Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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Is reactlon[BH homogeneous',NOIs initial rate affected bypresence o? product ?I-Surface catalysed reaction or cham reaction mvolvmg inhatlon or termmataon processes on wallsAre all reactants and products identlfied at all staqes CI the reactton? IIYESAre all stoichiometric ratas independent c4extent ot reaction and temperature ?IN0 IYES NOIs initial rate maximumIs initial rate maximum Is initial rate affected by Is initial rate affected byrate observed ? rate observed 7 presence of product ? presence of product ?I I Irate observed 7 rate observed 9reactionsI NOI YESPsecutiveConsecutivereactims inreactlonswhich products in which(act azrcatalysts product acts'as inhibitorchain reaction1Can rate Chain reactlon wtth long Reversiblebe chains and LOW ccncentra- reactionrepresented tions of chain carrters proceedingequillto brlumequakyon 1Set of parallel react-ions ot la) specialtypeop(b) minor significancesuch that effect onStOIchiOmetryUndetectabLe-Simple reactionP,W
420 TREATMENT OF EXPERIMENTAL DATAAppendix 4Numerical data for the construction of curves of a against loglo 8 for a 1st orderprocess perturbed by a 0th order process1. VALUES OF e FOR GIVEN VALUES OF c1 AND K0.2 0.5 1 .o 2.0 4.0 8.00.90.80.70.60.50.40.30.20.10.10540.22310.35670.51080.69320.91631.2041.6092.3030.08700.18230.28770.40550.53900.69320.87551.0991.3860.06900.14310.22310.31020.40550.51080.62860.76210.91630.05130.10540.16250.22310.28770.35670.43080.51080.59780.03390.06900.10540.14310.18230.22310.26570.31020.35670.02020.04080.06190.08340.10540.12780.15080.17440.19850.01 120.02250.03390.04550.05720.06900.08100.09310.10542. VALUES OF log,, 8 FOR GIVEN VALUES OF a AND K,0.9 7.022 2.940-0.8 1.348 T.261-0.7 1.552 i.4590.6 i.708 i.6080.5 i.841 T.7320.4 1.962 T.8410.3 0.081 i.9420.2 0.206 0.0410.1 0.362 0.1420.2 0.5 1 .o 2.0 4.0 8.0-2.839 2.710 2.530 2.305T.156 7.023 2.839 2.611~.349 i.211 ~.023 2.792-i.492 i.349 1.156 2.921T.608 7.459 i.261 T.0231.708 is52 T.349 T.107-1.798 i.424 in-1.882 T.708 T.492 T.242-1.962 i.777 ~ ~ 5 -.298 22.0482.3522.5302.6582.757'2.8392.9082.969T.023
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COMPREHENSIVE CHEMICAL KINETICS
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P.O.ELSEVIER PUBLISHING COMPANY335
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Contributors to Volume 1L. BATTDepa
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XCONTENTS4.3 Gas chromatography ...
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XI1CONTENTS4.6 Magnetic measurement
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4 EXPERIMENTAL METHODS FOR SLOW REA
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8EXPERIMENTAL METHODS FOR SLOW REAC
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Reaction Furnace CircuitI10 EXPERIM
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12 EXPERIMENTAL METHODS FOR SLOW RE
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22 EXPERIMENTAL METHOD§ FOR SLOW R
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~~ ~36 EXPERIMENTAL METHODS FOR SLO
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100 EXPERIMENTAL METHODS FOR SLOW R
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Chapter 2Experimental Methods for t
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114 EXPERIMENTAL METHODS FOR FAST R
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;,124 EXPERIMENTAL METHODS FOR FAST
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178 REFERENCES46 M. EIGEN AND L. DE
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Chapter 3Experimental Methods for t
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182 EXPERIMENTAL METHODS FOR HETERO
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~~~ ._190 EXPERIMENTAL METHODS FOR
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192 EXPERIMENT A L MET H 0 D S F 0
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194 EXPERIMENT A L MET H o D s F o
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206 EXPERXMENTAL METHODS FOR HETERO
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222 EXPERIMENT A L METHODS F 0 R HE
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230 EXPERIMENT A L METHOD s FOR HET
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236 EXPERIMENT A L METHOD s FOR HE
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242 EXPERIMENT A L ME TH 0 D S FOR
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248 EXPERIMENT A L METHOD s F o R H
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254 EXPERIMENTAL MET HODS FOR HETER
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258 EXPERIMENT A L METHODS F 0 R HE
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266 EXPERIMENT A L MET H o D s F o
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270 EXPERIMENTAL MET HODS FOR HE TE
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274 EXPERIMENT A L METHOD s FOR HE
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280 DETECTION AND ESTIMATION OF INT
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344 TREATMENT OF EXPERIMENTAL DATAf
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346 TREATMENT OF EXPERIMENTAL DATAp
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348 TREATMENT OF EXPERIMENTAL DATAg
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350 TREATMENT OF EXPERIMENTAL DATAT
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352 TREATMENT OF EXPERIMENTAL DATAW
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354 TREATMENT OF EXPERIMENTAL DATA[
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356 TREATMENT OF EXPERIMENTAL DATAT
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360 TREATMENT OF EXPERIMENTAL DATA(
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Page 437 and 438: IndexAabsorption cross section, che
Page 439 and 440: 424 INDEXbenzyl chloride, matrix ph
Page 441 and 442: 426 INDEXchlorine (contdj—, react
Page 443 and 444: 428 INDEXdeuterium oxide, addition
Page 445 and 446: 430 INDEXentropy change, in radical
Page 447 and 448: 432 INDEXfrequency of oscillation,
Page 449 and 450: 434 INDEXhydrogen atoms (contdj—,
Page 451 and 452: 436 INDEXisotopes (contd.J—, use
Page 453 and 454: 438 INDEXmethyl radicals, chain ter
Page 455 and 456: 440 INDEXoctadiene, ESR determinati
Page 457 and 458: 442 INDEXphotoelectric measurement,
Page 459 and 460: 444 INDEXrad, definition of, 66radi
Page 461 and 462: 446 INDEXSchmidt number, and mass t
Page 463 and 464: 448 INDEXTtailing reducer, in gas c
Page 465: 450 INDEXviscosity, and diffusion c
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Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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