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30<br />
Dynamic wetting transition: avoided critical behavior<br />
G. Delon ∗ , J.H. Snoeijer ∗ ,B. Andreotti ∗ and M. Fermigier ∗<br />
A solid surface can be coated by a thin film when the solid is withdrawn at<br />
constant speed out of a bath of liquid. This dip coating process was analyzed initially<br />
by Landau-Levich.<br />
In a partial wetting situation, there is a threshold velocity below which the meniscusissteadyandthesolidremainsdry.<br />
We investigate the dynamic wetting transition<br />
between the two states : at low velocity, a stable meniscus, at high velocity, an entrained<br />
film.<br />
It has been shown that a receding contact line becomes unstable when the capillary<br />
number exceeds a critical value Cac 1 . In our experiments, liquid entrainment occurs<br />
at a capillary number Ca ∗ which is lower than Cac. The critical behavior expected at<br />
Cac is thus avoided. The threshold velocity coincides precisely with the contact line<br />
velocity above the transition. We explain the occurence of an early transition by the<br />
nucleation of a a capillary ridge (see fig.) which moves ahead of the thin film. The<br />
characteristics of this ridge determine the threshold velocity for liquid entrainment.<br />
We discuss also the influence of the curvature of the solid surface on the wetting<br />
transition.<br />
∗ PMMH,ESPCI, 10 rue Vauquelin, 75005 Paris, France.<br />
1 J. Eggers Phys. Fluids 17, 082106 (2005).<br />
8<br />
z (cm)<br />
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6<br />
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U p<br />
100 µm<br />
Figure 1: (Left) Liquid film (brighter part) entrained by a vertical plate pulled out<br />
of bath of silicone oil. (Right) Time evolution of the ridge profile (vertical cross<br />
sections in the middle of the liquid film. The three oblique lines in this space-time<br />
diagram represent the velocity of the solid plate, the velocity of the contact line and<br />
the velocity of the front between ridge and thin film.<br />
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100<br />
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U cl<br />
300<br />
U j<br />
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t (s)