Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

XCONTENTS4.3 Gas chromatography ..........................4.3.1 Introduction ...........................4.3.2 Carrier gases ...........................4.3.3 Columns .............................4.3.4 Programmed temperature gas chromatography (PTGC) . . . . . . . . .4.3.5 Detectors .............................4.3.6 Product identification and trapping . . . . . . . . . . . . . . . . .4.3.7 Sampling and quantitative estimation . . . . . . . . . . . . . . .4.4 Spectroscopic methods .........................4.4.1 Introduction ...........................4.4.2 uv, visible and IR .........................4.4.3 Electron spin resonance ......................4.4.4 Mass spectrometry ........................4.4.5 Optical pumping .........................4.5 Other methods .............................4.5.1 Polarography ...........................4.5.2 Polarimetry ...........................4.5.3 Conductance measurements ....................4.5.4 Thermal conductivity ........................4.5.5 Calorimetry ............................4.5.6 Ultrasonic absorption measurements .................4.5.7 Gas density balance ........................4.5.8 Quartz fibre manometer ......................4.5.9 Interferometry and refractometry ..................4.5.10 Dielectric constant .........................REFERENCES ..................................Chapter 2 (D . N . HAGUE)1979797981828585888889919296969696919197101101102102103104Experimental methods for the study of fast reactions ............. 112INTRODUCTION ................................ 1121 . FLASH PHOTOLYSIS AND PULSE RADIOLYSIS ................... 1181.1 Flash photolysis ............................ 1181.1.1 Applications of flash photolysis . . . . . . . . . . . . . . . . . . . 1201.2 Pulse radiolysis ............................. 1211.2.1 The hydrated electron ....................... 1222 . snoa TUBE AND ABIABATIC COMPRESSION ................... 1232.1 The hydrogen/oxygen reaction ...................... 1273 . CHEMICAL RELAXATION METHODS ....................... 1283.1 The relaxation time ........................... 1283.2 Step.function. or transient methods .................... 1333.2.1 Temperature-jump ........................ 1343.2.2 Applications of T-jump ....................... 1353.3 Stationary methods ........................... 1373.3.1 Ultrasonic absorption ....................... 1393.3.2 Optical technique ......................... 1413.3.3 Ion-pair formation of metal salts . . . . . . . . . . . . . . . . . . 1424 . SPECTRAL LINE-BROADENING ......................... 1424.1 Nuclear magnetic resonance ....................... 1424.1.1 Applications Of NMR ........................ 1414.2 Electron spin resonance and other spectral methods ............ 149