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Preface The expedition ARK XIX/3 with the German icebreaking RV ...

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C. 2 Geochemical and hydrodynamic investigations at <strong>the</strong> sediment-water<br />

interface<br />

Sauter, E., Baumann, L., Wegner, J., Delius, J.<br />

In close interdisciplinary co-operation <strong>with</strong> <strong>the</strong> benthos biology and geology group <strong>the</strong><br />

geochemical investigations of <strong>the</strong> sedimentary and near-bottom environments at <strong>the</strong><br />

“Hausgarten” area west of Svålbard were performed. Scientific aim is <strong>the</strong> description<br />

of gradients in geochemical parameters close above and below <strong>the</strong> sediment/water<br />

interface. Those gradients are planed to be interpreted in close comparison to benthic<br />

habitat properties (e.g. species distribution and abundances) and <strong>the</strong> geological<br />

setting (e.g. sediment stratification).<br />

For this purpose <strong>the</strong> central “Hausgarten” station at 2500 m water depth amongst <strong>the</strong><br />

stations along <strong>the</strong> east-west depth transect from 1200 to 5500 m depth as well as of<br />

<strong>the</strong> north-south transect at about 2500 m depth have been sampled by multi corer and<br />

bottom water sampler. In addition, having <strong>the</strong> opportunity for targeted sampling and in<br />

situ measurements by means of “Victor 6000”, <strong>the</strong> focus was laid on micro profile<br />

measurements and high precision acoustic current measurements.<br />

Vertical gradients of nutrients, C org content, C/N ratio, porosity and o<strong>the</strong>r geochemical<br />

parameters will be determined from sediment samples taken at <strong>the</strong> stations indicated<br />

in Tab. C2-1 in order to characterize <strong>the</strong> geochemical milieu in which <strong>the</strong> organisms,<br />

analysed by <strong>the</strong> biology group, live. <strong>The</strong> oxygen concentration was determined by<br />

Winkler titration, immediately after sampling of <strong>the</strong> supernatant bottom water and <strong>the</strong><br />

bottom water sampler, respectively (Tab. C2-1). Nutrient gradients will also be<br />

analysed from <strong>the</strong> bottom water samples in order to quantify interfacial solute fluxes<br />

and rates metabolism.<br />

Special emphasis was laid on <strong>the</strong> exact measurement of oxygen micro gradients<br />

below <strong>the</strong> sediment/water interface. For this purpose a deep-sea micro profiler (MIC)<br />

has been modified to fit into <strong>the</strong> shuttle lander and to be operated by <strong>the</strong> ROV at <strong>the</strong><br />

seafloor (Fig. C2-1). A switch operated by <strong>the</strong> ROV allows keeping <strong>the</strong> system down<br />

at <strong>the</strong> sea floor for several individual measurements. Due to its small dimensions MIC<br />

can be placed precisely by <strong>the</strong> ROV. Thus, <strong>the</strong> system was deployed at one of <strong>the</strong><br />

disclusion experiment sites, where <strong>the</strong> sediment was covered by a cage for 4 years.<br />

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