- Page 1 and 2: BIOREMEDIATION OF VOLATILE ORGANIC
- Page 3 and 4: ABSTRACT The mass transfer of ethan
- Page 5 and 6: effect on the growth of P. putida.
- Page 7 and 8: ACKNOWLEDGMENT Of the countless peo
- Page 9 and 10: TABLE OF CONTENTS PERMISSION TO USE
- Page 11 and 12: 4.3 Batch Growth on Ethanol and Ben
- Page 13 and 14: LIST OF FIGURES Figure 3-1. Schemat
- Page 15 and 16: Figure 5.3 (b) Simulation of ethano
- Page 17 and 18: Figure 5-16. Continuous removal of
- Page 19 and 20: NOMENCLATURE a - Interfacial area,
- Page 21 and 22: CHAPTER ONE - INTRODUCTION 1.1 Air
- Page 23: esults (van Groenestijn and Hesseli
- Page 27 and 28: Table 2.2 VOC Emissions in the U.S.
- Page 29 and 30: (paint shop effluents, for instance
- Page 31 and 32: combustion provides 70 to 90% air p
- Page 33 and 34: used to degrade ethanol vapours and
- Page 35 and 36: g m -3 . This would suggest that th
- Page 37 and 38: treatment, This excessive biomass f
- Page 39 and 40: The simultaneous degradation of tol
- Page 41 and 42: emoves only water-soluble gases. Wa
- Page 43 and 44: 2.2.6 Pseudomonas It is well known
- Page 45 and 46: 2.3.2 Growth Models with Inhibition
- Page 47 and 48: where µ is the total specific grow
- Page 49 and 50: 2.4.1 Batch Reactor In a batch reac
- Page 51 and 52: discharged from the other end. The
- Page 53 and 54: element solution consisted of (gram
- Page 55 and 56: growth on ethanol, 20-48 hours for
- Page 57 and 58: Gas phase samples of toluene were c
- Page 59 and 60: Inlet sampler Exit sampler To fume
- Page 61 and 62: Once the oxygen meter indicated a s
- Page 63 and 64: centrifuged and the supernatant was
- Page 65 and 66: where k L a is the volumetric mass
- Page 67 and 68: Figure 4-2a shows ethanol liquid co
- Page 69 and 70: coefficient (k L a) in the well-mix
- Page 71 and 72: calculated by dividing the gas volu
- Page 73 and 74: Average bubble diameter, mm 8 7 6 5
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Bioflow III bioreactor. Equation (4
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3.5 y=Ln(S0/S) 3 2.5 2 1.5 1 y = 12
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Ethanol and biomass concentration,
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4.3.2 Batch Growth on Benzyl Alcoho
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Biomass and benzyl alcohol concentr
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ethanol loading was beyond the maxi
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Table 4-2. Comparison of bioremedia
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Biomass, benzyl alcohol and toluene
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4.4.3 Toluene-ethanol Bioremediatio
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Substrate and biomass concentration
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Biomass and benzyl alcohol concentr
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Biomass and benzoic acid concentrat
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ethanol. These results clearly indi
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CHAPTER FIVE - MATHEMATICAL MODELIN
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The stoichiometry of the biomass sy
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synthesis and in the ethanol catabo
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1 max Y ex = − 0.635 + 2δ + K 3
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Biomass Eq.5-18 Benzyl Alcohol Eq.5
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r x r N -1.27 -1 0 1 0 0 -0.2 0 0 2
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φ = −θ b ⋅ν (5-31) φ b = 1.
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The data sets used to evaluate the
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Figures 5.4a and 5.4b present 95% c
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Ethanol and biomass concentration (
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Ethanol measured (C-mol/L) 0.3 0.25
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Figures 5.5 (a-d) demonstrate the s
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Benzyl alcohol and biomass concentr
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Benzyl alcohol measured (C-mol/L) 0
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x = 5 ∑ i= 1 x N i (5-40) where x
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ethanol in a steady state mode is l
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where ν 1 , ν 2 , ν 3, ν 4 are
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Biomass concentration, g/L 1.5 1 0.
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φ T =ν 4 (5-53b) φx = −ν 1 (5
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In this study, a metabolic model ha
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Equations (5-34) and (5-35) and the
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ATP 1 = Y max ATP r x + m ATP ⋅ C
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Ethanol, biomass and ammonium conce
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Figure 5-13a shows that the lower t
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Biomass, substrate concentrations,
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C e DKe = (5-63) μ − D m Equatio
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corresponds with the value associat
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Biomass and ethanol concentrations
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than 4.0 mg/L at all dilution rates
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Biomass, benzyl alcohol and ammonia
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negligible ( y out , e = 0) , and e
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Figure 5-17 shows the results at a
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Biomass Concentrations, g/L 3.5 3 2
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C x ( 1 max Q max = ⋅{ D( Cb0 −
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1.2 g/L, the system could not be op
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The continuous models can capture a
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• Air stripping coefficients obta
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Toluene acts as an inhibitor on the
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Bruining, W. J., G. E. H. Joosten,
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Falatko, D. M., and J. T. Novak, 19
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Keuning, S., and D. Jager, 1994.
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Orshansky, F., and N. Narkis, 1997.
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Togna, A. P, M. Singh, 1994. “Bio
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APPENDIX A. Important Metabolic Pat
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III. Toluene Pathway (Adapted from
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Appendix B. Calibration Procedure a
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Figure B-2. Pseudomonas putida (ATC
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Appendix B-3. Calibration of Chemic
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Appendix B-4. Calibration of Toluen
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Appendix C. Experimental Results: A
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Probe response time, s 12 10 8 6 4
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Appendix C-2. Fed-batch Operation B
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Appendix D: Mathematical Solutions
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The microscopic model allows the fo
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13δ Y o , = 0.585 2 x = (D-24) (8K
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2 σ = −1.3E − 06 (E-11) Y xe Y
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Biomass, ethanol, and acetic acid c