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Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

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Biomass <strong>and</strong> benzyl<br />

alcohol concentrations,<br />

g/L<br />

2<br />

1.5<br />

1<br />

0.5<br />

0<br />

DO<br />

X<br />

Cb<br />

0 0.1 0.2 0.3<br />

Dilution rate, h -1<br />

8<br />

7<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

Dissolved Oxygen, mg/L<br />

Figure 5-19. Continuous removal <strong>of</strong> toluene <strong>and</strong> benzyl alcohol<br />

(C b0 = 0.6 g/L; y t,in = 12.0 mg/L)<br />

Figure 5-20 reveals that at a benzyl alcohol concentration <strong>of</strong> 1.2 g/L, the system<br />

could be operated at steady state for dilution rates up to 0.11 h -1 with a toluene gas inlet<br />

concentration <strong>of</strong> 5 mg/L. When dilution rates are higher than 0.11 h -1 , the DO level<br />

drops to a value that is below the critical value for bacteria growth. Thus oxygen mass<br />

transfer becomes a rate–limiting factor at these conditions while cells are washed out,<br />

<strong>and</strong> no consumption occurs. The sharp corner observed in the predicted DO curve<br />

shown in Figure 5-20 occurs due to the program setting the biomass concentration to<br />

zero. The prediction results also indicate that at a benzyl alcohol feed concentration <strong>of</strong><br />

148

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