Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

XI1CONTENTS4.6 Magnetic measurements . . . . . . . . . . . . .4.7 Dilatometry . . . . . . . . . . . . . . . . . .4.8 Other methods . . . . . . . . . . . . . . . . .5 . THE LIQUID-GAS INTERFACE . . . . . . . . . . . . .5.1 Introduction . . . . . . . . . . . . . . . . . .5.2 Measurement of film pressure-film area characteristics5.3 Surface potential measurements . . . . . . . . . .5.4 Other methods . . . . . . . . . . . . . . . . .REFERENCES ................................ . . . . . . . . .. . . . . . . . . .. . . . . . . . . ...................... . . . . . . . . .. . . . . . . . . .. . . . . . . . . .261261263263263264267269270Chapter 4 (R . P . WAYNE)The detection and estimation of intermediates . . . . . . . . . . . . . . . . 2791 . INTRODUCTION ............................... 2791.1 Stable intermediates . . . . . . . . . . . . . . . . . . . . . . . . . . . 2801.2 Free radicals and atoms . . . . . . . . . . . . . . . . . . . . . . . . . 2821.3 Excited species . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2821.41011s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2832 . CLASSICALSPECTROSCOPY .......................... 2842.1 Emission spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . 2862.2 Absorption spectroscopy . ........................ 2903 . MASSSPECTROMETRY ............................ 2943.1 Uncharged species . . . . . . . . . . . . . . . . . . . . . . . . . . . 2943.2 Ionic species . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 306'4 . ESR SPECTROMETRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3085 . 'CHEMICAL' METHODS ............................ 3146 . MISCELLANEOUS PHYSICAL TECHNIQUES .................... 3246.1 Pressure measurement . . . . . . . . . . . . . . . . . . . . . . . . . 3246.2 Thermal conductivity measurement .................... 3246.3 Calorimetry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3256.4 Wrede-Harteck gauges . . . . . . . . . . . . . . . . . . . . . . . . . 3277 . ELECTRICAL METHODS FOR CHARGED SPECIES .................. 3288 . TRAPPED RADICALS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 336Chapter 5 (D . MARGERISON)The treatment of experimental data . ..................... 3431 . INTRODUCTION ............................... 3432 . TESTING THE DATA FOR CONSISTENCY WITH EQUATIONS OF THE TYPE-d[A]/dr = k[A]"[B]b ........................... 3482.1 Reactions with known invariant stoichiometry . . . . . . . . . . . . . . 3492.1.1 Estimation of the orders a and b . . . . . . . . . . . . . . . . . . . 351(a) Estimation of total order, a+b . . . . . . . . . . . . . . . . . . 351(b) Estimation of the order. a . . . . . . . . . . . . . . . . . . . 358(c) Estimation of the order. b . ................... 360