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Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

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used to degrade ethanol vapours <strong>and</strong> a maximum elimination capacity <strong>of</strong> 185 g ethanol<br />

h -1 m -3 <strong>of</strong> reactor volume was achieved (Shim et al., 1995). Critical ethanol loading,<br />

defined as the maximum loading to achieve greater than 99% elimination at various<br />

residence times have been determined, with typical maximum ethanol loadings <strong>of</strong> 180<br />

<strong>and</strong> 109 g ethanol h -1 m -3 <strong>of</strong> reactor volume at residence times <strong>of</strong> 12.4 <strong>and</strong> 1.5 minutes,<br />

respectively.<br />

The performance <strong>of</strong> a continuously operated bi<strong>of</strong>ilter for removal <strong>of</strong> ethanol<br />

vapour at relatively high inlet concentrations was examined <strong>and</strong> a maximum elimination<br />

capacity <strong>of</strong> 195 g m -3 h -1 was achieved (Arulneyam <strong>and</strong> Swaminathan, 2000).<br />

Concentrations as high as 10 g m -3 could be degraded at a gas velocity <strong>of</strong> 15 m h -1 ;<br />

however, higher concentrations <strong>and</strong> higher gas flow rates reduced the removal<br />

efficiency due to mass transfer limitations <strong>and</strong> short residence times. They also<br />

observed that at all gas flow rates, the elimination capacity increased with increasing<br />

ethanol concentration until a threshold concentration after which it remained constant.<br />

<strong>Ethanol</strong> vapour was removed using a bioreactor (2.7 m 3 ) packed with a novel microbial<br />

support consisting <strong>of</strong> a highly porous inorganic matrix coated with a thin layer <strong>of</strong><br />

activated carbon (Cioci et al., 1997). The plant was operated continuously for two<br />

months, <strong>and</strong> the inlet waste air was maintained at a temperature <strong>of</strong> 20 0 C <strong>and</strong> a gas flow<br />

rate <strong>of</strong> 200 m 3 h -1 throughout the experimentation. The ethanol concentration was varied<br />

between 90 <strong>and</strong> 2200 mg m -3 , <strong>and</strong> removal efficiencies ranging from 80 to 99.9% were<br />

obtained. An aerobic biodegradation with a concentration <strong>of</strong> 1 g ethanol m -3 was studied<br />

in an experimental bi<strong>of</strong>ilter using wood bark as a packing material (Ramirez-Lopez et<br />

al., 2000). With the addition <strong>of</strong> nutrient, after 45 days <strong>of</strong> continuous bi<strong>of</strong>ilter operation<br />

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