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State of the Bay Report 2011-Final.pdf - Anchor Environmental

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<strong>State</strong> <strong>of</strong> Saldanha <strong>Bay</strong> & Langebaan Lagoon <strong>2011</strong><br />

Sediments<br />

Enrichment factors calculated for both Small <strong>Bay</strong> and Big <strong>Bay</strong> indicated that <strong>the</strong> Cd levels<br />

recorded in <strong>2011</strong> exceeded pre-development levels at all sites. The Yacht Club Basin was<br />

approximately 28 times higher, while <strong>the</strong> multi-purpose quay site was 16 time higher (Table 5.4).<br />

The results <strong>of</strong> <strong>2011</strong> indicate that <strong>the</strong> concentrations <strong>of</strong> Cd have increased at all sites within Small<br />

<strong>Bay</strong>. Fur<strong>the</strong>rmore Cd was not detected in Big <strong>Bay</strong> or Langebaan Lagoon in 2010, however; in <strong>2011</strong><br />

Cd was detected at all sites, with <strong>the</strong> exception <strong>of</strong> two in Langebaan Lagoon. This indicates a system<br />

wide increase since 2010. Given <strong>the</strong> relatively pristine nature <strong>of</strong> some <strong>of</strong> <strong>the</strong> sites (sou<strong>the</strong>rn lagoon)<br />

and <strong>the</strong> great distance from storm water drains, it is likely that this increase is <strong>the</strong> result <strong>of</strong> natural<br />

fluctuations. Indeed, Cd concentrations have been found to occur in naturally high concentrations in<br />

<strong>the</strong> organic rich sediments <strong>of</strong> <strong>the</strong> near shore zone <strong>of</strong> <strong>the</strong> sou<strong>the</strong>rn Benguela (including Saldanha <strong>Bay</strong><br />

area). It is important to note, however, that Cd levels did not increase consistently and in some<br />

areas, notably <strong>the</strong> Yacht Club Basin, multi-purpose quay, Salamander <strong>Bay</strong> and Donkergat, <strong>the</strong><br />

increase is most likely attributable to anthropogenic activities in close proximity. Fur<strong>the</strong>rmore it<br />

must be noted that nei<strong>the</strong>r Salamander <strong>Bay</strong> nor Donkergat were tested for trace metals prior to<br />

<strong>2011</strong> so it is unclear as to whe<strong>the</strong>r contamination occurred during 2009 or 2010.<br />

5.4.2.2 Copper<br />

Copper (Cu) is used as a biocide in antifouling products as it very effective for killing marine<br />

organisms that attach <strong>the</strong>mselves to <strong>the</strong> surfaces <strong>of</strong> boats and ships. Anti-fouling paints release Cu<br />

into <strong>the</strong> sea and can make a significant contribution to Cu concentrations in <strong>the</strong> marine environment<br />

(Clark 1986). Concentrations <strong>of</strong> Cu were detected at most sites in Saldanha <strong>Bay</strong> and Langebaan<br />

Lagoon in <strong>2011</strong> (Table 5.3), with <strong>the</strong> exception <strong>of</strong> three sites in Big <strong>Bay</strong> and two in Langebaan<br />

Lagoon. All sites with <strong>the</strong> exception <strong>of</strong> <strong>the</strong> Yacht Club Basin, <strong>the</strong> multi-purpose quay and Salamander<br />

<strong>Bay</strong> had relatively low concentrations <strong>of</strong> Cu. The concentration <strong>of</strong> Cu at <strong>the</strong> Yacht Club Basin<br />

exceeded <strong>the</strong> ERL.<br />

The Yacht Club Basin had dramatically higher normalized Cu:Al ratio compared to o<strong>the</strong>r sites.<br />

This area is subject to high boating activity. The input <strong>of</strong> Cu at this site may thus be related to <strong>the</strong><br />

use <strong>of</strong> antifouling paints, which characteristically have a high Cu content, and <strong>the</strong> sheltered nature <strong>of</strong><br />

this site. O<strong>the</strong>r sites with high Cu:Al ratios included SB2, SB3, SB14 (multi-purpose quay) and S1<br />

(Salamander <strong>Bay</strong>). The high ratios at SB14 are most likely attributable to a combination <strong>of</strong> <strong>the</strong><br />

depositional nature <strong>of</strong> <strong>the</strong> site and export and shipping activities, while that in Salamander <strong>Bay</strong> may<br />

to be related to boating and, in all likelihood, <strong>the</strong> recent dredging activities. There is no apparent<br />

reason for <strong>the</strong> elevated Cu:Al ratios found at SB2 and SB3.<br />

Concentrations <strong>of</strong> Cu are 99 and 37 times greater than <strong>the</strong> historical average at sites SB1 and<br />

SB14 respectively (Yacht Club Basin and Multi-purpose Quay). These sites are both depositional<br />

zones for organic matter and are also associated with a high degree <strong>of</strong> boating/shipping activity. The<br />

combination <strong>of</strong> boating activities as well at as <strong>the</strong> reduction <strong>of</strong> currents are most likely <strong>the</strong> primary<br />

contributors to this long-term build up <strong>of</strong> Cu at <strong>the</strong>se sites.<br />

Figure 5.23 shows <strong>the</strong> temporal variation in Cu concentrations within Saldanha bay<br />

sediments. As with all <strong>the</strong> o<strong>the</strong>r metals in Saldanha <strong>Bay</strong> sediments, Cu concentrations peaked in<br />

1999 after <strong>the</strong> major 1997 dredging event. There was a subsequent decline in Cu concentrations<br />

over <strong>the</strong> period 1999-2004 at <strong>the</strong> Mussel Farm, Channel end <strong>of</strong> <strong>the</strong> ore terminal, at <strong>the</strong> Multipurpose<br />

quay, and within Big <strong>Bay</strong>. The concentrations <strong>of</strong> Cu in Big <strong>Bay</strong> and at <strong>the</strong> Mussel Farm have<br />

remained low (

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