Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

434 INDEXhydrogen atoms (contdj—, study by ESR, 313—, use for cleaning metal surfaces, 181hydrogen bonding, study by NMR, 148hydrogen bromide, adsorption on glass, 10—, as actinometer, 61—, as radical trap, 74—, as scavenger in radiolysis, 70—, effect on hydrocarbon oxidation, 76—, mixing time with CO a and (Me 3 CO) 2 , 22—, reaction + CH 3 , 74—, reaction + RO a , 76—, reaction + triplet acetone, 5hydrogen chloride, adsorption on glass, 10—, as radical trap, 74—, catalysis of (Me s CO) 2 decomposition, 88—, determination by conductivity, 97—, determination by gas titration, 78—, dissolution of Fe and CaCO s by, 253—, effect on EtOH NMR lines, 148—, effect on Me 2 0 decomposition, 76—, excited from H-f-Cl a , 55, 90, 288—, isotopic exchange + KC1, 249—, mixing time with (Me 3 CO) 2 , 22—, photosensitised decomposition of, 78—, reaction -f CH 3 , 74—, reaction + H, 190hydrogen cyanide, from matrix photolysis ofCH,N 8 , 335hydrogen deuteride, determination by gas chromatography,237hydrogen discharge tube, 52hydrogen fluoride, as radical trap, 74, 75—, reaction + CH 3 , 74—, reaction + glass vessels, 10—, reaction + SiO a , 253hydrogen iodide, adsorption in glass vessels, 10—, as actinometer, 61—, as radical trap, 74—, as scavenger in radiolysis, 70—, decomposition, rate expression for, 396—, photolysis and o-p H^ conversion, 72—, photolysis in CO matrix, 332—, reaction + CH 3 , 74—, reaction + hot H, 283hydrogen ions, reaction + CF 3 CO a -, 152—, reaction + CH 3 COCO a -, 161—, reaction + hydrated electron, 122—, reaction + OH", 112hydrogen peroxide, and catalytic, current inpolarography, 161, 162—, determination by polarography, §6-—, matrix photolysis of and ESR, 311—, reaction + NaCIO giving singlet O a , 322hydrogen sulphide, as radical trap, 75—, chemisorption on metals, 190—, photolysis in CO matrix, 332—, reaction -f N, 313hydroperoxy radicals, detection in flames,287—, from H+O a , mass spectrometric study,302hydroquinone, inhibition of chain reactions by,316hydroxyl ions, from hydrated electron reactions,123—, reaction + CH 3 I, rate expression for, 396—, reaction + H+, 112—, reaction + NH 4 +, 139hydroxyl radicals, determination of in H 2 +O ain shock tube, 128—, excited, from H+O a , 282—, —, from H 2 +0 2 , 286—, extinction coefficient of, determination,291, 292—, from H+N0 2 , 292—, in flames, determination of, 287, 290, 302,318, 319—, reaction + H+Na, 319—, reaction + 0 3 , 283—, study of by ESR, 313hydroxypropyl radical, from triplet acetone +HBr, 5hydroxyquinoline, reaction + Mg a+ , 131-133Iignited catalysts, 220IlkoviC equation, 160, 161impedance bridge, for capacity/voltage curvedetermination, 250impregnated catalysts, 221inconel tube, in furnace, 8, 9indicators, use in relaxation methods, 133—, use in T-jump, 136indium, chemisorption on, 190—, clean surface by cleavage, 184induction period, for solid decomposition, 246—, of reactions, and mechanism, 399inert electrolyte, in electroreduction, 157inert gas, and photocells, 62—, as charge transfer agent, 70—, as energy transfer agent, 16, 17—, as reference in dosimetry, 69—, effect in flash photolysis, 120—, effect on CH 3 CHO decomposition, 3—, effect on H a +O a reaction, 18—, effect on radiolysis, 70, 77—, in beam microbalances, 198—, in chemical transport, 248—, in Hg lamps, 39, 44, 47, 52, 53