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CONTINUUM MECHANICS for ENGINEERS

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The entropy production is always positive, which leads to a statement of the<br />

second law in the <strong>for</strong>m of the Clausius-Duhem inequality<br />

d<br />

r qi⋅ni ρηdV<br />

≥ dV − dS<br />

dt∫<br />

∫θ ∫ θ<br />

P P<br />

(5.8-16)<br />

This global <strong>for</strong>m can easily be posed locally by the now-familiar procedures.<br />

Applying the divergence theorem to the heat flux term yields<br />

∫ ∫<br />

∂P<br />

Furthermore, the differentiation of the entropy term is simplified by the fact<br />

that it is a specific quantity (see Section 5.3, Eq 5.3-11). Thus, we write<br />

∫<br />

P<br />

(5.8-17)<br />

and since this must hold <strong>for</strong> all arbitrary portions of the body, and the<br />

integrand is continuous, then<br />

Thus, the local <strong>for</strong>m of the Clausius-Duhem equation is<br />

(5.8-18a)<br />

Often, the gradient of the temperature is written as g i = θ ,i in which case<br />

Eq 5.8-18a becomes<br />

(5.8-18b)<br />

Combining this result with Eq 5.7-13 brings the stress power and internal<br />

energy into the expression, giving a reduced <strong>for</strong>m of the Clausius-Duhem<br />

equation<br />

∂P<br />

qi⋅ni qi<br />

dS = ⎛ ⎞<br />

⎜ ⎟<br />

θ ⎝ θ ⎠ ,<br />

P<br />

ρη˙ − ρ +<br />

θ θ<br />

⎛<br />

⎡<br />

r qj<br />

⎞<br />

⎢ ⎜ ⎟<br />

⎢ ⎝ ⎠<br />

⎣<br />

, j<br />

i<br />

dV<br />

⎤<br />

⎥dV<br />

≥ 0<br />

⎥<br />

⎦<br />

,<br />

ρη˙ − ρ + ρη˙ ρ θ,<br />

θ θ<br />

θ θ θ<br />

⎛ r qj ⎞ r qjj<br />

1<br />

⎜ ⎟ = − + − qj<br />

j ≥0<br />

2<br />

⎝ ⎠<br />

, j<br />

ρθη ρ<br />

θ θ<br />

˙<br />

1<br />

− r+ qii , − qi,<br />

i≥0<br />

ρθη˙ 1<br />

− ρr+<br />

qii , − qigi≥0 θ<br />

ρθη˙ 1<br />

− ρu˙+ Dijσ ij − qigi≥0 θ<br />

(5.8-19)

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