Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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2 SHOCK TUBE AND ADIABATIC COMPRESSION 123ea
;,124 EXPERIMENTAL METHODS FOR FAST REACTIONSDriver gasIIDiaphragmvObservationpointsFig. 3. Schematic arrangement for the shock tube.sure is instantaneous. This is a shock wave, and, if their energy were not graduallydissipated to the medium, all sounds would eventually become shock waves a sufficientlylarge distance from the source. Shock waves are used in the study of thekinetics of gas reactions most conveniently in a shock tube. A good general accountof the application of the technique to chemical kinetics has been given by Bauer”.Other general treatments give varying amounts of theoretical and practical de-In principle, the design of a shock tube is very simple; it is illustrated in Fig. 3.Typically, a smooth metal or glass tube about twenty feet long and a few inches indiameter is divided into two compartments by a thin diaphragm made of a suitablematerial such as cellophane or aluminum foil. About a third of the tube comprisesa high-pressure region containing the “driver” gas, often hydrogen or helium. Theremainder of the tube is a comparatively low-pressure region containing the gasmixture whose reactions are to be studied. The experiment is started by puncturingFig. 4. Becker’sso~model for the formation of a shock wave.
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COMPREHENSIVE CHEMICAL KINETICS
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P.O.ELSEVIER PUBLISHING COMPANY335
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Contributors to Volume 1L. BATTDepa
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XCONTENTS4.3 Gas chromatography ...
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XI1CONTENTS4.6 Magnetic measurement
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4 EXPERIMENTAL METHODS FOR SLOW REA
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8EXPERIMENTAL METHODS FOR SLOW REAC
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Reaction Furnace CircuitI10 EXPERIM
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12 EXPERIMENTAL METHODS FOR SLOW RE
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~~ ~36 EXPERIMENTAL METHODS FOR SLO
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174 EXPERIMENTAL METHODS FOR FAST R
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176 EXPERIMENTAL METHODS FOR FAST R
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178 REFERENCES46 M. EIGEN AND L. DE
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Chapter 3Experimental Methods for t
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182 EXPERIMENTAL METHODS FOR HETERO
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~~~ ._190 EXPERIMENTAL METHODS FOR
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192 EXPERIMENT A L MET H 0 D S F 0
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194 EXPERIMENT A L MET H o D s F o
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206 EXPERXMENTAL METHODS FOR HETERO
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222 EXPERIMENT A L METHODS F 0 R HE
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230 EXPERIMENT A L METHOD s FOR HET
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236 EXPERIMENT A L METHOD s FOR HE
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242 EXPERIMENT A L ME TH 0 D S FOR
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248 EXPERIMENT A L METHOD s F o R H
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254 EXPERIMENTAL MET HODS FOR HETER
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258 EXPERIMENT A L METHODS F 0 R HE
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266 EXPERIMENT A L MET H o D s F o
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270 EXPERIMENTAL MET HODS FOR HE TE
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274 EXPERIMENT A L METHOD s FOR HE
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280 DETECTION AND ESTIMATION OF INT
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344 TREATMENT OF EXPERIMENTAL DATAf
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346 TREATMENT OF EXPERIMENTAL DATAp
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348 TREATMENT OF EXPERIMENTAL DATAg
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350 TREATMENT OF EXPERIMENTAL DATAT
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352 TREATMENT OF EXPERIMENTAL DATAW
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366 TREATMENT OF EXPERIMENTAL DATAW
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370 TREATMENT OF EXPERIMENTAL DATAc
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41 2 TREATMENT OF EXPERIMENTAL DATA
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~~414 TREATMENT OF EXPERIMENTAL DAT
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41 8 TREATMENT OF EXPERIMENTAL DATA
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IndexAabsorption cross section, che
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424 INDEXbenzyl chloride, matrix ph
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426 INDEXchlorine (contdj—, react
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428 INDEXdeuterium oxide, addition
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430 INDEXentropy change, in radical
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432 INDEXfrequency of oscillation,
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434 INDEXhydrogen atoms (contdj—,
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436 INDEXisotopes (contd.J—, use
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438 INDEXmethyl radicals, chain ter
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440 INDEXoctadiene, ESR determinati
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442 INDEXphotoelectric measurement,
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444 INDEXrad, definition of, 66radi
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446 INDEXSchmidt number, and mass t
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448 INDEXTtailing reducer, in gas c
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450 INDEXviscosity, and diffusion c
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Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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