n - PATh :.: Process and Product Applied Thermodynamics research ...

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Aos meus pais, irmãos, tios, primos e avós pelo amor incondicional Aos meus amigos por me aceitarem como sou Aos meus orientadores pela confiança
o júri presidente Prof. Dr. Joaquim Manuel Vieira professor catedrático do Departamento de Cerâmica e Vidro da Universidade de Aveiro Prof. Dra. Lourdes Fern<strong>and</strong>ez Vega senior <strong>research</strong> scientist do Instituto de Ciências de Materiais de Barcelona Prof. Dr. Eduardo Jorge Morilla Filipe professor auxiliar do Instituto Superior Técnico da Universidade Técnica de Lisboa Prof. Dra. Isabel Maria Almeida Fonseca professora associada da Faculdade de Ciências e Tecnologia da Universidade de Coimbra Prof. Dr. António José Venâncio Ferrer Correia professor catedrático do Departamento de Química da Universidade de Aveiro Prof. Dra. Isabel Maria Delgado Jana Marrucho Ferreira professora auxiliar do Departamento de Química da Universidade de Aveiro Prof. Dr. João Manuel da Costa e Araújo Pereira Coutinho professor associado do Departamento de Química da Universidade de Aveiro
Page 1: Ana Maria Antunes Dias Universidade
Page 5 and 6: palavras-chave resumo perfluoroalca
Page 7 and 8: Contents Notation List of Tables Li
Page 9 and 10: Notation Abbreviations AAD EoS LCST
Page 11 and 12: List of Tables Table I.1 Average Bo
Page 13 and 14: Table III.6 Adjusted Binary Paramet
Page 15 and 16: Figure II.9 Comparison between corr
Page 17 and 18: Figure III.8 Temperature-density di
Page 19 and 20: Figure III.25 Vapor-phase mole frac
Page 21 and 22: I.1. Fluorine Properties General In
Page 23 and 24: Table I.2. Physicochemical Properti
Page 25 and 26: General Introduction order to compa
Page 27 and 28: General Introduction the numerous a
Page 29 and 30: General Introduction carbon dioxide
Page 31 and 32: General Introduction animals. That
Page 33 and 34: General Introduction Table I.3. Lit
Page 35 and 36: References General Introduction Ban
Page 37 and 38: General Introduction Hildebrand, J.
Page 39 and 40: General Introduction Rowinsky EK. N
Page 41 and 42: II. Part EXPERIMENTAL METHODS, RESU
Page 43 and 44: Experimental Methods, Results and D
Page 49 and 50: Table II.3. (continued) T K ρexp g
Page 51 and 52: ρ / g.cm-3 1.750 1.730 1.710 1.690
Page 53 and 54:
Experimental Methods, Results and D
Page 55 and 56:
I. 3. Vapour pressure I.3.1. Biblio
Page 57 and 58:
I.3.2. Apparatus and Procedure Expe
Page 59 and 60:
I.3.3. Experimental Results and Dis
Page 61 and 62:
Page 63 and 64:
Table II.8. (continued) T K Pexp kP
Page 65 and 66:
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ΔH vap = TΔS vap 2⎛ d ln P ⎞
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I.4. Solubility at atmospheric pres
Page 71 and 72:
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x2 (T,P2) 7.0E-03 6.0E-03 5.0E-03 4
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L 2,1 0.70 0.60 0.50 0.40 0.30 285
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P / MPa 6 5 4 3 2 1 0 P / MPa 14 12
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II.6. Liquid - Liquid Equilibrium I
Page 97 and 98:
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Page 101 and 102:
0 τ β Δ1 2Δ1 [ 1+ B τ + B τ +
Page 103 and 104:
References Experimental Methods, Re
Page 105 and 106:
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Page 109 and 110:
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III.1. Introduction Modeling Most c
Page 113 and 114:
Modeling The pioneering work of Wer
Page 115 and 116:
III.2. Soft-SAFT Model Modeling A S
Page 117 and 118:
Modeling The equation of state is w
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Chain Term Modeling Originally Wert
Page 121 and 122:
Modeling The model is easily extend
Page 123 and 124:
( ) ( ) ∑∑∑ 3 2 2 2 2 qq 32π
Page 125 and 126:
Modeling HRT is a promising theory,
Page 127 and 128:
( ρ) ρ , 0 ≤ ρ ( ρ) 2 Modelin
Page 129 and 130:
III.3. Application to Pure Compound
Page 131 and 132:
Modeling From the optimised paramet
Page 133 and 134:
T / K 400 350 300 250 200 150 100 5
Page 135 and 136:
ln Pvap 1.0E+01 1.0E+00 1.0E-01 1.0
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Modeling Table III.2. Absolute Aver
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Modeling The correlation coefficien
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Pvap (MPa) 4.00 3.50 3.00 2.50 2.00
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Modeling The mixture parameters a a
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Modeling the assumptions made by th
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Modeling between oxygen and perfluo
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xSolute 5.5E-03 5.0E-03 4.5E-03 4.0
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Modeling previous work, dealing wit
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Modeling These results confirm that
Page 155 and 156:
Modeling CO2 binary mixtures using
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Modeling average deviation (AAD) be
Page 159 and 160:
P / MPa 14 12 10 8 6 4 2 0 0 0.2 0.
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Modeling Figures III.16, III.17 and
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Modeling calculations from the orig
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Table III.9. References for VLE exp
Page 167 and 168:
P / MPa 20 18 16 14 12 10 8 6 4 2 0
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Modeling Finally, Figure III.24 pre
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III.4.4. VLE and LLE of Alkane and
Page 173 and 174:
Modeling number of perfluro-n-alkan
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y C6F14 1.0 0.8 0.6 0.4 0.2 0.0 0.0
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P / MPa 0.08 0.07 0.06 0.05 0.04 0.
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P / MPa 0.12 0.10 0.08 0.06 0.04 0.
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Modeling approach based on the meth
Page 183 and 184:
Modeling Blas, F. J.; Vega, L. F.,
Page 185 and 186:
DIPPR, Thermophysical Properties Da
Page 187 and 188:
Modeling Hildebrand, J. H.; Fisher,
Page 189 and 190:
Modeling McCabe, C.; Jackson, SAFT-
Page 191 and 192:
Modeling Poling, B.; Prauznitz, J.;
Page 193 and 194:
Modeling Wertheim, M. S., Fluids wi
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