02.09.2014 Views

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

φ<br />

T<br />

=ν 4<br />

(5-53b)<br />

φx = −ν 1<br />

(5-53c)<br />

where<br />

φ<br />

b<br />

, φ t<br />

<strong>and</strong> φx<br />

are the flow <strong>of</strong> benzyl alcohol, toluene, <strong>and</strong> biomass into the<br />

system (C-mol/L h), respectively.<br />

Again, if the well-known assumption (Roels, 1983) is made that no net accumulation <strong>of</strong><br />

NADH 2 <strong>and</strong> ATP takes place, the Equations (5-47a) <strong>and</strong> (5-47b) can be obtained:<br />

− α b<br />

⋅ν<br />

+ δ ⋅ν<br />

0<br />

(5-53d)<br />

1 1 4<br />

=<br />

13 1<br />

.084 ⋅ν + ν<br />

2<br />

−ν<br />

3<br />

− ν = 0<br />

(5-53e)<br />

7 7<br />

1<br />

4<br />

Therefore, by coupling Equations (5-53a) to (5-53e), the relation between the flows <strong>of</strong><br />

benzyl alcohol, toluene <strong>and</strong> biomass in steady state continuous mode can be expressed<br />

by:<br />

φ ⋅ Y + φ ⋅Y<br />

= ( −φ<br />

) + m C<br />

(5-54)<br />

b<br />

max<br />

bx<br />

T<br />

max<br />

tx<br />

x<br />

bt<br />

x<br />

Coupling with the parameters obtained from Equations (5-38) <strong>and</strong> (5-39), the following<br />

results can be obtained:<br />

1 7( K + 1.274δ<br />

)<br />

=<br />

= 0.44 (5-54a)<br />

max<br />

Y bx<br />

(13δ<br />

)<br />

<strong>and</strong><br />

max 12δ<br />

Y tx<br />

=<br />

= 0.414 (5-54b)<br />

7( K + 1.274δ<br />

)<br />

In Equation (5-54),<br />

( − φ ) = μC<br />

, therefore, the concentration <strong>of</strong> biomass can be<br />

x<br />

x<br />

acquired by Equation (5-55):<br />

C<br />

x<br />

1 max<br />

tx<br />

bt<br />

= max<br />

⋅ ( φb<br />

⋅Ybx<br />

+<br />

T<br />

⋅Y<br />

( μ + m )<br />

φ<br />

)<br />

(5-55)<br />

117

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!