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Évaluation pour les pays méditerranéens des nouveaux POP<br />

ANNEX I: Overview of use of alternative flame retardants to PentaBDE in several<br />

materials and applications. Source: UNEP, 2009b.<br />

Materials/polymers/resins Inorganic Phosphorus/nitrogen Halogen organic Alternative<br />

alternatives to organic alternatives alternatives to flame<br />

PentaBDE to PentaBDE<br />

PentaBDE retardant<br />

materials<br />

Epoxy resins Aluminium Metallic phosphinates<br />

hydroxide (ATH)<br />

Reactive nitrogen and<br />

Magnesium phosphorus constituents<br />

hydroxide (unspecified)<br />

Ammonium poly<br />

phosphate<br />

DOPO 13<br />

Tetrabromobis Polyethylene<br />

phenol A (reactive) sulphide<br />

Etylenebis<br />

(tetrabromo)<br />

phtalimid<br />

Red phosphorus<br />

Zinc<br />

hydroxystannate<br />

(ZHS), Zinc<br />

stannate (ZS) &<br />

ZHS/ZS-coated<br />

ATH<br />

Polyvinylchloride (PVC) Aluminium<br />

hydroxide (ATH)<br />

Zinc borate<br />

Zincmolybdenum<br />

compounds<br />

(together with<br />

phosphate<br />

esters)<br />

Zinc<br />

hydroxystannate<br />

(ZHS), Zinc<br />

stannate (ZS) &<br />

ZHS/ZS-coated<br />

ATH<br />

Polyurethane (PUR) Ammonium poly<br />

phosphate<br />

Red phosphorus<br />

Tricresyl<br />

phosphate (also<br />

plasticizer)<br />

Melamine (nitrogen<br />

based)<br />

Dimethyl<br />

propyl phosphonate<br />

(DMPP)<br />

Reofos (non-halogen<br />

flame retardant)<br />

13 DOPO=Dihydrooxaphosphaphenanthrene oxide<br />

Tris<br />

(dichloropropyl)<br />

phosphate<br />

Vinylbromide<br />

Bromoalkyl<br />

phosphates<br />

Tetrabromophtalic<br />

anhydride<br />

Tris(chloroethyl)<br />

phosphate<br />

(TCPP) (together<br />

with brominated<br />

polyols or red<br />

phosphorus)<br />

Rigid PVC<br />

is flame<br />

inherent<br />

itself<br />

Intumescent<br />

systems<br />

177<br />

Applications<br />

Circuit boards,<br />

protective<br />

coatings<br />

Cable sheets<br />

Cushioning<br />

materials,<br />

packaging,<br />

padding

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