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State of the Bay Report 2011-Final.pdf - Anchor Environmental

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<strong>State</strong> <strong>of</strong> Saldanha <strong>Bay</strong> & Langebaan Lagoon <strong>2011</strong><br />

Sediments<br />

5.4.1 Historical data<br />

Dramatic increases in trace metal concentrations, especially those <strong>of</strong> cadmium and lead<br />

after <strong>the</strong> start <strong>of</strong> <strong>the</strong> iron ore export from Saldanha <strong>Bay</strong>, raised concern for <strong>the</strong> safety and health <strong>of</strong><br />

marine organisms, specifically those being farmed for human consumption (mussels and oysters). Of<br />

particular concern were <strong>the</strong> concentrations <strong>of</strong> cadmium which exceeded <strong>the</strong> lower toxic effect level<br />

published by <strong>the</strong> NOAA. Both lead and copper concentrates are exported from Saldanha <strong>Bay</strong> and it<br />

was hypo<strong>the</strong>sised that <strong>the</strong> overall increase <strong>of</strong> metal concentrations was directly associated with <strong>the</strong><br />

export <strong>of</strong> <strong>the</strong>se metals. The concentrations <strong>of</strong> twelve different metals have been evaluated on<br />

various occasions in Saldanha <strong>Bay</strong>; however, <strong>the</strong> overall fluctuations in concentrations are similarly<br />

reflected by several key metals throughout <strong>the</strong> time period. For <strong>the</strong> purposes <strong>of</strong> this report, four<br />

metals that have <strong>the</strong> greatest potential impact on <strong>the</strong> environment were selected from <strong>the</strong> group.<br />

These are cadmium (Cd), lead (Pb), copper (Cu) and nickel (Ni).<br />

The earliest data on metal concentrations in Saldanha <strong>Bay</strong> were collected in 1980, prior to<br />

<strong>the</strong> time at which iron ore concentrate was first exported from <strong>the</strong> ore terminal. The sites sampled<br />

were 2 km north <strong>of</strong> <strong>the</strong> Multi-purpose Quay (Small <strong>Bay</strong>) and 3 km south <strong>of</strong> <strong>the</strong> Multi-purpose Quay<br />

(Big <strong>Bay</strong>) and metals reported on included lead (Pb), cadmium (Cd) and copper (Cu). Concentrations<br />

<strong>of</strong> <strong>the</strong>se metals in 1980 were very low, well below <strong>the</strong> sediment toxicity thresholds (Figure 5.21,<br />

Figure 5.25, Figure 5.23 and Figure 5.27). Subsequent sampling <strong>of</strong> metals in Saldanha <strong>Bay</strong> (for which<br />

data is available) only took place nearly 20 years later in 1999. During <strong>the</strong> period between <strong>the</strong>se<br />

sampling events, a considerable volume <strong>of</strong> ore had been exported from <strong>the</strong> <strong>Bay</strong>, areas <strong>of</strong> Saldanha<br />

<strong>Bay</strong> had been dredged (1997/98), and <strong>the</strong> Mussel Farm and <strong>the</strong> small craft harbour (Yacht Club<br />

Basin) had been established (1984). As a result <strong>of</strong> <strong>the</strong>se activities, <strong>the</strong> concentrations <strong>of</strong> metals in<br />

1999 were very much higher (up to 60 fold higher) at all stations monitored (Figure 5.21, Figure 5.25,<br />

Figure 5.23 and Figure 5.27). This reflects <strong>the</strong> accumulation <strong>of</strong> metals in <strong>the</strong> intervening 20 years,<br />

much <strong>of</strong> which had recently been re-suspended during <strong>the</strong> dredging event and had settled in <strong>the</strong><br />

surficial (surface) sediments in <strong>the</strong> <strong>Bay</strong>. Concentrations <strong>of</strong> most metals in Saldanha <strong>Bay</strong> were<br />

considerably lower in <strong>the</strong> period 2000-2010, although nowhere near levels measured in 1980. This<br />

closely mirrors changes in <strong>the</strong> proportion <strong>of</strong> mud in <strong>the</strong> sediments, and most likely reflects <strong>the</strong><br />

removal <strong>of</strong> fine sediments toge<strong>the</strong>r with <strong>the</strong> trace metal contaminants from <strong>the</strong> <strong>Bay</strong>, by wave and<br />

tidal action. Monitoring surveys between 2001 and <strong>2011</strong>, revealed that with a few exceptions, metal<br />

concentrations had continued to decrease in Saldanha <strong>Bay</strong> and were much reduced from <strong>the</strong><br />

exceptionally high concentrations recorded in 1999 and 2000.<br />

5.4.2 Analysis and results for <strong>2011</strong><br />

Sediments were analyzed for concentrations <strong>of</strong> aluminium (Al), iron (Fe), copper (Cu),<br />

cadmium (Cd), nickel (Ni), lead (Pb) and zinc (Zn). For <strong>the</strong> purpose <strong>of</strong> this report only <strong>the</strong> data for Cd,<br />

Cu, Pb, Ni and Fe are presented as <strong>the</strong>se are <strong>the</strong> metals deemed to pose <strong>the</strong> greatest threat to <strong>the</strong><br />

health <strong>of</strong> <strong>the</strong> marine environment. Metals in <strong>the</strong> sediments were analyzed by Scientific Services<br />

using a Nitric Acid (HNO 3 ) / Perchloric Acid (HClO 3 )/ Hydrogen Peroxide (H 2 O 2 )/ Microwave digestion<br />

and JY Ultima Inductively Coupled Plasma Optical Emission Spectrometer. The concentrations <strong>of</strong><br />

metals in <strong>the</strong> sediments <strong>of</strong> Saldanha <strong>Bay</strong> and Langebaan Lagoon in <strong>2011</strong> are shown in Table 5.3. The<br />

concentrations <strong>of</strong> trace metals at <strong>the</strong> sites sampled in <strong>2011</strong> were used to interpolate <strong>the</strong> metal<br />

concentrations over <strong>the</strong> full extent <strong>of</strong> <strong>the</strong> <strong>Bay</strong> and Lagoon using GIS s<strong>of</strong>tware. These interpolations<br />

provide an indication <strong>of</strong> <strong>the</strong> spatial variation in <strong>the</strong> concentration <strong>of</strong> <strong>the</strong> various trace metals in <strong>the</strong><br />

<strong>Bay</strong> and <strong>the</strong> Lagoon.<br />

105<br />

ANCHOR<br />

e n v i r o n m en t a l

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