Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 423allene, from photolysis of C 3 H 6 , 63allocinnamic acid, cis-trans isomerisation, 72allyl radical, and inhibition by C 3 H 6 , 73alpha-particles, induced reactions, vessels for,64—, in ionising electrode method, 268—, production of and range, 66alternating current bridge, 213, 215aluminium, beam for microbalance, 199—, chemisorption on, 190—, diaphragm for shock tube, 124—, preparation of films of, 183—, range of high energy particles in, 66—, removal from Ni alloy for Raney nickel,221aluminium oxide, adsorption of N0 2 on, 208—, catalyst support, 222—, chemisorption on, 190—, column in gas chromatography, 80, 81—, —, for H 2 , D a and HD, 237—, gel catalyst, preparation of, 221—, support for metal for IR study, 217americium, in ionising electrode method, 268amines, as radical traps, 75aminopyrenes, protonation of and fluorescencequenching, 156ammonia, as radical trap, 75—, chemisorption on metals, 190—, determination by gas titration, 78—, diffusion flame, spectroscopy of, 290—, photolysis of, and o-p H 2 conversion, 72,317—, —, in matrix, 334, 335ammonium azide, from pyrolysis HN 3 , 334ammonium ions, reaction -h OH - , 139ammonium perchlorate, decomposition of, 247ammonium permanganate, decomposition of,247ammonium salts, for catalyst preparation, 220,221amplification, of photomultiplier, 62, 63amplifier, photoelectric, for galvanometer, 59,60amyl nitrite, flash photolysis of + C a H 8 /0 2 /PbEt 4 , 120aniline, as radical trap, 74anode film, for photoemission method, 202—, for space charge limited diode, 204, 205anthracene, triplet state from flash photolysis,294anti-knock action, of PbEt 4 , 126, illantimony, clean surface by cleavage, 184^—, mirrors of, radical removal by, 315—, preparation of films of, 183appearance potential curves, 296, 298, 299appearance potentials, of ions and radicals, determinationby mass spectrometry, 296, 297argon, collision cross section for electrons, 330—, effect on radiolysis, 70—, efficiency of energy transfer by, 17—, matrices of, for trapped radicals, 334, 335—, resonance lamp, 52—, use in ion bombardment, 185—, use in shock tubes, 126Arrhenius parameters, 1, 3, 4, 404arsenic, clean surface of by cleavage, 184—, mirrors of, radical removal by, 315—, preparation of films of, 183aspect ratio, and reactors for catalysis, 233 'atoms, as intermediates, 282—, determination by calorimetry, 98, 99, 325,326—, — effusion gauge, 327, 328—, — ESR, 91, 92, 313—, — gas titration, 78, 320-322—, —r mass spectrometry, 300, 302, 303—, — pressure measurement, 324—, — thermal conductivity, 325—, hot, see hot atoms—, interstitial, in solids, study by ESR, 310attenuation constant, in ultrasonic absorption,139Auger electron emission, for cleaning surfaces,182autoclaves, for high pressure catalytic reactions,230, 251azides, matrix photolysis of, 334, 335azomethane, as photosensitiser, 77—, decomposition of, energy transfer in, 17—, effect on «-C 4 H 10 decomposition, 76, 77—, radiolysis of, 63Bbaking, of vacuum system, 7, 10barium, chemisorption on, 190—, preparation of films of, 183Bayard-Alpert gauge, in flash desorption, 196beam microbalances, 198, 199beams, pulsed and continuous, production of,65Beer-Lambert law, 35, 89, 217—, and flash photolysis, 119bellows, use in dilatometry, 262benzene, as photosensitiser, 77—, as radical trap, 74benzoic acid, dimerisation, 139benzophenone ion, ESR spectrum of, 151benzylamine, matrix photolysis, ESR study of,310