rok 2007 - Fakulta chemickej a potravinÃ¡rskej technolÃ³gie

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DEPARTMENT OF CHEMICAL PHYSICS Head of Department: Assoc. Prof. Pavol Fedorko, PhD. (since 1.9.2007) Telephone: ++421259325681 Fax: ++421252493198 E-mail: pavol.fedorko@stuba.sk Assoc. Prof. Viliam Laurinc, PhD. (till 31.8.2007) I. STAFF Full Professors: Fedor Valach, PhD., DSc. Associate Professors: Pavol Fedorko, PhD.; Oľga Holá, PhD.; Viliam Laurinc, PhD.; Vladimír Lukeš, PhD. Assistant Professors : Július Annus; Ladislav Bušovský; Miroslav Tokarčík, PhD.; Daniela Žilinská; Michal Ilčin Research Fellows: Tibor Pálszegi, PhD. (till 31.8.2007) PhD Students: Michal Ilčin; Ján Rimarčík (since 1.10.2007), Roland Šolc Technical staff: Anton Adamko II. TEACHING AND RESEARCH LABORATORIES A. Teaching laboratories: Laboratory of Physics I. Laboratory of Physics II. B. Research laboratories: Laboratory of X-ray Diffraction Laboratory of Electrical Properties Laboratory of Gamma Radiation Source Laboratory of Computational Chemical Physics III. TEACHING A. Undergraduate Study: 1. semester (Bc) Seminar in Basic Physics 0/2/0 Bušovský, Bučinský, Gál, Gróf, Lukeš 1. semester (Bc) Physics I 2/2/0 Physics Laboratory I. 0/0/2 Annus Bušovský, Fedorko, Holá, Laurinc, Lukeš, Tokarčík, Valach, Žilinská 2. semester(Bc) Physics II. 2/2/0 Bušovský, Fedorko, Holá, Laurinc, Lukeš, Tokarčík, Valach, Žilinská Physics Laboratory II. 0/0/2 Annus, Bučinský, Gál, Gróf, Ilčin, Lukeš, Olejníková, Pálszegi, Tokarčík, Žilinská 5. semester (Bc) Modelling of the Molecular Properties 0/2/0 Laurinc, Lukeš, Ilčin 2. semester (MSc) Statistical Thermodynamics 2/1/0 Laurinc, Lukeš 108
B. PhD Study: Biophysics I 2/0/0 Valach IV. CURRENT RESEARCH PROJECTS A. VEGA Project No 1/3572/06 Molecular modelling of the structural fragments containing the transition element atoms in the crystal structures of metalloproteins (Fedor Valach) Methods development for the structure solution of fragments involved in the crystal structures of metalloproteins. Molecular modelling of the structural fragments and quantification of their basicity properties. Structural correlations determination of hydrogen bonds and their structural interpretation for the crystal structures of organic, organometallic and coordination compounds. Prediction of valence-bond structure of anionic fragments in the crystals of proteins. Determination and interpretation of the correlations between the metal-ligand bond lengths in the structures of metalloproteins. The criteria development for reliability testing of the protein crystal structures solved from the X-ray and synchrotron diffraction data. Project duration: from 01.01.2006 to 31.12.2008 B. VEGA Project No 1/3036/06 Research of electro-optical properties of novel organic materials as precursors with potential application in electronic and nanotechnology (Vladimír Lukeš) Quantum-chemical study (at the ab initio, DFT and semiempirical levels) of the electronic structure and properties of benzenoid and heterocyclic compounds of furane, thiophene, pyrrole, imidazole and pyrazine derivatives with potential electro- and photoactive properties will be performed. The basic relations between structure (e.g. conformations, effective conjugation length, effect of substitutents), microscopic quantities (dipole moments, polarizabilities, hyperpolarizabilies, HOMO-LUMO separation) and absorption and luminescence spectral characteristics will be investigated. A selection of new molecules which are perspective candidates for electrooptical applications and nano-technique will be proposed on the basis of this research. Project duration: from 01.01.2006 to 31.12.2008 C. VEGA Project No 1/2021/05 Physical properties of conducting polymers, conducting polymer nanocomposites and new conjugated systems (Pavol Fedorko) The project deals with two representatives of the conducting polymers, doped polyaniline and doped substituted polythiophene gels, in which the effect of the structural disorder on the electrical properties is studied. In doped polyaniline, disorder is created by thermal and irradiation aging of the material and by adding plasticizers. This also gives information useful from the application point of view. In the frame of this part of the project, the metallic character of the conductivity of doped polyaniline is investigated more in detail. In substituted polythiophene gels, the conformational state of the polymer network and thus the degree of the structural disorder is varied by swelling in solvents and the dependence of the conductivity of the gel on its swelling ratio is studied. Preparation and properties of conducting polymer nanocomposites as materials enlarging the application potential of the conducting conjugated systems are also studied, using polypyrrole covered nanoparticles and carbon nanotubes as conducting fillers. Theoretical modeling and design of new aromatic and heteroaromatic conjugated systems with properties interesting from the point of view of applications in molecular electronics are also part of the project. Project duration: from 01.01.2005 to 31.12.2007 E. APVT Project No 20-005004 Study of stabilisers in polymer matrices – relation between their structure and stabilising effects (Vladimír Lukeš) Project is oriented on finding suitable (environment-friendly and non-toxic) antioxidants and their concentration relations which are necessary for effective stabilization of polymers (e.g. polyisoprene, PVC, polyurethane, etc.). The stability of polymers with selected additives is experimentaly investigated (DSC, spectral measurements). The materials suitable for application in medicine and food industry are subjected to the gamma irradiation and the irradiation effect is investigated. As a part of our research, the dependence between effect and structure of used antioxidants is also studied. Project duration: from 01.01.2005 to 31.12.2007 109
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ANNUAL REPORT 2007 Faculty of Chemi
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DEPARTMENT OF ANALYTICAL CHEMISTRY
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IV. CURRENT RESEARCH PROJECTS A. VE
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I. APVV Project -20-035205: Develop
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B. International Cooperation Instit
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Zapadlo, M. Palacky University, Olo
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Lehotay, J. Pharmaceutical Faculty
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Bratislava, Slovak Republic : 27th
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In: Acta Crystallographica Section
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[30] Hroboňová, K., Lehotay, J.,
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Slovak Republic, 2007, A10. ISBN 98
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prístupov. In: Syntéza a analýza
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DEPARTMENT OF NMR SPECTROSCOPY AND
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Duslo Šaľa ZoD Ing. J.Uhlár, PhD
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INSTITUTE OF INORGANIC CHEMISTRY, T
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1. semester (MSc) Laboratory Practi
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APVT Project APVT-20-005504 Synthes
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F. Visits of Staff Members and Post
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[2] Bienko, A., Klak, J., Mrozinski
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konference Vodárenská biologie 20
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IV. CURRENT RESEARCH PROJECTS VEGA
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J. Híveš Slovak Chemical Society
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In 59. Zjazd chemických spoločnos
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Technology of ceramics 2/0/0 Smrčk
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978-80-8073-806-8 - Hutnícka fakul
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DEPARTMENT OF BIOCHEMISTRY AND MICR
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IV. CURRENT RESEARCH PROJECTS APVT
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IV. CURRENT RESEARCH PROJECTS Conju
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Kvasnička Vladimír Kvasnička Vla
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Slezská univerzita. - ISBN 978-80-
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DEPARTMENT OF ORGANIC CHEMISTRY Hea
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APVV project LPP-0238-06 Asymmetric
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Synkola, Bratislava Duslo, Šaľa S
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Považanec František Slovak Societ
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B. Graduate Theses (MS Degree) for
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[11] Hýrošová E., Fišera Ľ., M
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products. To substantial products o
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Hronec M., Horváth B., Krejčová
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DEPARTMENT OF PETROLEUM TECHNOLOGY
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VÚRUP, j. s. co., Bratislava Hudec
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STU v Bratislave, 2007. - ISBN 978-
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Determination of filler/modifier an
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Hudec I. 11 th International Semina
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discharge type atmospheric plasma i
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D. VEGA project 1/2475/05 (Anton Ma
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B. Undergraduate Study: Technology
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Institut Royal du Patrimoine Artist
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[3] Gilan, A., Mikula, M.: Lesk pap
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Paper Technology I. 3/0 Šutý Chem
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E. Visitors from abroad Name Organi
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Pulp and Paper 2007. 30.-31.10.2007
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VI. COOPERATION A. Cooperation in S
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E. Visitors from abroad Name Organi
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Baran, D. Olejník, P. Kajanová J.
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Chapter or pages in book [1] Lauren
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