2. Absolute Aver
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Modeling The correlation coefficien
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Pvap (MPa) 4.00 3.50 3.00 2.50 2.00
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Modeling The mixture parameters a a
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Modeling the assumptions made by th
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Modeling between oxygen and perfluo
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xSolute 5.5E-03 5.0E-03 4.5E-03 4.0
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Modeling previous work, dealing wit
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Modeling These results confirm that
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Modeling CO2 binary mixtures using
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Modeling average deviation (AAD) be
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P / MPa 14 12 10 8 6 4 2 0 0 0.2 0.
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Modeling Figures III.16, III.17 and
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Modeling calculations from the orig
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Table III.9. References for VLE exp
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P / MPa 20 18 16 14 12 10 8 6 4 2 0
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Modeling Finally, Figure III.24 pre
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III.4.4. VLE and LLE of Alkane and
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Modeling number of perfluro-n-alkan
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y C6F14 1.0 0.8 0.6 0.4 0.2 0.0 0.0
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P / MPa 0.08 0.07 0.06 0.05 0.04 0.
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P / MPa 0.12 0.10 0.08 0.06 0.04 0.
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Modeling approach based on the meth
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Modeling Blas, F. J.; Vega, L. F.,
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DIPPR, Thermophysical Properties Da
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Modeling Hildebrand, J. H.; Fisher,
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Modeling McCabe, C.; Jackson, SAFT-
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Modeling Poling, B.; Prauznitz, J.;
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Modeling Wertheim, M. S., Fluids wi
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