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Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

Experimental Study of Biodegradation of Ethanol and Toluene Vapors

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y=Ln[(S*-S)/(S*-S0)]<br />

3.5<br />

3<br />

2.5<br />

2<br />

1.5<br />

1<br />

0.5<br />

0<br />

y = 0.0010t<br />

R 2 = 0.9978<br />

y = 0.00088t<br />

R 2 = 0.99642<br />

y = 0.00084t<br />

R 2 = 0.99709<br />

0 1000 2000 3000 4000<br />

Time, sec<br />

300 rpm<br />

450 rpm<br />

600 rpm<br />

Figure 4-1 Determination <strong>of</strong> toluene mass transfer coefficients<br />

<strong>Ethanol</strong> mass transfer results demonstrated that at inlet ethanol concentrations <strong>of</strong><br />

80.0 to 92.0 mg/L, air flow rates up to 3.8 L/min <strong>and</strong> mixing speeds <strong>of</strong> 135 to 600 RPM,<br />

ethanol was completely removed from the air streams by the aqueous phase in the<br />

reactor. <strong>Ethanol</strong> liquid concentrations can then be calculated from the material balance:<br />

dS<br />

dt<br />

Q( C<br />

g, in<br />

− C<br />

g,<br />

out<br />

= (4-3)<br />

V<br />

e<br />

)<br />

where S e is ethanol concentration in the liquid phase (g/L), t is time in minutes, V is the<br />

working volume <strong>of</strong> the reactor (L), Q is the air flow rate (L/min), <strong>and</strong> C g,in (g/Lair) <strong>and</strong><br />

C g,out (g/Lair) are the ethanol concentrations in the inlet <strong>and</strong> outlet air streams,<br />

respectively.<br />

46

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