Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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APPENDIX 4 42 1Appendix 4 (continued)Numerical data for the construction of curves of a against loglo 0 for a 1st orderprocess perturbed by a 2nd order process1. VALUES OF e FOR GIVEN VALUES OF a AND K0.2 0.5 1 .o 2.0 4.0 8.00.90.80.70.60.50.40.30.20.10.10540.22310.35670.51080.69320.91631.2041.6092.3030.0886 0.071 50.1892 0.15420.3054 0.25130.4418 0.36770.6061 0.51080.8109 0.69321.080 0.93831.466 1.2992.140 1.9460.0541 0.0364 0.02200.1178 0.0800 0.04880.1942 0.1335 0.08220.2877 0.2007 0.12520.4055 0.2877 0.18230.5596 0.4055 0.26240.7732 0.5754 0.38301.099 0.8473 0.58781.705 1.386 1.0300.01230.02740.04650.071 50.10540.15420.23050.36770.69322. VALUES OF log,, e FOR GIVEN VALUES OF a AND K0.2 0.5 1 .o 2.0 4.0 8.00.90.80.70.60.50.40.30.20.1T.022T.348T.552T.708i.841T.9620.0810.2060.3622.947T.2777.485i.645T.783T.9090.0330. I660.3302.854T.188T.400T.566T.7087.841T.9720.1140.2892.7337.071i.288T.459i.6087.748T.888 -0.0410.232-2.5612.903-1.1267.303T.459-1.608T.760T.9280.1422.3422.6882.915T.098i.261T.419T.583T.769'0.0132.0892.4382.668-2.8547.023T.1881.363T.566i.841
IndexAabsorption cross section, chemical, 140absorption of radiation, 35—, and intermittent illumination, 50—, determination of, 55, 63absorption spectra, and determination of intermediates,290-294—, and flash photolysis, 119—, and photochemistry, 35—, of hydrated electron, 122accelerated flow method, 164accelerators, see particle acceleratorsacetaldehyde, as actinometer, 61—, as radical trap, 75—, cool flame, emission of, 286—, —, products of, 281—, decomposition of, 2, 3, 5—, —, and D substitution, 78—, —, chain initiation and termination, 3—, —, order, 2, 14—, —, steady state, time to, 4, 5—, from C a H 4 0 pyrolysis, determination byIR, 90—, reaction + CH 3 , 3, 76—, reaction + NO, 73—, reaction + 0 2 , mass spectrometric study,95acetone, as actinometer, 61—, from Me 3 CO decomposition, 4, 316—, polymerisation in presence of H halides, 71—, thermal conductivity of, 82—, triplet state, quenching of, 5acetylene, as dosimeter, 68—, chemisorption on metals, 190—, collision cross-section for electrons, 330—, determination by gas chromatography, 80—, determination by interferometry, 103—, determination by mass spectrometry, 302—, emission from vibrational!^ excited, 287—, flames, determination of electrons in, 329,330—, —, study of negative ions in by mass spectrometry,308—, from photolysis C 3 H 6 , 63—, reaction + O, ions from by mass spectrometry,307—, reaction + O a -f C 5 H u N0 2 +J>bEt4, flashphotolysis, 120'acetyl radicals, in decomposition of CH 3 CJi6,3acid-base reactions, and fluorescence quenching,156—, rate data for, 162acids, determination by spectroscopy, 290—, effect on EtOH NMR lines, 148—, reaction + hydrated electron, 123actinometry, 35, 61, 62activated complex, see transition stateactivation energy, and explosion, 18—, and microcatalytic reactor, 235—, and NO+O s reaction, 289—, and thermograms, 257-260—, calculation of, 404-406—, for desorption from Sash filament method,195—, of catalytic reaction, and mass transfer,224, 230—, of CH 3 +halogens and H halides, 74—, of diffusion controlled reactions, 253—, of H+D a O, 317—, of N+O a , 167—, of 0+N 2 0, 318—, of radical reactions, 116, 117—, —, and enthalpies, 3, 4active centres, reaction + isoprene, kineticsof, 410-418adiabatic compression, and shock waves, 125—, principle of method, 127adiabatic propagation of sound waves, 139adiabatic reactions, pressure effects in, 2, 17—, rate coefficients for, 30adsorbed volume, determination of, 187-197adsorbed weight, determination of, 197-199adsorption, at liquid interface, 263—, from solution, 249-251—, kinetics of, 189—, of H halides on glass, 10—, of H 2 and H a O on glass, 11—, on semiconductors, 212, 213—, types of, 180ageing, of Hg vapour lamps, 44—, of reaction vessels, 11, 26air, range of high energy particles in, 66alcohols, effect on dissociation constant of aminopyrenes,156aldehydes, determination by polarography, 96—, determination in combustion systems, 280,281, 290alkali metals, adsorption on W, thermionicemission study, 201alkyl halides, pyrolysis of to give carbonaceousfilm, 11—, reaction -f Co(CN) s 8 -, 166alkyl nitrites, pyrolysis of to give carbonaceousfilm, 11
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COMPREHENSIVE CHEMICAL KINETICS
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P.O.ELSEVIER PUBLISHING COMPANY335
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Contributors to Volume 1L. BATTDepa
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XCONTENTS4.3 Gas chromatography ...
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XI1CONTENTS4.6 Magnetic measurement
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4 EXPERIMENTAL METHODS FOR SLOW REA
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8EXPERIMENTAL METHODS FOR SLOW REAC
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Reaction Furnace CircuitI10 EXPERIM
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178 REFERENCES46 M. EIGEN AND L. DE
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Chapter 3Experimental Methods for t
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182 EXPERIMENTAL METHODS FOR HETERO
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206 EXPERXMENTAL METHODS FOR HETERO
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280 DETECTION AND ESTIMATION OF INT
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344 TREATMENT OF EXPERIMENTAL DATAf
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Page 439 and 440: 424 INDEXbenzyl chloride, matrix ph
Page 441 and 442: 426 INDEXchlorine (contdj—, react
Page 443 and 444: 428 INDEXdeuterium oxide, addition
Page 445 and 446: 430 INDEXentropy change, in radical
Page 447 and 448: 432 INDEXfrequency of oscillation,
Page 449 and 450: 434 INDEXhydrogen atoms (contdj—,
Page 451 and 452: 436 INDEXisotopes (contd.J—, use
Page 453 and 454: 438 INDEXmethyl radicals, chain ter
Page 455 and 456: 440 INDEXoctadiene, ESR determinati
Page 457 and 458: 442 INDEXphotoelectric measurement,
Page 459 and 460: 444 INDEXrad, definition of, 66radi
Page 461 and 462: 446 INDEXSchmidt number, and mass t
Page 463 and 464: 448 INDEXTtailing reducer, in gas c
Page 465: 450 INDEXviscosity, and diffusion c
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